固体力学中侵入问题的若干新进展

本文主要介绍了固体力学中侵入问题近10余年来的发展情况。重点综述了侵入断裂实验及理论研究的新成果;讨论了动静态侵入断裂的关系;简述了侵入方法在测定材料断裂韧性方面的应用。      

Photonic bandgap via nonlinear modulation assisted by spontaneously generated coherence

A four-level double-ladder atomic system with two upper states coupled to the excited state by a standing-wave trigger field is explored to generate photonic bandgap (PBG) structure. With the assistance of spontaneously generated coherence (SGC) from the two decay pathways, we can obtain single or double fully developed PBG when the trigger field is far away from resonance or resonant. While in the absence of SGC, the atomic medium becomes strong absorptive to the probe field, and therefore the resulting PBGs are severely malformed or even cannot be opened up. Numerical results show that the PBG structure is originated from the third-order cross Kerr nonlinear modulation between the probe and trigger fields. This mechanism differs from the recent schemes based on linear modulation.     

The characters of self-assembly core/shell nanoparticles of amphiphilic hyperbranched polyethers as drug carriers

The characters of self-assembly core/shell nanoparticles of amphiphilic hyperbranched polyethers (HP-g-PEO) as drug carriers were investigated. The HP-g-PEO consisting of hydrophobic HP-g-PEO core and hydrophilic poly(ethylene glycol) arms was prepared by the cation ring-opening polymerization. A series of HP-g-PEO samples with different degree of branching (DB) were synthesized under various reaction temperatures. Nanoparticles (NP) were obtained by self-assembly of HP-g-PEO in aqueous media. The structure of resulting HP-g-PEO was characterized by IR, ¹³CNMR and GPC. Dynamic light scattering and transmission electron microscopy were applied to characterize the sizes and size distributions of NP. The results demonstrated that the mean diameters of NP were less than 100 nm, which exhibited uniform spherical formations and narrow size distributions. Using hydrophobic drug Probucol (PRO) as model drug, the particle sizes of drug loaded NP were larger than relative blank NP. The drug loading efficiency (LE) and incorporation efficiency (IE) of these NP were achieved to 35 and 89%, respectively. The in vitro release of PRO from the NP exhibited a sustained release and the cumulative drugs released for more than 600 h. The most important factor to affect drug release was the value of DB of HP-g-PEO. With the DB of HP-g-PEO increasing, the size and size distribution of NP decreased as well as the release rate. However, the small DB was beneficial to the LE of NP. Nanoparticle size and size distribution, LE, IE, and drug release rate were slightly affected by the initial solution concentration of polyethers. The co-incorporated hydrophilic drug had influence slightly on the release of drug from drug loaded NP. The results of in vitro drug release suggested that the core/shell NP performed good controlled release behaviors with potential practice as novelty drug delivery vehicles.     

Experimental Study of a High Power Coupler for a Tunable Cavity Formed by a Vane-Type Structure

In this study, a high power coupler designed for a tunable planar cavity is experimentally tested. The cavity consists of a periodical vane-type structure, of which the height of the vane can be mechanically adjusted so that the resonance frequency can be fine tuned. The cavity is designed to be operated at mode and resonant at 2.45 GHz. The high power coupler is composed of a rectangular waveguide and a cylindrical ceramic rod with tapered ends. One end of the ceramic rod is intruded into the gap between two vanes of the cavity. Through this coupler, the TE₁₀ mode of the rectangular waveguide is converted into the TE₁₁ mode of the ceramic rod and then couples to the TEM mode in the gap between vanes of the cavity. Experimental results show that a microwave power up to 5 kW can be effectively transmitted to excite the mode of the cavity . This cavity can be used to excite large area plasmas     

Quantitative enantiomeric analysis of chlorcyclizine,hydroxyzine, and meclizine by capillary electrophoresis

A simple capillary zone electrophoresis method was developed for the quantitative enantiomeric analysis of piperazine antihistamines with teratogenic suspicion in animals. Enantioseparation of chlorcyclizine, hydroxyzine, and meclizine was performed in glycine buffer (0.6 mol L^-1; pH 3.00) with sulfated -cyclodextrin (5 mg mL^-1) as a chiral selector; and the separated drugs were monitored by ultra-violet detector. The lower quantitation of the individual enantiomer is attainable at 10 µmol L^-1, using an achiral piperazine drug (cyclizine) as internal standard. The method is simple and rapid with a short run time (<5 min) for the analysis of chlorcyclizine, hydroxyzine or meclizine enantiomers.     

Line Intensities of (12)C(16)O(2) in the 1.2-1.4 µm Spectral Region

The 7000-8500 cm(-1) spectral region of (12)C(16)O(2) has been investigated using the high-resolution FT spectrometer of LPPM in Orsay. The two strongest bands in this region are the 10031 <-- 00001 and 10032 <-- 00001 bands centered at 8294 and 8192 cm(-1). Line intensities in these two bands and in the 40013 <-- 00001 and 40014 <-- 00001 bands have been measured. Using the method of effective operators, these line intensities have been included in a new fit of effective dipole-moment parameters to all available experimental data in the same spectral region of (12)C(16)O(2). The corresponding calculated line intensities of the 10031 <-- 00001 and 10032 <-- 00001 bands are compared with the experimental ones. Copyright 2000 Academic Press.     

Synthesis and crystal structures of silver(I) complexes of 3(5)-methyl-5(3)-phenyl-1<Emphasis Type="Italic">H</Emphasis>-1,2,4-triazole: two isomeric infinite chains coexisting in the same crystal

Reactions of 3(5)-methyl-5(3)-phenyl-1H-1,2,4-triazole (3-Me-5-Ph-tzH) with AgNO₃ in the absence/presence of NH₃ yield a mononuclear [Ag(3-Me-5-Ph-tzH)₂]NO₃·3H₂O (1) and a polymeric [Ag(3-Me-5-Ph-tz)]_n (2), respectively. Two structurally different infinite chains, however, with the same formula of AgC₉H₈N₃—one is double-decked and the other single zigzag—coexist in 1:1 ratio in the crystal of 2. As far as we know, 2 is the first binary silver(I) complex based on an asymmetric triazole and represents a rare case of two supramolecular isomers coexisting in the same crystal.