Supramolecular Wiring of Benzo‐1,3‐chalcogenazoles through Programmed Chalcogen Bonding Interactions

The high‐yielding synthesis of 2‐substituted benzo‐1,3‐tellurazoles and benzo‐1,3‐selenazoles through a dehydrative cyclization reaction has been reported, giving access to a large variety of benzo‐1,3‐chalcogenazoles. Exceptionally, these aromatic heterocycles proved to be very stable and thus very handy to form controlled solid‐state organizations in which wire‐like polymeric structures are formed through secondary N???Y bonding interactions (SBIs) engaging the chalcogen (Y=Se or Te) and nitrogen atoms. In particular, it has been shown that the recognition properties of the chalcogen centre at the solid state could be programmed by selectively barring one of its σ‐holes through a combination of electronic and steric effects exerted by the substituent at the 2‐position. As predicted by the electrostatic potential surfaces calculated by quantum chemical modelling, the pyridyl groups revealed to be the stronger chalcogen bonding acceptors, and thus the best ligand candidate for programming the molecular organization at the solid state. In contrast, the thiophenyl group is an unsuitable substituent for establishing SBIs in this molecular system as it gives rise to chalcogen–chalcogen repulsion. The weaker chalcogen donor properties of the Se analogues trigger the formation of feeble N???Se contacts, which are manifested in similar solid‐state polymers featuring longer nitrogen–chalcogen distances.     

Free molecular sound propagation

The sound propagation through a gas in the free-molecular regime is studied on the basis of the linearized collisionless Boltzmann equation. The two principal quantities that characterize the sound propagation, namely the phase and amplitude of the perturbation, are determined by taking into account the influence of the receptor. It is shown that at a small distance between the source and the receptor the presence of the last changes qualitatively the sound characteristics. Two phase velocities are introduced: a differential and an integral, which are different in the free molecular regime.     

On Relativistic Collisional Invariants

Two simple proofs of the result that a relativistic summational invariant is a linear combination of the momentum four-vector p are given by assuming that is a continuous and differentiable function of class C ². The results can be extended to the case when is just assumed to be a generalized function.     

Low-energy behavior of the 3He(α, γ)7Be cross section

Cross sections for the ³He(α, γ)⁷Be reaction have been measured at several energies from E_c.m. = 165 to 1169 keV by counting prompt γ-rays from a windowless, differentially pumped, recirculating, ³He gas target. The cross-section factor S₃₄(E_c.m.) and branching ratio γ₁/γ₀ were determined at each energy. Cross sections were also measured at E_c.m. = 947 and 1255 keV by counting the γ-rays from the ⁷Be produced in a ³He gas cell with a Ni entrance foil. Combining the results of these two independent experiments yields a zero-energy intercept for the cross-section factor of S₃₄(0) = 0.53 ± 0.03 keV · b. The relationship between these measurements and several theoretical calculations, and the import of the extrapolated cross section for the solar-neutrino problem are discussed.     

Strain-induced reorientation and mobility in nematic liquid-crystalline elastomers as studied by time-resolved FTIR spectroscopy

Polarized Fourier transform infrared (FTIR) spectroscopy is employed to study the segmental orientation and mobility of liquid-crystalline elastomers (LCEs) with a monodomain structure in response to external mechanical fields parallel and perpendicular to the initial nematic director. The mean orientation and the molecular order parameter of the different molecular moieties referring to the mesogen, the spacer and the network are analyzed in detail. Parallel stretch leaves the mean orientation of the different molecular moieties and its molecular order parameter nearly uninfluenced. Perpendicular stretch results in a threshold-like dependence: for elongation ratios λ ⩽ λ_c = 1.3 (10 mol% crosslinker density), respectively λ ⩽ λ_c = 1.6 (5 mol% crosslinker density) no change of the mean orientation and the molecular order parameters is observed, while for λ ≥ λ_c all molecular units reorient and their molecular order parameters are strongly decreased. The present studies give no indications that the reorientational dynamics of the network and the mesogens differ as long as the elongation ratio is smaller than λ_c.     

Multi-echo imaging in highly inhomogeneous magnetic fields

A new pulsed field gradient multi-echo imaging technique to encode position in the phase of every echo generated by a CPMG sequence in the presence of a strongly inhomogeneous static magnetic field is presented. It was applied to improve the sensitivity in an imaging experiment by adding the echo train acquired during the CPMG sequence and to spatially resolve relaxation times of inhomogeneous specimens using single-sided probes. The sequence was implemented in a new bar-magnet MOUSE equipped with a gradient coil system to apply a pulsed magnetic field with a constant gradient along one spatial coordinate. An important reduction by a factor larger than two orders of magnitude in the acquisition time was obtained compared to the previously published single-point imaging technique.     

Strong attraction between charged spheres due to metastable ionized states

We report a mechanism which can lead to long-range attractions between like-charged spherical macroions, stemming from the existence of metastable ionized states. We show that the ground state of a single highly charged colloid plus a few excess counterions is overcharged. For the case of two highly charged macroions in their neutralizing divalent counterion solution we demonstrate that, in the regime of strong Coulomb coupling, the counterion clouds are very likely to be unevenly distributed, leading to one overcharged and one undercharged macroion. This long-living metastable configuration in turn leads to a long-range Coulomb attraction.     

Green light generation in a periodically poled Zn-doped LiNbO3 planar waveguide fabricated by He+ implantation

An optical planar waveguide is investigated in ZnO-doped periodically poled lithium niobate formed by He⁺ implantation. Optical losses were found to be 2 dB/cm. Second-harmonic generation is used to produce a green laser beam by quasi-phase matching in the obtained waveguide. The conversion efficiency was found to be 10^-2%/W. Photorefractive resistance properties are reported and discussed relating to un-doped periodically poled lithium niobate. PACS 42.65.-k; 42.65.Wi; 42.82.-m