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71.
Dr. Gábor London Kuang‐Yen Chen Dr. Gregory T. Carroll Prof. Dr. Ben L. Feringa 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(32):10690-10697
We report the synthesis of altitudinal molecular motors that contain functional groups in their rotor part. In an approach to achieve dynamic control over the properties of solid surfaces, a hydrophobic perfluorobutyl chain and a relatively hydrophilic cyano group were introduced to the rotor part of the motors. Molecular motors were attached to quartz surfaces by using interfacial 1,3‐dipolar cycloadditions. To test the effect of the functional groups on the rotary motion, photochemical and thermal isomerization studies of the motors were performed both in solution and when attached to the surface. We found that the substituents have no significant effect on the thermal and photochemical processes, and the functionalized motors preserved their rotary function both in solution and on a quartz surface. Preliminary results on the influence of the functional groups on surface wettability are also described. 相似文献
72.
Dr. Gui‐Chao Kuang Ming‐Jun Teng Prof. Xin‐Ru Jia Prof. Dr. Er‐Qiang Chen Prof. Dr. Yen Wei 《化学:亚洲杂志》2011,6(5):1163-1170
There is a delicate balance for a low‐weight molecule to behave as a gelator or crystal. The synthesis of two novel amino acid‐based naphthalene‐dendrons, Nap ‐ G1 and Nap ‐ G2 is described. Both dendrons display polymorphic properties in organic solvents. Nap ‐ G1 developed a fibrous network with β‐sheet architecture in cyclohexane but exhibited a spherulitic network in mixed solvents (chloroform/petroleum ether 1:5, v/v). On the other hand, Nap ‐ G2 acted as an efficient organogelator in chloroform but formed crystalline fibers in relatively high polarity solvents (such as acetone and methanol). Combinations of characterizations have been employed to study the polymorphism. 相似文献
73.
Ionic liquids for the convenient synthesis of functional nanoparticles and other inorganic nanostructures 总被引:12,自引:0,他引:12
Antonietti M Kuang D Smarsly B Zhou Y 《Angewandte Chemie (International ed. in English)》2004,43(38):4988-4992
Ionic liquids are a new class of organic solvents with high polarity and a preorganized solvent structure. Very polar reactions can be carried out in these liquid in the absence of or with a controlled amount of water, and crystalline nanoparticles can be synthesized conveniently at ambient temperatures. The pronounced self-organization of the solvent is used in the synthesis of self-assembled, highly organized hybrid nanostructures with unparalleled quality. The extraordinary potential of ionic liquids in materials synthesis is described in this minireview and a physicochemical explanation is given. 相似文献
74.
Hierarchical porous silica materials with a trimodal pore system using surfactant templates 总被引:1,自引:0,他引:1
Porous silica exhibiting a hierarchically ordered trimodal pore system with a well-defined reverse opal microstructure and bimodal mesoporosity in the walls has been prepared by using polystyrene latex spheres, a novel block copolymer and an ionic liquid surfactant as templates. The resulting materials exhibit hierarchical order at three length scales (small mesopores: 2-3 nm; large mesopores: 11-12 nm; macropores: 360 nm). 相似文献
75.
Based on the theories of nonlinear continuum mechanics, piezoelectricity and elastic waves in solids, theoretical analysis of Bleustein-Gulyaev surface acoustic wave propagation in a prestressed layered piezoelectric structure are described. Numerical calculations are performed for the case that the layer and the substrate are identical LiNbO(3) except that they are polarized in opposite directions. It is found that an almost linear behavior of the relative change in phase velocity versus the initial stress is obtained for both surface electrically free and shorted cases. Potential applications in the design of acoustic wave devices are suggested. 相似文献
76.
Ambrose D Arroyo C Bachman M Connor D Eckhause M Graessle S Hancock AD Hartman K Hebert M Hoff CH Hoffmann GW Irwin GM Kane JR Kanematsu N Kuang Y Lang K Lee R Martin RD McDonough J Milder A Molzon WR Pommot-Maia M Riley PJ Ritchie JL Rubin PD Vassilakopoulos VI 《Physical review letters》2000,84(7):1389-1392
We report results from Experiment 871, performed at the BNL AGS, of a measurement of the branching ratio K(0)(L)-->&mgr;(+)&mgr;(-) with respect to the CP-violating mode K(0)(L)-->pi(+)pi(-). This experiment detected over 6200 candidate &mgr;(+)&mgr;(-) events, a factor of 6 more than that seen in all previous measurements combined. The resulting branching ratio gamma(K(0)(L)-->&mgr;(+)&mgr;(-))/gamma(K(0)(L)-->pi(+)pi(-)) = (3. 474+/-0.057)x10(-6) leads to a branching fraction B(K(0)(L)-->&mgr;(+)&mgr;(-)) = (7.18+/-0.17)x10(-9), which is consistent with the current world average, and reduces the uncertainty in this decay mode by a factor of 3. 相似文献
77.
Lu‐Feng Zou Kuang Shen Yao Fu Qing‐Xiang Guo 《Journal of Physical Organic Chemistry》2007,20(10):754-763
Experimental studies showed that sulfur radicals play the vital role in petroleum formation. 1 Sulfur‐ centered radicals also exhibit activities in antioxidant functions. Here we conduct a theoretical investigation of their precursor‐disulfides. By investigation into substituent effect on sulfur? sulfur bond dissociation enthalpies (S? S BDEs), we would like to find the most effective provider for sulfur radicals. In the present work, 50 alpha‐substituted disulfides and 16 para‐substituted aryl disulfides are studied systematically, with the general formula XS‐SX or HS‐SX. The substituent effect on S? S BDEs is found to be very eminent, ranging from 33.2 to 75.0 kcal/mol for alpha‐substituted disulfide, and from 43.7 to 59.7 kcal/mol for para‐substituted phenyl disulfides. We also evaluate the performance of 44 density functional methods to get an accurate prediction. A further study indicates that substituents play a major role in radical energies, instead of molecule energies, which is substantiated by the good linearity between XS‐SX bond dissociation enthalpy (BDE) and HS‐SX BDE. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
78.
Liu Haiqing Wang Xiangwei Kuang Chunxia Li Lei Zhai Yunyun 《Journal of Solid State Electrochemistry》2018,22(11):3579-3587
Journal of Solid State Electrochemistry - Ionic conductivity is an important separator parameter influencing the cycle life and rate capability of lithium-ion batteries (LIBs). To improve the ionic... 相似文献
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