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941.
The reactions of dimethyltin dichloride with nitrogen and sulfur donor ligands derived by condensation of S‐benzyldithiocarbazate with indol‐3‐carboxylaldehyde, thiophene‐2‐aldehyde and furfuraldehyde have been investigated in 1:1 and 1:2 molar ratios in anhydrous alcohol. These ligands act as mononegatively charged bidentate species and coordinate to the central tin(IV) atom through the thiosulfur by proton exchange with the azomethine nitrogen. The newly synthesized complexes have been characterized by elemental analysis, conductance measurements and molecular weight determinations. The mode of bonding and the geometry of the complexes have been suggested on the basis of infrared, electronic and 1H, 13C and 119Sn NMR spectroscopy, and probable structures have been assigned to these complexes. A few representative ligands and their tin(IV) complexes have also been screened for their antifungal and antibacterial activities and found to be quite active in this respect. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
942.
B. K. Kardashev Yu. A. Burenkov B. I. Smirnov V. V. Shpeizman V. A. Stepanov V. M. Chernov D. Singh K. C. Goretta 《Physics of the Solid State》2001,43(6):1084-1088
This paper reports a study of the effect of temperature and strain amplitude on Young’s modulus and ultrasonic damping in ceramic samples of graphitelike boron nitride prepared in the RF and USA by different technologies and using various additions to improve the mechanical properties of the ceramic. It is shown that, in addition to the influence on the effective elasticity modulus, additions improve the sample microplasticity, which apparently increases the strength of the material. 相似文献
943.
In the present communication a method based on the three body forces for the evaluation of second and third order elastic constants of mixed ammonium halides has been described. The Lundqvist three body potential is used along with long range Coulombian and short-range overlap repulsive potentials. The latter is taken of the Born-Mayer type and effective up to first neighbours only. It has been assumed that the charge transfer and short-range parameters depend linearly on the composition of solid solutions. Theoretical results obtained, for the entire range of compositions of mixed NH4Cl and NH4Br, have been compared with the recently measured experimental values and the theoretical results of other workers, whenever these are available.The authors are thankful to Dr. J. Shanker, Department of Physics, Agra University, Agra, for helpful discussions. 相似文献
944.
A study of hyperon semileptonic decays has been made in various quark models and compared with the standard Cabibbo analysis which is found to be in good agreement with experiments. Results obtained in a quasirelativistic constituent quark model are in reasonable agreement with the standard Cabibbo analysis and show no sizeableSU(3) symmetry breaking effects. Results in other quark models which take into account theSU(3) symmetry breaking effects in the dominant form factors are similar to the quasirelativistic constituent quark model. 相似文献
945.
Excitation functions for103Rh (α,xn);x = 1–4 and103Rh (α,αxn);x = 1–3 reactions were measured up to 50 MeV bombarding energy using stacked foil activation technique and high purity germanium
(HPGe) γ-ray spectroscopy method. The experimental results were compared with calculations considering equilibrium as well
as pre-equilibrium hybrid model of Blann (ALICE/90). It is found that the initial exciton configurationn
0 = 4(4p0h) gives fairly good agreements for (α,xn) reactions. There seems to be indication of direct inelastic scattering effects in (α,αxn)-type of reactions. 相似文献
946.
Parametric study of optical emission from two successive laser pulses produced chromium and magnesium plasma is presented.
The line emission from chromium and magnesium plasma showed an increase by more than six times for double laser pulse excitation
than for single-pulse excitation. An optimum increase in emission intensity was noted for inter-pulse delay of ∼2–3 μs for
all the elements. The experimental observations were qualitatively explained on the basis of absorption of second laser pulse
in the pre-formed (by first laser) coronal plasma by inverse Bremsstrahlung process, which were found responsible for the
excitation of more ions and atoms in the plasma. This process starts as the plasma scale length becomes greater than the laser
wavelength. This study further indicated the suitability of this technique in the field of elemental analysis 相似文献
947.
Jyotsna Galgale Nupinder Kaur Preeti Singh Manik Manake N. K. Gaur R. K. Singh 《Pramana》2004,63(2):413-417
An extended three-body force shell model (ETSM) has been applied to investigate the static and dynamic properties of KCN
x
Cl1−x
for the compositionx = 0.56 and 1.0 at 300 K. The phonon dispersion curves computed by us are compared with the single crystal neutron diffraction
data. The unusual features of these curves are the upward curvature seen in some of the acoustic branches. This is a result
ofK-dependent softening of the phonon due to translation-rotation coupling. The transverse acoustic branch is more soft near
the zone centre. 相似文献
948.
Fluorescence spectrum of Dy3+, Dy3+-Ho3+, Tb3+ and Tb3+-Er3+ doped in calibo glass have been studied using Ar+ and excimer lasers. Non-radiative energy transfer from trivalent dysprosium and terbium (donors) to holmium and erbium (acceptors)
respectively has been observed on the basis of decrease in the life time of the levels and reduction in fluorescence intensity
of Dy3+ and Tb3+ on increasing Ho and Er concentrations. The interaction mechanism of donor and acceptor ions is found to be dipole-dipole
in both cases. Various parameters such as donor-acceptor distances, non-radiative energy transfer efficiency (η) and energy transfer probability (P
da) have been computed. Stark splitting have also been marked in several intense transition of the two. 相似文献
949.
It is found from Maxwell's equations that the magnetic field lines are good analogues of relativistic strings. It is shown that the superconducting current in the neutron star's interior causes local rotation of magnetic flux tubes carrying quantized flux. 相似文献
950.
A system consisting of two interacting particles, one of which has the angular momentum 1/2 and the other of which has an arbitrary angular momentum (a muonium-like system) is considered. The possibility of reconstruction of all the elements of the spin density matrix with the help of the μSR method is shown. For entangled states (Einstein-Podolsky-Rosen and Schrödinger cat states), the time dependence of components of the polarization vector (μSR photographs) is demonstrated. It is shown that, to identify these states, two μSR photographs suffice. 相似文献