Certification of the sulphur content of three rapeseed reference materials

Summary The sulphur content of three rapeseed reference materials has been certified on the basis of measurements made by inductively coupled plasma-optical emission spectroscopy, isotope-dilution mass spectrometry and ion chromatography. Their suitability for the calibration of x-ray fluorescence spectrometers used for measuring sulphur in rapeseed samples was established.     

Optimum parameters for the generalized ADI method

Summary. In the context of the generalized ADI method, we are concerned with the problem of finding in the set of rational functions r with numerator degree m and denominator degree n an element that minimizes where E,F are disjoint real intervals. By extending a recent analysis by Levin and Saff, we present an explicit formula for choosing the pair (m,n) for given m +n. Furthermore, we provide a characterization of and a Remes type algorithm for its determination. Extensive numerical computations furnish some comparison of with asymptotically optimal solutions based on Fejér-Walsh and Leja-Bagby points. Received September 6, 1996 / revised version received June 30, 1997     

Magnetism in disordered magnetic Fe82−xNixCr18

The zero field μSR-method has been used to study the magnetism in the disordered magnetic alloy Fe_82−xNi_xCr₁₈ near the three-critical, pointx=25. The dynamic and static local field distributions are analyzed. The difference between spin-glass states obtained either from the paramagnetic or after the double transition is discussed.     

The method of concentrating a substance from a solution in a stationary sorbent layer and its theoretical basis

The principle of concentrating a substance from a mixture flow in a stationary sorbent layer of infinite length that was previously developed for gas chromatography is extended to liquid chromatography. Translated fromIzevestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1063–1065, May, 1997.     

Phonon growth in a many valley model semiconductor at low lattice temperatures

It is shown how the traditional method of neglecting the energy of acoustic phonons and approximating their distribution by the equipartition law leads to significant errors in the phonon growth rate in a many-valley model semiconductor when the lattice temperature is low.     

Spontaneous photorefractive effect in Sr1−x CaxTiO3 (x=0.014)

The temperature dependence of the principal values of the refractive index in Sr_1−x Ca_xTiO₃ (x=0.014) has been measured in the 17–275 K range under various conditions of sample illumination with 1.96 eV photons. The spontaneous photorefractive contribution δn ^ph to the temperature-induced variation of the refractive index of Sr_1−x Ca_xTiO₃, which appears after illumination of the sample in the ferrophase (transition temperature T _c=32 K) and persists in the paraphase under heating up to 150 K, has been separated. The photoinduced polarization has been estimated. Fiz. Tverd. Tela (St. Petersburg) 39, 711–713 (April 1997)     

Integrated Superconducting Submillimeter-Wave Receivers

We overview recent achievements in the field of cryogenic submillimeter-wave receivers based on superconductor–insulator–superconductor (SIS) tunnel junctions. The main attention is paid to the novel superconducting integrated receivers (SIRs) with an on-chip superconducting local oscillator. The single-chip microcircuit of the receiver, which integrates a quantum mixer based on the nonlinearity of a quasi-particle current in the SIS junction, a planar superconducting receiving antenna, and a cryogenic local oscillator, is described. Being dc-powered only by batteries, such a microcircuit operates as a submillimeter-wave superheterodyne receiver without any additional microwave equipment. Such receivers are very attractive for radioastronomical research, space communication systems, and monitoring of the environment from satellites, balloons, and special aircraft. A breadboard of a superconducting spectrometer with a phase-locked flux-flow oscillator (FFO) has been developed and tested. A frequency resolution better than 10 kHz was reached at a frequency of 365 GHz. We describe a balloon-borne 500-650 GHz integrated spectrometer for oblique atmospheric sounding, developed for the international Terahertz Limb Sounder (TELIS) project. The first flight is scheduled for 2005.     

Topochemically Controlled Redox Reactions in the System In/Sn/Cl

The difference in reactivity of the two modifications of InCl in solid state reactions with SnCl₂ is discussed. It is explained on the basis of semi‐empirical and ab initio calculations giving the density of states diagrams of InCl and the energies of possible disproportionation reactions. Their general features are discussed on the basis of a simple bonding picture for open‐packed structures involving inert pair elements. A detailed analysis of the DOS distribution allows to pinpoint the observed redox instability to a specific structural feature of α‐InCl.