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101.
102.
A. Ya. Vainer K. M. Dyumaev A. M. Kovalenko A. V. Vishnyakov K. I. Zelikson Sh. N. Sukharskaya 《Doklady Chemistry》2017,477(1):235-238
A new strategy was proposed for the synthesis of fluorene-containing indole polyphenols, based on the Suzuki–Miyaura reaction of hexabrominated symmetric indole trimer with the monoboryl N,N'-di[9,9'-bis(3',5'-dimethoxybenzyl)fluoren-2'-yl]aniline derivative and subsequent chemical transformations. The prepared compound was applicable for the development of a promising positive resist for electron-beam nanolithography capable of forming patterns with a 12 nm resolution. 相似文献
103.
A. R. Khamatgalimov V. I. Kovalenko 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2010,84(4):636-641
Quantum chemical calculations of electronic and geometric structures were performed for molecules of 24 isomers of C84 fullerenes obeying the isolated pentagons rule. The reasons for the instability of isomers not obtained experimentally were established, and the possibility of obtaining some of them was proven. It was shown that the deformation of hexagons and pentagons is the most important geometric parameter directly connected with the thermodynamic instability of fullerenes having closed shells, reflecting the local strain of the molecules. 相似文献
104.
Elena E. Zvereva Sergey A. Katsyuba Alexander E. Vandyukov Alla V. Chernova Valery I. Kovalenko Svetlana E. Solovieva Igor S. Antipin Alexander I. Konovalov 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2010,75(2):872-879
It is demonstrated that dissolution of aminothiacalix[4]arene in chloroform results in transformation of 1,3-alternate conformation, adopted in single-crystal and bulk polycrystalline solids, to the pinched-cone form. This conformer is stabilised by the intramolecular hydrogen bonds of two distal amino-groups acting as H-donors with another two amino moieties that appear as H-acceptors. The H-bonds cause quite small (ca. 10–20 cm?1) red shift of the IR bands of the NH2 stretching vibrations, which suggests rather weak NH?N hydrogen bonding. This latter is sufficient to stabilize the pinched-cone conformation in the chloroform solution, but the energy gap between the pinched-cone and other conformations is small, and solid-state intermolecular forces easily overcome it, leading to realisation of the 1,3-alternate conformer. The comparison of the DFT computed and experimental vibrational and NMR spectra demonstrates good quality of present quantum-chemical computations, allows complete interpretation of the spectra and reveals simple IR and NMR spectroscopic markers of the conformers of aminothiacalix[4]arenes. 相似文献
105.
O. A. Bezshyyko A. N. Vodin L. O. Golinka-Bezshyyko A. M. Dovbnya I. N. Kadenko A. O. Kivernyk A. A. Kovalenko V. A. Kushnir A. I. Levon V. V. Mitrochenko S. M. Olejnik G. E. Tuller 《Bulletin of the Russian Academy of Sciences: Physics》2011,75(7):941-945
The isomer ratios for nuclei 104m,g Ag, 110m,g In, 108m,g In as products of the photonuclear reactions 107Ag(γ, 3n)104m,g Ag, 113In(γ, 3n)110m,g In, 109Ag(γ, 5n)104m,g Ag, 115In)(γ, 5n)110m,g In, 115In(γ, 7n)108m,g In are obtained. The Bremsstrahlung of electrons with energies within 32–84 MeV from the LU-40 linear accelerator was used for the irradiation of targets. The energy resolution and mean current of the electron beam were ~1% and 5 μA, respectively. The induced activity was used to obtain experimental isomer ratios. An HPGe spectrometer with an energy resolution of 1.9 keV for 60Co γ-line 1332 keV was used to acquire the instrumental γ-ray spectra of the activation products. A set of serial measurements with various acquisition times was performed. The cooling times varied from 5 seconds to several hours for Ag and up to tens of hours for In specimens. The obtained experimental isomer ratios are compared with the results from theoretical calculations. 相似文献
106.
I. Gnesi N. Angelov M. Artoni S. Baginyan F. Balestra Yu. Batusov P. Batyuk I. Belolaptikov A. Bianconi T. Blokhintseva M. Chiosso M. L. Colantoni M. Corradini A. Dem’yanov V. Drozdov V. Frolov R. Garfagnini A. Grasso V. Grebenyuk V. Ivanov A. Kirilov V. Kovalenko E. Lodi Rizzini V. Lyashenko A. Maggiora A. Moiseenko V. Panyushkin D. Panzieri B. Parsamyan G. Piragino G. Pontecorvo A. Rozhdestvensky N. Russakovich E. Scalas M. Schepkin F. Tosello L. Venturelli G. F. Zosi 《The European Physical Journal A - Hadrons and Nuclei》2011,47(1):1-10
107.
Numerical simulation of radio energy transfer in the ionospheric layer with random small-scale irregularities for the case of a point ground-based source and total reflection has been carried out using a specially designed algorithm based on Monte Carlo method ideas. The model demonstrates a redistribution of the reflected radiation power at the Earth's surface caused by multiple scattering. The data obtained can serve as confirmation of the effect of the anomalous attenuation of the signal power in the vicinity of the sounder. This result is in agreement with a more rigorous theory of the anomalous attenuation effect based on the solution of the radiative transfer equation. 相似文献
108.
109.
Radiophysics and Quantum Electronics - 相似文献
110.
Mitchenko S. A. Khomutov E. V. Kovalenko V. V. Beletskaya I. P. 《Kinetics and Catalysis》2002,43(4):469-474
Mechanochemical treatment of solid-phase K2PtX6 salts in a vibrating mill in an argon or air atmosphere produced paramagnetic Pt(III) complexes via the homolytic cleavage of the Pt–X bond. Lewis acid sites were found on the surface of the mechanically activated K2PtCl6 salt using the paramagnetic probe method. The sites can be attributed to coordinatively unsaturated Pt(IV) complexes formed via Pt–Cl bond heterolysis. 相似文献