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51.
考察了化学位移各向异性对半整数自旋四极核2D NMR章动的影响.用数值方法对2D NMR章动实验的演化期的Hamiltonian矩阵进行对角化,然后用帐篷法进行粉末平均,获得了自旋为I=3/2、5/2、7/2和9/2的四极核在不同化学位移各向异性下的2D NMR章动谱.实验结果与理论计算符合较好. 相似文献
52.
The universal magneto-optic (MO) coupled-mode equations for magnetostatic waves (MSWs) and guided optical waves (GOWs) under arbitrarily tilted bias magnetic fields are presented for the first time and, as an example, applied to the noncollinear Stokes interaction between the incident TE0-mode light and magnetostatic backward volume wave (MSBVW) excited by single-element microstrip line transducer in yttrium–iron–garnet (YIG) film. Our calculation indicates that, for the case of magnetization parallel to the MSBVW propagation direction, the diffraction efficiency (DE) is equal to the mode-conversion efficiency of the diffracted lights (MCDE) and the calculated curve of relative DE for the MSBVW-based MO Bragg cell in pure YIG waveguide is in good agreement with the experimental data. In contrast, the diffraction performance can be greatly improved by optimizing the bias magnetic field and the DE gain can be increased by 6.3 dB in the tangentially magnetized film. The angular dependences of the DE and the corresponding Bragg angle upon the magnetization direction are also discussed in the paper. 相似文献
53.
Li‐Ming Tang Yan‐Guo Li Wei‐Ping Ye Yue‐Sheng Li 《Journal of polymer science. Part A, Polymer chemistry》2006,44(20):5846-5854
Ethylene–propylene copolymerization, using [(Ph)NC(R2)CHC(R1)O]2TiCl2 (R1 = CF3, Ph, or t‐Bu; R2 = CH3 or CF3) titanium complexes activated with modified methylaluminoxane as a cocatalyst, was investigated. High‐molecular‐weight ethylene–propylene copolymers with relatively narrow molecular weight distributions and a broad range of chemical compositions were obtained. Substituents R1 and R2 influenced the copolymerization behavior, including the copolymerization activity, methylene sequence distribution, molecular weight, and polydispersity. With small steric hindrance at R1 and R2, one complex (R1 = CF3; R2 = CH3) displayed high catalytic activity and produced copolymers with high propylene incorporation but low molecular weight. The microstructures of the copolymers were analyzed with 13C NMR to determine the methylene sequence distribution and number‐average sequence lengths of uninterrupted methylene carbons. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5846–5854, 2006 相似文献
54.
Ye Lin Feng Zeng‐Guo Zhao Yu‐Mei Wu Feng Chen Shi Wang Guo‐Qing 《Journal of polymer science. Part A, Polymer chemistry》2006,44(11):3650-3665
A novel cyclic ether monomer 3‐{2‐[2‐(2‐hydroxyethoxy)ethoxy]ethoxy‐methyl}‐3′‐methyloxetane (HEMO) was prepared from the reaction of 3‐hydroxymethyl‐3′‐methyloxetane tosylate with triethylene glycol. The corresponding hyperbranched polyether (PHEMO) was synthesized using BF3·Et2O as initiator through cationic ring‐opening polymerization. The evidence from 1H and 13C NMR analyses revealed that the hyperbranched structure is constructed by the competition between two chain propagation mechanisms, i.e. active chain end and activated monomer mechanism. The terminal structure of PHEMO with a cyclic fragment was definitely detected by MALDI‐TOF measurement. A DSC test implied that the resulting polyether has excellent segment motion performance potentially beneficial for the ion transport of polymer electrolytes. Moreover, a TGA assay showed that this hyperbranched polymer possesses high thermostability as compared to its liquid counterpart. The ion conductivity was measured to reach 5.6 × 10?5 S/cm at room temperature and 6.3 × 10?4 S/cm at 80 °C after doped with LiTFSI at a ratio of Li:O = 0.05, presenting the promise to meet the practical requirement of lithium ion batteries for polymer electrolytes. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3650–3665, 2006 相似文献
55.
