高效液相色谱法测定萨拉沙星

采用高效液相色谱法测定了萨拉沙星。色谱柱为μ－BondapakTMC18柱（3．9mm×300mm）,流动相为V（乙腈）：V（甲醇）：V（2mmol／L磷酸,用三乙胺调pH3．5）＝30：5：65,用二极管阵列检测器检测,检测波长278nm,得到了满意的分离效果。     

Numerical method of studying nonlinear interactions between long waves and multiple short waves

Although the nonlinear interactions between a single short gravity wave and a long wave can be solved analytically, the solution is less tractable in more general cases involving multiple short waves. In this work we present a numerical method of studying nonlinear interactions between a long wave and multiple short harmonic waves in infinitely deep water. Specifically, this method is applied to the calculation of the temporal and spatial evolutions of the surface elevations in which a given long wave interacts with several short harmonic waves. Another important application of our method is to quantitatively analyse the nonlinear interactions between an arbitrary short wave train and another short wave train. From simulation results, we obtain that the mechanism for the nonlinear interactions between one short wave train and another short wave train (expressed as wave train 2) leads to the energy focusing of the other short wave train (expressed as wave train 3). This mechanism occurs on wave components with a narrow frequency bandwidth, whose frequencies are near that of wave train 3.     

Density functional theory study of AunMn(n=1-8) clusters

Equilibrium geometries, relative stabilities, and magnetic properties of small Au_nMn (n=1-8) clusters have been investigated using density functional theory at the PW91P86 level. It is found that Mn atoms in the ground state Au_nMn isomers tend to occupy the most highly coordinated position and the lowest energy structure of Au_nMn clusters with even n is similar to that of pure Au_n+1 clusters, except for n=2. The substitution of Au atom in Au_n+1 cluster by a Mn atom improves the stability of the host clusters. Maximum peaks are observed for Au_nMn clusters at n=2, 4 on the size dependence of second-order energy differences and fragmentation energies, implying that the two clusters possess relatively higher stability. The HOMO-LUMO energy gaps of the ground state Au_nMn clusters show a pronounced odd-even oscillation with the number of Au atoms, and the energy gap of Au₂Mn cluster is the biggest among all the clusters. The magnetism calculations indicate that the total magnetic moment of Au_nMn cluster, which has a very large magnetic moment in comparison to the pure Au_n+1 cluster, is mainly localized on Mn atom.     

Growth and optical properties of Pr<Superscript>3+</Superscript>:KLu(WO<Subscript>4</Subscript>)<Subscript>2</Subscript> laser crystal: a candidate for red emission laser

A Pr³⁺:KLu(WO₄)₂ crystal with dimension of 30 × 30 × 15 mm³ was grown in the K₂W₂O₇ flux. A slice was cut from the crystal, and the polarized absorption and fluorescence spectra were measured at room temperature. Based on the J-O theory, the oscillator intensity parameters Ω _t (t = 2, 4, 6), spontaneous emission probabilities and branch ratios were estimated and good results had been obtained. Furthermore, the crystal has a relatively large emission cross-section in the region of 615–630 nm with the highest value of 14.5 × 10^?20 cm², which indicates that the crystal is good for the application in red emission laser. The emission decay time for ¹D₂ and ³P₀ multiplets was discussed. By adapting the I-H model to fit the emission decay curves, the lifetime for ¹D₂ at 607 nm and ³P₀ at 615 nm are 19.72 μs and 8.95 μs, respectively. Then the corresponding fluorescence quantum efficiencies of the two multiplets reach 83.7 % and 87.9 %, respectively. All the studies illustrate that this crystal is potential in red emission laser application.     

压电激励圆形曲梁的静态响应及位移控制

研究压电激励圆形曲梁的静态位移响应及位移控制的参数特性。将压电夹层圆形曲梁等效为单层结构,基于一维小曲率曲梁理论,建立其控制方程。在集中弯矩和径向集中力以及电载荷作用下,分析了带压电激励器的圆形悬臂曲梁的静态响应。与有限元结果比较表明:本文的理论模型能够模拟压电激励的小曲率圆形曲梁的静态响应。压电夹层圆形曲梁在任意位置的径向集中力载荷作用下,控制其自由端径向位移响应为零,求得控制电压的解析表达,数值分析表明:随着集中力载荷的位置变化和梁长的变化,最优控制电压将出现峰值和反号。     

纤锌矿结构AlInN电子及光学性质的第一性原理研究

本文通过基于密度泛函理论的第一性原理,研究了纤锌矿结构Al1-xInxN在不同In浓度下的稳固结构,以及电子和光学性质的变化规律。研究表明,AlInN不同In浓度的晶格结构都很稳定,说明AlInN的兼容性很好。晶格常数随In浓度的增大不断增大,而混晶的带隙则不断减小。并且随In浓度的增大,混晶在紫外光区的吸收系数、反射系数及折射率增大,吸收边、吸收峰和反射峰蓝移,且这两个峰的峰值减小。AlInN的吸收、反射和折射率曲线在Eg处出现峰值行为,此Eg处的峰值大小随In浓度的增加而增大。当In浓度达到87.5%时,混晶AlInN在紫外光区的吸收、反射和折射能力均达到最强,表明此时的掺杂效果最好。     

光学条纹相机时间扫描性能应用

对相机全屏扫速性能进行了系统分析,发现基于相机整体的平均扫速及扫速非线性处理扫描时间的传统方法不能反映相机空间畸变现象,并且扫速非线性放大了数据处理不确定度,从而降低了相机应用价值。建立了一套基于全屏扫速及扫速不确定度的扫描时间精细处理方法,它自洽消除了相机的空间畸变和扫速非线性的系统性影响。开展了理论分析和验证实验,结果表明:精细处理方法很容易使扫描时间数据处理相对不确定度降低到1%以内,显著提高了条纹相机时间扫描精度和应用可靠性。     

Indium(III)-catalyzed asymmetric hetero-Diels-Alder reaction of Brassard-type diene with aliphatic aldehydes

A highly diastereo- and enantioselective hetero-Diels-Alder (HDA) reaction of a Brassard-type diene with aliphatic aldehydes has been developed. The chiral N,N'-dioxide L2/In(OTf)(3) complex was efficient toward the obtention of the corresponding β-methoxy-γ-methyl α,β-unsaturated δ-lactones in good yields (up to 86%) as well as dr and ee values (up to 97:3 cis/trans and 94% ee). In addition, the product 4a could be easily transformed into the methyl-protected epi-prelactone B by hydrogenation.     

C-Z type singular integral operators on weighted Herz-type Hardy spaces

The HK _q ^a,p (w₁,w₂) and HK _q ^a,p (w₁, w₂) boundedness of C-Z type singular integral operators are proved.     

光学条纹相机时间扫描性能应用

对相机全屏扫速性能进行了系统分析,发现基于相机整体的平均扫速及扫速非线性处理扫描时间的传统方法不能反映相机空间畸变现象,并且扫速非线性放大了数据处理不确定度,从而降低了相机应用价值。建立了一套基于全屏扫速及扫速不确定度的扫描时间精细处理方法,它自洽消除了相机的空间畸变和扫速非线性的系统性影响。开展了理论分析和验证实验,结果表明:精细处理方法很容易使扫描时间数据处理相对不确定度降低到1%以内,显著提高了条纹相机时间扫描精度和应用可靠性。