Fleet algorithm for X-ray pulsar profile construction and TOA solution based on compressed sensing

X-ray pulse profile and time of arrival (TOA) are the two important physical quantities for pulsar navigation. With the standard and integrated X-ray pulse profiles modeled, X-ray pulse profile construction is studied and TOA is solved using compressed sensing (CS) technology. The observation matrix and waveform complete dictionary are mainly examined. A column vector-based matching pursuit algorithm is presented. The feasibility of obtaining X-ray pulse profile construction by compressed sensing technology is verified by numerical simulation. Compared with the X-ray pulse profile construction method based on epoch folding, the proposed method exhibits improved real-time performance, and its detection time for integrated X-ray pulse profile could be reduced by one order of magnitude. This proposed method can also solve for TOA solution and construct the X-ray pulse profile simultaneously, which is essential to improve pulsar navigation efficiency.     

Accurate measurement of high resolution spectrum obtained by F–P etalon and ICCD

The Fabry–Pérot (F–P) etalon and intensified charge-coupled device (ICCD) can be used to obtain the scattering spectrum and retrieve the medium parameters. However, the instrumental broadening, along with the noise, which is mainly caused by the quantum nature of the scattered light and thermally generated electrons in ICCD, will affect the measurement accuracy of the spectrum characteristics. In this paper, the characteristics of these influencing factors are analyzed, and a processing method is proposed for accurate measurement. Experiment results show that the method can improve the measurement accuracy from tens of MHzs to MHz magnitude.     

基于优度评价方法的面向信号软件平台中的仪器更换研究

针对现在维护ATS时遇到的对仪器更换方案很难选择的问题,首先讨论在维护ATS时,更换ATS中仪器的必要性,并介绍面向信号ATS软件平台给测试带来的便利,然后在面向信号ATS软件平台的基础上使用可拓学中物元模型较为完善的对仪器进行形式化的描述,并通过蕴含分析和发散分析来生成仪器的更换方案,最后通过一个简单的例子介绍使用优度评价方法来定量描述仪器更换方案的优劣以选择较优的更换方案。     

Access to spirocyclic oxindoles via N-heterocyclic carbene-catalyzed reactions of enals and oxindole-derived α,β-unsaturated imines

A diastereoselective access to β-lactam fused spirocyclic oxindoles and related compounds bearing all carbon spiro centers is described. This N-heterocyclic carbene-catalyzed process employed challenging β,β-disubstituted α,β-unsaturated imines to react with enals.     

Bridged polyhedral oligomeric silsesquioxane (POSS): A potential member of silsequioxanes

Two novel and well-defined polyhedral oligomeric silsesquioxanes（POSS） with two same Si₈O₁₂ cores and a reactive NH group, namely bridged-POSS（2a and 2b）,have been prepared by the traditional ’corner-capping’ reaction.X-ray diffraction demonstrates that those two POSS have the similar T₈ structure.From the thermo-gravimetric analysis,bridged-POSS shows the belter thermal degradation stability than the contrastive POSS.     

Convenient synthesis and application of novel bi-SO3H-functionalized ionic liquids based on piperazinium

In this article,series of novel bi-SO₃H-functionalized ILs were synthesized using simple,efficient and economic procedure. Hammett method had been used to determine the acidity order of these ionic liquids,and the acidities of bi-SO₃H-functionalized ILs were stronger than that of traditional single-SO₃H-functionalized ILs.Their catalytic activities in the synthesis of N-（3-phenyl）-3- oxo-l-（phenylpropyl）acetamide were investigated and they were consistent with their acidities.     

NASICON结构的锂离子导电微晶玻璃结构与电导率

通过对LixAlx-1Ge3-x(PO4)3(x=1.1～1.9)锂离子导电玻璃的差示量热扫描(DSC)数据,结合XRD及其Rietveld精修、FESEM和交流阻抗等测试方法,研究了该系微晶玻璃的物相组成、主晶相晶胞参数变化情况、微观结构形貌、锂离子电导率和电化学窗口等。结果表明:LixAlx-1Ge3-x(PO4)3(x=1.1～1.9)锂离子导电微晶玻璃析出导电主晶相为LiGe2(PO4)3。当x=1.5时,由于导电主晶相LiGe2(PO4)3晶粒充分长大、分布均匀,晶界清晰,LAGP导电微晶玻璃的室温电导率最高(可达5.3×10-4 S.cm-1),电化学窗口为7.2V,可以满足全固态锂离子电池对电解质高室温电导率和宽电化学窗口的应用要求。     

Crystalline metallic Au nanoparticle-loaded α-Bi(2)O(3) microrods for improved photocatalysis

Crystalline metallic Au nanoparticles were loaded on α-Bi(2)O(3) microrods (Au/α-Bi(2)O(3)) using an Au deposition-precipitation method. The prepared samples were characterized by scanning electron and transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and UV-vis diffuse reflectance spectroscopy. Upon visible light irradiation, the Au/α-Bi(2)O(3) exhibits much higher photocatalytic activities than the pure α-Bi(2)O(3) for the degradation of Rhodamine B and 2,4-dichlorophenol in aqueous solution. The role of the Au and the paths of electron transport in the photocatalysis of the Au/α-Bi(2)O(3) were investigated and discussed in detail based on the analysis of the photo-generated hydroxyl radicals (˙OH) and hydrogen peroxide (H(2)O(2)) in the visible light irradiated suspension of pure α-Bi(2)O(3) and Au/α-Bi(2)O(3). The result reveals that the Au loaded on α-Bi(2)O(3) plays a critical role in the separation of the electron and hole pairs by accumulating the electrons from the excited α-Bi(2)O(3), which is responsible for the enhanced photocatalytic activity.     

The development of direct multicolour fluorescence cross-correlation spectroscopy: towards a new tool for tracking complex biomolecular events in real-time

Direct three-colour fluorescence cross-correlation spectroscopy can reveal interactions between three fluorescently labelled biomolecules, giving insight toward the complex events that constitute signal transduction pathways. Here we provide the optical and theoretical basis for this technology and demonstrate its ability to detect specific biological associations between nanoparticle-labelled DNA molecules.