全文获取类型
收费全文 | 778篇 |
免费 | 16篇 |
国内免费 | 3篇 |
专业分类
化学 | 485篇 |
晶体学 | 6篇 |
力学 | 25篇 |
数学 | 100篇 |
物理学 | 181篇 |
出版年
2022年 | 16篇 |
2021年 | 13篇 |
2019年 | 11篇 |
2018年 | 22篇 |
2017年 | 27篇 |
2016年 | 18篇 |
2015年 | 14篇 |
2014年 | 24篇 |
2013年 | 55篇 |
2012年 | 35篇 |
2011年 | 33篇 |
2010年 | 25篇 |
2009年 | 26篇 |
2008年 | 30篇 |
2007年 | 25篇 |
2006年 | 19篇 |
2005年 | 14篇 |
2004年 | 15篇 |
2003年 | 12篇 |
2002年 | 18篇 |
2001年 | 7篇 |
2000年 | 11篇 |
1999年 | 6篇 |
1997年 | 7篇 |
1995年 | 6篇 |
1993年 | 9篇 |
1992年 | 6篇 |
1991年 | 5篇 |
1990年 | 7篇 |
1989年 | 7篇 |
1988年 | 6篇 |
1987年 | 9篇 |
1986年 | 7篇 |
1985年 | 10篇 |
1984年 | 15篇 |
1983年 | 5篇 |
1982年 | 6篇 |
1981年 | 9篇 |
1980年 | 15篇 |
1979年 | 15篇 |
1978年 | 13篇 |
1977年 | 20篇 |
1976年 | 6篇 |
1975年 | 5篇 |
1974年 | 14篇 |
1973年 | 10篇 |
1972年 | 9篇 |
1971年 | 8篇 |
1957年 | 7篇 |
1954年 | 7篇 |
排序方式: 共有797条查询结果,搜索用时 31 毫秒
31.
Debprasad Patra Poulami Pattanayak Jahar Lal Pratihar Surajit Chattopadhyay 《Polyhedron》2007,26(18):5484-5490
The reactions of HL 1 [where HL is 1N-(2-pyridyl-2-methyl)-2-arylazoaniline and is formulated as ArN = NC6H4N(H)(CH2C5H4N); Ar = C6H5 (for HL1) or p-MeC6H4 (for HL2) or p-ClC6H4 (for HL3)] with K2PtCl4 and Co(ClO4)3 · 6H2O afforded the (L)PtCl and [(L)2Co]ClO4 complexes, respectively. The HL ligands bind the platinum(II) and cobalt(III) centres in a tridentate (N,N,N) fashion, forming new diazoketiminato chelates upon dissociating the amino proton. The X-ray structures of (L3)PtCl and [(L3)2Co]ClO4 were determined. Redox properties of the new complexes have been examined. 相似文献
32.
Chloramine-T has been used as an oxidizing agent in hydrochloric acid medium' for the volumetric estimations of potassium iodide, hydrazine sulphate, arscnious oxide, stannous chloride, mercurous chloride, tartar-emetic, potassium thiocyanate and ferrous ammonium sulphate, using iodine monochloride as a catalyst and pre-oxidizer. Chloroform is used as an indicator. It is coloured pink owing to the liberation of iodine during the titration and becomes very pale yellow at the end-point because of the formation of iodine monochloride. 相似文献
33.
Pier Luigi BuldiniJawahar Lal Sharma 《Microchemical Journal》2002,72(3):277-284
An ion chromatographic method has been developed for the determination of some microelements in different types of milk. It involves oxidative photodegradation of the organic matrix with H2O2 in a UV digester, equipped with a high-pressure mercury lamp. The temperature of the sample is maintained at 85±5 °C by a combined air/water cooling system. This procedure provides an efficient alternative to traditional dry ashing and wet digestion methods. Milk degrades in less than 2 h, while inorganic constituents, except for iodide, nitrate, nitrite, sulfite and manganese (II), are unaffected by UV radiation. Depending upon the type of milk (whole, skimmed, powdered, evaporated, etc.) to be analysed, the amount of sample and the UV photolysis time can be adjusted as per requirements. The clear solution resulting from the UV digestion is diluted, filtered and injected onto an ion chromatograph equipped with both conductivity and variable-wavelength UV-Vis detectors. The method has been tested with standards and real milk samples and has been found to be satisfactory for the determination of total chloride, bromide, phosphorus (as phosphate) and sulfur (as sulfate), and of copper, nickel, zinc, cobalt, iron and lead. 相似文献
34.
