A study on anomalous yield drop behaviour in modified beta titanium alloys

ABSTRACT

The yield drop phenomenon observed in the Ti–15V-3Al–3Sn-3Cr (Ti–15–3) beta-titanium alloy and its anomalous behaviour in the boron and carbon added Ti–15–3 alloys have been studied. While the base and the carbon containing alloys exhibit yield drop, the boron containing alloy with smaller grain size than base alloy does not appear to show this phenomenon. Tensile tests were interrupted at different stress levels followed by analyses of slip lines and sub-structural characteristics using scanning and transmission electron microscopes to understand this anomalous yield point phenomenon. Infrared thermal imaging technique was used to map the strain localisation and the spatiotemporal evolution of deformation along the gauge length of the specimens during the tensile tests. Deformation in these alloys initiates only in a few grains. Pile-up of dislocations in these grains subsequently triggers the formation of dislocations in other grains and their rapid multiplications. The spreading of deformation by the generation of dislocations from pile up dislocations in one grain to neighbouring un-deformed grains and their rapid multiplication to new regions influence the yield drop phenomenon and its characteristics. It is shown in this study that microscopic instability in the grain level is a necessary, but not the sufficient condition for the manifestation of macroscopic instability during tensile deformation in polycrystalline materials. The presence of boride particles at grain boundaries restricts the slip transfer across the grains as well as the spreading of deformation to new regions, which causes the suppression of yield drop in the boron containing alloy.     

A porous open-framework titanium oxophenylphosphate

Highly porous titanium oxophenylphosphate (TPP-1) has been synthesized hydrothermally at 448 K using phenylphosphonic acid (PPA) as the organophosphorus source without the aid of any template or structure-directing agent (SDA). Powder XRD, TEM, SEM-EDS, N₂ sorption, ICP-AES chemical analysis, ¹³C and ³¹P MAS NMR, UV-Vis, XPS spectroscopic tools, TG-DTA and NH₃-TPD were used to characterize this material. XRD, N₂ sorption and TEM image analysis suggested the disordered layered framework structure and the presence of large-size micropores along with mesopores in this material. Spectroscopic data suggested the presence of phenyl group, O, Ti and P in this open-framework material, where Ti centers can adopt both tetrahedral and octahedral geometry. TPP-1 showed fairly good H₂ adsorption capacity under normal pressure to high pressure at 77 K. Physisorption data on hydrogen has suggested the potential application of this porous material in H₂ storage.     

Ortho-Alkoxy-benzamide Directed Formation of a Single Crystalline Hydrogen-bonded Crosslinked Organic Framework and Its Boron Trifluoride Uptake and Catalysis

Boron trifluoride (BF₃) is a highly corrosive gas widely used in industry. Confining BF₃ in porous materials ensures safe and convenient handling and prevents its degradation. Hence, it is highly desired to develop porous materials with high adsorption capacity, high stability, and resistance to BF₃ corrosion. Herein, we designed and synthesized a Lewis basic single-crystalline hydrogen-bond crosslinked organic framework (H_COF-50) for BF₃ storage and its application in catalysis. Specifically, we introduced self-complementary ortho-alkoxy-benzamide hydrogen-bonding moieties to direct the formation of highly organized hydrogen-bonded networks, which were subsequently photo-crosslinked to generate H_COFs. The H_COF-50 features Lewis basic thioether linkages and electron-rich pore surfaces for BF₃ uptake. As a result, H_COF-50 shows a record-high 14.2 mmol/g BF₃ uptake capacity. The BF₃ uptake in H_COF-50 is reversible, leading to the slow release of BF₃. We leveraged this property to reduce the undesirable chain transfer and termination in the cationic polymerization of vinyl ethers. Polymers with higher molecular weights and lower polydispersity were generated compared to those synthesized using BF₃ ⋅ Et₂O. The elucidation of the structure–property relationship, as provided by the single-crystal X-ray structures, combined with the high BF₃ uptake capacity and controlled sorption, highlights the molecular understanding of framework-guest interactions in addressing contemporary challenges.     

Spectral engineering and tunable thermoelectric behavior in a quasiperiodic ladder network

Double-stranded quasiperiodic copper mean arrangement has been studied in respect of its electronic property and thermoelectric signature. The two-arm network is demonstrated by a tight-binding Hamiltonian. The eigenspectrum of such aperiodic mesh that does not convey translational invariance, is significantly dependent on the parameters of the Hamiltonian. It is observed that specific correlation between the parameters obtained from the commutation relation between the on-site energy and overlap integral matrices can eventually modify the spectral nature and generate absolutely continuous energy spectrum. This part is populated by atypical extended states that has a large localization length substantiated by the flow of the hopping integral under successive real space renormalization group method steps. This sounds delocalization of single particle energy states in such non-translationally invariant networks. Further this can be engineered at will by selective choice of the relative strengths of the parameters. This precise correlation has a crucial impact on the thermoelectric behavior. Anomalous nature of thermoelectric coefficient may inspire the experimentalists to frame tunable thermo-devices. Specific correlations can help us to tune the continuous band and determine the band position at will.     

