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171.
Takashi Iizawa Haruo Ono Kouji Okatome 《Journal of polymer science. Part A, Polymer chemistry》1996,34(12):2407-2414
Soluble polymeric phase transfer catalysts (PTCs) containing benzyltributylphosphonium chloride moieties and polar N,N-dialkyl-acrylamide with long alkyl groups such as N,N-dipropylacrylamide, N,N-dibutylacrylamide, N,N-dihexylacrylamide, and N,N-dioctylacrylamide were prepared via two-step reactions from p-chloromethylstyrene and the corresponding N,N-dialkylacrylamide. When the obtained polymers were added, the phase transfer catalyzed reaction of benzylchloride with solid potassium acetate to proceed smoothly. The catalytic activity was strongly affected by the content of phosphonium chloride and the varieties of comonomer unit in the polymeric PTC. The polymeric PTC containing the N,N-dihexylacrylamide unit showed excellent high catalytic activity in a low polar solvent such as the mixed solvent of toluene with 70 vol % n-tridecane. Therefore, the polymer containing lipophilic long chains such as the hexyl group is desirable for polymeric PTC. © 1996 John Wiley & Sons, Inc. 相似文献
172.
Takeshi Fukuda Kouji Fujimoto Mauro M. Murakami Kenji Kawabata Takeaki Miyamoto 《Macromolecular Symposia》1996,101(1):147-155
Three co-operative phenomena that are supposed to originate in the orientation-dependent interactions among polymer segments are discussed and attempted to be interpreted in terms of a common set of polymer models. 相似文献
173.
Kouji Maeda Akira Sonoda Hideo Miki Yusuke Asakuma Keisuke Fukui 《Crystal Research and Technology》2004,39(11):1006-1013
Single potassium dihydrogen phosphate (KDP) crystals were grown in a supersaturated solution containing an organic dye (sunset yellow FCF, brilliant blue FCF, and sky blue). The growth rate, morphology, and impurity dye distribution of faces, (100) and (101) in a KDP crystal were measured as dye concentration and the supersatutation of KDP were changed. Complete expressions for the effect of dye on all aspects of the growth of KDP crystals were discussed. The growth rates of (100) and (101) faces were well correlated by the empirical equation, and resulted in good estimation of the morphology. The distribution of dye in a KDP crystal was represented by the distribution model containing the minimum growth rate for coloring. The growth rate equation and distribution equation were expressed by functions of the supersaturation and dye concentration, and they could effectively provide the operational conditions with coloring the KDP crystal. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
174.
Ho-Hi Lee Kouji Kimura Takatomo Takai Hitoshi Senda Akio kuwae Kazuhiko Hanai 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》1999,55(14):2877
Polymorphs I and II of phenylpyruvic acid are obtained as mixtures of both crystal forms or relatively pure crystals, from different solvents. Polymorph I is more stable than polymorph II at room temperature. Spectral characteristics of these polymorphs are discussed on the basis of IR, Raman and solid state 13C NMR spectra. Also, the assignment of the IR features observed in the 1600–1700 cm−1 region is re-investigated by referring to the spectra of heavy-atom substituted derivatives. It is suggested that the C=O stretching band is split by the crystal field for both polymorphs. 相似文献
175.
Kiyoshi Tanaka Makoto Deguchi Satoru Yamaguchi Kouji Yamada Satoru Iwata 《Journal of heterocyclic chemistry》2001,38(1):131-136
2‐(3,4,5,6‐Tetrafluoro‐2‐hydroxyphenyl)benzoxazole ( 2 ) emits the long wavelength fluorescence around 500 nm in nonpolar solvent via the intramolecular proton transfer process in the excited state of 2 (enol‐form) and also emits the intermediate wavelength fluorescence around 440 nm in polar solvent, which is assumed to originate from the excited state of 2 (anion). The ease of formation of 2 (anion), compared to 2‐(2‐hydroxyphenyl)benzoxazole ( 1 ), is explained by the strongly inductive fluorine atoms. In a solvent with the intermediate polarity, 2 emits both fluorescences and their relative intensity is dependent on the concentration of 2 , which is supposed to be caused by the high sensitivity of the intermediate wavelength emission to the concentration quenching. 相似文献
176.