A. Malki J. P. Coffin G. Guillaume F. Jundt K. Krishan F. Rami P. Wagner P. Fintz M. Zahar M. Gonin B. Heusch M. Ohta B. Rastegar D. Rebreyend F. Merchez J. Mistretta S. Kox 《Zeitschrift für Physik A Hadrons and Nuclei》1991,339(2):283-292
In an attempt to separate preequilibrium and thermalised emissions of light particles in low impact parameter heavy-ion collisions, the40Ar+24Mg reaction has been studied at 27.5 MeV/nucleon. Exclusive measurements have permitted us to examine, in some detail, heavy fragments and charged particles (p, d, t,-particle). The fragments recognized as evaporation residues have been selected and, due to inverse kinematic conditions, the related preequilibrium and statistical emissions of light particles resulting from incomplete fusion reaction appear to be distinguishable to a fair extent. This separation is fully supported by Monte Carlo calculations. Some experimental characteristics of the light particles have been examined and compared to the predictions of dynamical calculations. These calculations, associating a preequilibrium (interpreted as prompt emitted particles) model with a statistical-decay model, follow the evolution of the collision from the point of contact between the projectile and the target to the final evaporation-residue formation on an event by event basis. The predictions of these calculations have been compared to experimental data and satisfactory agreement is achieved for fragment-mass distribution, proton-energy spectra, and proton-angular distribution. 相似文献
35.
Summary
N-benzamidosalicylaldimine (H2L) complexes of CuII, NiII, CoII, FeII, MnII. VOIV and TiOIV have been prepared. The ligand probably coordinates to the metal from the hydroxyl, carbonyl and imino groups. 相似文献
36.
Zusammenfassung Es wurde das polarographische Verhalten von Indium(III) in verschiedenen Nitraten in Abhängigkeit von der Konzentration untersucht. Die Ergebnisse wurden unter besonderer Beachtung der Faktoren Viskosität, Diffusionskoeffizienten und Ionensolvatation interpretiert. Die scheinbaren Geschwindigkeitskonstanten wurden nach dem Verfahren vonDelahay bestimmt und ein quasireversibles Verhalten festgestellt.
An den allfällige Korrespondenz zu richten ist. 相似文献
Polarography of indium(III) in alkali and alkaline earth nitrates
Polarographic behavior of Indium(III) in several nitrates of varying concentrations has been studied and resuts interpreted in the light of factors viscosity, diffusion coefficients and ion solvation. The apparent rate constants were determined byDelahay's treatment which revealed its quasireversible behavior.
An den allfällige Korrespondenz zu richten ist. 相似文献
37.
Lal Sohan Arora Sanjiv Kumar Vinod Rani Shikha Sharma Chetan Kumar Parvin 《Journal of Thermal Analysis and Calorimetry》2018,132(3):1707-1716
Journal of Thermal Analysis and Calorimetry - The synthesis of Schiff bases of chitosan is performed by the reaction of chitosan with different heteroaryl aldehydes, i.e., furfuraldehyde,... 相似文献
38.
39.
A symmetric monoidal category naturally arises as the mathematical structure that organizes physical systems, processes, and composition thereof, both sequentially and in parallel. This structure admits a purely graphical calculus. This paper is concerned with the encoding of a fixed causal structure within a symmetric monoidal category: causal dependencies will correspond to topological connectedness in the graphical language. We show that correlations, either classical or quantum, force terminality of the tensor unit. We also show that well-definedness of the concept of a global state forces the monoidal product to be only partially defined, which in turn results in a relativistic covariance theorem. Except for these assumptions, at no stage do we assume anything more than purely compositional symmetric-monoidal categorical structure. We cast these two structural results in terms of a mathematical entity, which we call a causal category. We provide methods of constructing causal categories, and we study the consequences of these methods for the general framework of categorical quantum mechanics. 相似文献
40.
On irradiation with sunlight N-α-cyanoamines (I) undergo a novel cyclisation with the induction of one methylene group from the solvent (methanol) to give new benzoimidazoloquinolines (II) in good yield. 相似文献