Measurement and theoretical estimation of induced activity in <Superscript>nat</Superscript>In by high energy neutrons

Induced radioactivity in natural indium (^natIn) foils by high energy neutrons was measured at the KENS Facility, KEK, Japan, where a 16.7 cm thick W target was bombarded by protons of 500 MeV. High energy neutrons consequently produced irradiated the In targets placed at different depths inside a 4 m thick concrete shield placed at the beam exit. The measured activities were compared with the results calculated using the nuclear reaction model codes ALICE-91 and EMPIRE-2.18. To estimate the induced activity, excitation functions of the various radionuclides were calculated using the two codes and folded with the appropriate neutron energy distribution at different depths of the concrete shield. The calculated excitation functions of a given nuclide were found to vary widely from one another in some cases. The performances of the codes for different input parameters like level densities and inverse cross-sections are reported in this paper. Our analysis shows that neither of the two codes reproduced all the measured activities satisfactorily, requiring further improvements in the models adopted.     

Phase behavior of mixtures of polyoxyethylene(10) stearyl ether (Brij-76), 1-butanol, isooctane, and mixed polar solvents I. Water and formamide (or N,N-dimethyl formamide)

The isothermal phase diagram of the quaternary system polyoxyethylene(10) stearyl ether (Brij-76)/1-butanol/isooctane/water has been constructed at 30 degrees C with equal amounts of oil and water. A regular fishtail diagram was obtained, confirming the establishment of hydrophile-lipophile balance (HLB) in the system. Mixing of formamide (FA) [or N,N-dimethyl formamide (DMF)] with water as a cosolvent altered the HLB and decreased the solubilization capacity of the quaternary system. No three-phase body appeared at high FA or DMF content. Similar observations were noted for temperature-induced phase diagrams. The effect of DMF was more pronounced than that of FA in reducing the maximum solubilization capacity. The results have been summarized on the basis of HLB and mutual solubility of the components.     

Stability of dual solutions in stagnation-point flow and heat transfer over a porous shrinking sheet with thermal radiation

An analysis is carried out to study the steady two-dimensional stagnation-point flow and heat transfer of an incompressible viscous fluid over a porous shrinking sheet in the presence of thermal radiation. A set of similarity transformations reduce the boundary layer equations to a set of non-linear ordinary differential equations which are solved numerically using fourth order Runge-Kutta method with shooting technique. The analysis of the result obtained shows that as the porosity parameter β increases, the range of region of existence of similarity solution increases. It is also observed that multiple solutions exist for a certain range of the ratio of the shrinking velocity to the free stream velocity (i.e., α) which again depends on β. We then discuss the stability of the unsteady solutions about each steady solution, showing that one steady state solution corresponds to a stable solution whereas the other corresponds to an unstable solution. The stable solution corresponds to the physically relevant solution. Further we obtain numerical results for each solution, which enable us to discuss the features of the respective solutions.     

Silver-Gold Nanocomposite Substrates for Metal-Enhanced Fluorescence: Ensemble and Single-Molecule Spectroscopic Studies

In recent years, there has been a growing interest in the studies involving the interactions of fluorophores with plasmonic nanostructures or nanoparticles. These interactions lead to several favorable effects such as increase in the fluorescence intensities, increased photostabilities, and reduced excited-state lifetimes that can be exploited to improve the capabilities of present fluorescence methodologies. In this regard, we report the use of newly developed silver-gold nanocomposite (Ag-Au-NC) structures as substrates for metal-enhanced fluorescence (MEF). The Ag-Au-NC substrates have been prepared by a one-step galvanic replacement reaction from thin silver films coated on glass slides. This approach is simple and suitable for the fabrication of MEF substrates with large area. We have observed about 15-fold enhancement in the fluorescence intensity of ATTO655 from ensemble fluorescence measurements using these substrates. The fluorescence enhancement on the Ag-Au-NC substrates is also accompanied by a reduction in the fluorescence lifetime of ATTO655, which is consistent with the fluorophore-plasmon coupling mechanism. Single-molecule fluorescence measurements have been performed to gain more insight into the metal-fluorophore interactions and to unravel the heterogeneity in the interaction of individual fluorophores with the fabricated substrates. The single-molecule studies are in good agreement with the ensemble measurements and show maximum enhancements of ~50-fold for molecules located in proximity to the "hotspots" on the substrates. In essence, the Ag-Au-NC substrates have a very good potential for various MEF applications.     

Magnetohydrodynamic stagnation-point flow of a power-law fluid towards a stretching surface

Steady two-dimensional stagnation-point flow of an electrically conducting power-law fluid over a stretching surface is investigated when the surface is stretched in its own plane with a velocity proportional to the distance from the stagnation-point. We have discussed the uniqueness of the solution except when the ratio of free stream velocity and stretching velocity is equal to 1. The effect of magnetic field on the flow characteristic is explored numerically and it is concluded that the velocity at a point decreases/increases with increase in the magnetic field when the free stream velocity is less/greater than the stretching velocity. It is further observed that for a given value of magnetic parameter M, the dimensionless shear stress coefficient |F^″(0)| increases with increase in power-law index n when the value of the ratio of free stream velocity and stretching velocity is close to 1 but not equal to 1. But when the value of this ratio further differs from 1, the variation of |F^″(0)| with n is non-monotonic.