Dependence of the energy of surface-active substances/metal interaction on their ionization potentials. Evaluation of hydrophilicity of metal

The function Δ(ΔG _A ⁰), which is the difference of Gibbs energies characterizing surface-active substance (surfactant, SAS) adsorption at metal/solution and air/solution surfaces, has been introduced. The equation connecting the function Δ(ΔG _A ⁰) with SAS ionization potential has been obtained using the elementary theory of donor-acceptor interactions. Published experimental data on SAS adsorption at mercury, bismuth and gold have been used for Δ(ΔG _A ⁰) calculation. The dependence of Δ(ΔG _A ⁰) on ionization potentials can be described by an equation derived in this work. It has been demonstrated that the value of the hydrophilicity of gold is much higher than the values for mercury and bismuth. The lifetime of SAS molecules at a metal surface has been estimated. The question of the possibility of theoretica l estimation of standard energies ΔG _A ⁰ characterizing SAS adsorption at a metal/solution surface has been discussed. Received: 9 December 1996 / Accepted: 13 January 1997     

Self-assembly of C60 fullerenes on quasi-one-dimensional Si(111)4 × 1-In surface

Using scanning tunneling microscopy observations, self-assembly of C₆₀ fullerenes in the course of room-temperature adsorption onto Si(111)4 × 1-In reconstruction and after subsequent annealing at temperatures ranging from 150 to 450 °C has been studied. Adsorbed C₆₀ fullerenes have been found to occupy off-centered positions on In-atom rows forming linear chains with a maximal length of eight C₆₀ molecules. Intermolecular spacing within the regular chains equals three lattice constants of Si(111) surface. Two energetically different adsorption states of C₆₀ have been detected, one of which is occupied preferentially at room temperature, while occupation of the second (more tight) state dominates at temperature above ~ 150 °C. In the first state, C₆₀ fullerene resides plausibly in a continuous rotation, while in the second state a C₆₀ molecule is fixed tightly in a single orientation with a C₆₀ hexagon pointing upward. Transition of C₆₀ fullerenes to the more stable state is accompanied by expelling In atoms from the Si(111)4 × 1-In reconstruction.     

Evolution of the Shape of the Anode Boundary under Electrochemical Dimensional Machining of Metals

This paper presents a method for calculating the anode boundary under unsteady conditions of electrochemical dimensional machining of metals. The plane quasistationary problem of determining the shape of the anode boundary for various machining times is considered.     

Numerical investigation and self-similar solutions of the glacier-ocean interaction problem

The mathematical modeling of the heat and mass transfer processes in glaciers is an effective means of investigating and predicting their development. A full explanation of the problem of constructing appropriate mathematical models is given in [1–5]. By analyzing the equations involved [3, 6] it is possible to establish the principal factors and dimensionless numbers determining glacier dynamics and provide justification for neglecting the secondary terms. In particular, a simplified closed system of differential equations for the detailed calculation of all the hydrodynamic characteristics of the glacier can be obtained for K_hj « 1 up to O(K _h ² ), where K_h is the ratio of the vertical and horizontal scales of the ice mass investigated (K_h 10^–4–10^–6). In this case many of the qualitative characteristics of glacier dynamics are preserved even in one-dimensional models within the subisothermal approximation.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 3–7, September–October, 1986.     

Precise and accurate compound-specific carbon and nitrogen isotope analysis of RDX by GC-IRMS

A new analytical method is presented for the compound-specific carbon and nitrogen isotope ratio analysis of a thermo-labile nitramine explosive hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) by gas chromatograph coupled to an isotope ratio mass spectrometer (GC-IRMS). Two main approaches were used to minimise thermal decomposition of the compound during gas chromatographic separation: programmed temperature vaporisation (PTV) as an injection technique and a high-temperature ramp rate during the GC run. δ¹⁵N and δ¹³C values of RDX measured by GC-IRMS and elemental analyser (EA)-IRMS were in good agreement within a standard deviation of 0.3‰ and 0.4‰ for nitrogen and carbon, respectively. Application of the method for the isotope analysis of RDX during alkaline hydrolysis at 50°C revealed isotope fractionation factors ε _carbon?=??7.8‰ and ε _nitrogen?=??5.3‰.     

Tight focusing with a binary microaxicon

Using a near-field scanning microscope (NT-MDT) with a 100 nm aperture cantilever held 1 μm apart from a microaxicon of diameter 14 μm and period 800 nm, we measure a focal spot resulting from the illumination by a linearly polarized laser light of wavelength λ=532 nm, with its FWHM being equal to 0.58λ, and the depth of focus being 5.6λ. The rms deviation of the focal spot intensity from the calculated value is 6%. The focus intensity is five times larger than the maximal illumination beam intensity.     

The Coulomb integrals and the diffraction model of transfer reactions

The resonating group interaction of three clusters, in the single channel no-distortion approximation, is split into a leading part and a residual part. In norm kernel eigenstate representation, the leading part exhibits a peculiar, fish bone like symmetry. An off-shell transformation, which leads to an energy-independent interaction, also reduces the strength of the three-body Pauli potential. The smallness of this potential is related to the possibility of interpreting cluster relative motion wave functions as probability density amplitudes. Neglecting all residual interactions and introducing, instead, fitting parameters into the two-cluster direct interactions leads to a three-cluster optical model. In this model the on-shell behaviour of two-cluster interactions is determined by experimental data, while their off-shell behaviour, as well as the three-cluster Pauli potential, are determined by the Pauli principle.