We prepared two vinyl copolymers P1 and P2 containing pendant distyrylbenzene and aromatic 1,3,4‐oxadiazole derivatives, respectively, from their precursor poly(styrene‐ran‐4‐vinylbenzyl chloride) (Mw = 11,400, PDI = 1.18), which had been prepared by the controlled radical polymerization (RAFT). Two main chain polymers containing similar isolated distyrylbenzene ( P3) and aromatic 1,3,4‐oxadiazole ( P4 ) chromophores were also synthesized for comparative study. The resulted copolymers ( P1 – P4 ) are soluble in common organic solvents and are basically amorphous materials with 5% weight‐loss temperature higher than 360 °C. The PL spectral results reveal that the architecture of P1 prevents the formation of inter‐ or intramolecular interaction. The HOMO and LUMO levels of P2 , estimated from cyclic voltammetric data, are ?5.96 and ?3.81 eV, respectively, which are much lower than those of P1 (?5.12 and ?3.11 eV). The emission of blend from P1 and P2 are contributed mainly from distyrylbenzene fluorophore (~450 nm) owing to efficient energy transfer. Moreover, the blend exhibits three kinds of redox behavior depending on their weight ratios. The luminance and current efficiency of the EL device lpar;ITO/PEDOT/ MEH ‐ PPV + P2 /Al) are 503 cd/m2 and 0.11 cd/A, which can be improved to 1285 cd/m2 and 0.44 cd/A, respectively, as the weight ratio of P2 increases from 0 to 20%. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5362–5377, 2006 相似文献
56.
STRONG LAW OF LARGE NUMBERS AND ASYMPTOTIC EQUIPARTITION PROPERTY FOR NONSYMMETRIC MARKOV CHAIN FIELDS ON CAYLEY TREES 总被引:1,自引:0,他引:1
Some strong laws of large numbers for the frequcncies of occurrence of states and ordered couples of states for nonsymmetric Markov chain fields(NSMC)on Cayley trees are studied.In the proof,a new technique for the study of strong liinit theorems of Markov chains is extended to the case of Markov chain fields.The asymptotic equiparti- tion properties with almost everywhere(a.e.)convergence for NSMC on Cayley trees are obtained. 相似文献
57.
I.IntroductionDuetospatia1andtemporalvariabilityoftheocean-acousticenvironment,especially,theeffectsofboundaryaswel1asmediumonpropagationofacousticwavesinshal1owwater,theacousticpropagationisextrcmelycomp1icatcd.Multipathtransmissionisthebasiccharacteris-hcsofunderwatersoundchannels.Undctcrminedmultipathstructurescangreatlylimittheperformanceofunderwateracousticdetcction.However,ifthemultipathcharacteristicsofacousticpropagationinunderwatcrsoundchanne1sareknown,spaee-timeresolutionandpro-cess… 相似文献
58.
The correlation times (τc) and cross relaxation rates of toluene, dimethylformamide, tetrahydrofuran, water-acetone and water-dioxane adsorbed on silica gel, alumina and charcoal were obtained by measurements of the integrated intensities of cross and diagonal peaks in their NOESY spectra. The (τc) of the above mentioned systems is in the range of 10?6?10?9 s, much longer than that in the liquid (10?12?10?14 s). It was found that intramolecular rotation of toluene adsorbed on charcoal is slower than that on SiO2, Al2O3 and the inversion of α and β protons in tetrahydrofuran is very fast (τc = 1.76×10?9 s). The cross relaxation plays an important role in the relaxation of molecules adsorbed on solid surfaces with low electron densities. 相似文献
59.
负载型双金属簇催化剂的多相一氧化碳加氢反应性能索全伶,李晔(内蒙古工业大学化学工程系,呼和浩特010062)殷元骐,金道森(中国科学院兰州化学物理研究所,兰州730000)关键词一氧化碳加氢,多相催化,双金属簇催化剂,钾效应。1.引言异核金属羰基簇作... 相似文献
60.
海螵蛸入药部分和废弃部分8种无机元素分析 总被引:3,自引:0,他引:3
为合理开发利用海螵蛸 ,用原子吸收分光光度法测定了海螵蛸中入药部分和废弃部分中8种人体必需无机元素含量。结果表明 ,入药部分和废弃部分中钙含量丰富 ,分别达到 742 1 3× 1 0 - 3和 65 9 76× 1 0 - 3。入药部分铜、铁含量较废弃部分高 ,分别为 9 41× 1 0 - 6 、 91 86× 1 0 - 6 和2 3 5× 1 0 - 6 、 2 5 7× 1 0 - 6 。废弃部分含锌丰富 ,为 3 5 3 62× 1 0 - 6 ,数倍于入药部分 64 65× 1 0 - 6 。可见海螵蛸入药部分和废弃部分均具有良好的开发前景 相似文献