We report a facile method for preparing enamides, based on the Curtius rearrangement and acylation of alkenylcarbamate. Using this approach, total syntheses of coscinamides, chondriamides, and igzamide were achieved. 相似文献
177.
Shoji Ando Haruhiko Aoyagi Michinori Waki Tetsuo Kato Nobuo Izumiya Kouji Okamoto Michio Kondo 《Tetrahedron letters》1982,23(21):2195-2198
Gramicidin S (GS) analogs, (D-Ser(Bzl)4,4′]-GS (), [D-Ser4,4′]-GS (), and [L-Orn(Boc)2,2′,D-Ser4,4′]-GS () were synthesized and showed high antibacterial activity. One residue of D-Ser in was converted asymmetrically to D-Ala via α,β-dehydroalanine. 相似文献
178.
Iida K Inagaki J Shinohara K Suemori Y Ogawa M Dewa T Nango M 《Langmuir : the ACS journal of surfaces and colloids》2005,21(7):3069-3075
The subunit light-harvesting 1 (LH 1) complexes isolated from photosynthetic bacteria Rhodospirillum rubrum using n-octyl-beta-glucoside were reassociated and adsorbed on a mica substrate using spin-coat methods with the aim of using this LH complex in a nanodevice. The near-IR absorption and fluorescence spectra of the LH 1 complexes indicated that the LH 1 complex on the mica was stable, and efficient energy transfer from a carotenoid to a bacteriochlorophyll a was observed. Atomic force microscopy of the reassociated LH 1 complexes, under air, showed the expected ringlike structure. The outer and inner diameters of the ringlike structure of the LH 1 complex were approximately 30 and 8 nm, respectively, and the ringlike structure protruded by 0.2-0.6 nm. 相似文献
179.
Unicellular thermophilic cyanobacterium Synechococcus elongatus displayed phototaxis on agar plate at 55 degrees C. Equal-quantum action spectra for phototactic migration were determined at various fluence rates using the Okazaki Large Spectrograph as the light source. The shapes of the action spectra drastically changed depending on the fluence rate of the unilateral monochromatic irradiation: at a low fluence rate (3 mumol/m2/s), only lights in the red region had significant effect; at a medium fluence rate (10 mumol/m2/s), four major action peaks were observed at 530 nm (green), 570 nm (yellow), 640 nm (red) and 680 nm (red). At high fluence rates (30-90 mumol/m2/s), the former two peaks remained, while red peaks at 640 nm and 680 nm disappeared and, interestingly, an action peak around 700-740 nm (far-red) newly appeared. These results indicate that two or more distinct photoreceptors are involved in the phototaxis and that suitable photoreceptors are selectively active in response to the stimulus of light fluence rates. Far-red or red background lights irradiated vertically from above drastically inhibited phototaxis toward red light or far-red light, respectively. These results indicate involvement of some phytochrome(s). 相似文献
180.
In our investigation of a cell proliferation-based screening assay using human ligand-dependent cell lines for medicinal herbal extracts, the acetone extract of the whole plants of Euphorbia lunulata (EL) was observed for its proliferation activity for insulin- and interleukin-10 (IL-10)-dependent cell lines. Fractionation of the active extract led to the isolation of one new flavonoid galactoside, quercetin 3-O-(2',3'-digalloyl)-beta-D-galactopyranoside (1), and four known ones, quercetin 3-O-(2'-galloyl)-beta-D-galactopyranoside (2), hyperin (3), quercetin (4), and gallic acid (5). Compounds 1 and 2 showed insulin-like activity. Compounds 4 and 5 showed IL-10-like activity. This is the first report of these activities of EL, and 1 and 2 will become the seed compounds for the development of a nonpeptidyl insulin substitutional medicine. Compounds 4 and 5 support the pharmacological use of EL, which has been employed as an herbal medicine for the treatment of bronchial asthma. 相似文献