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101.
Zegers RG Sumihama M Ahn DS Ahn JK Akimune H Asano Y Chang WC Daté S Ejiri H Fujimura H Fujiwara M Hicks K Hotta T Imai K Ishikawa T Iwata T Kawai H Kim ZY Kino K Kohri H Kumagai N Makino S Matsumura T Matsuoka N Mibe T Miwa K Miyabe M Miyachi Y Morita M Muramatsu N Nakano T Niiyama M Nomachi M Ohashi Y Ooba T Ohkuma H Oshuev DS Rangacharyulu C Sakaguchi A Sasaki T Shagin PM Shiino Y Shimizu H Sugaya Y Toyokawa H Wakai A Wang CW Wang SC Yonehara K Yorita T Yoshimura M Yosoi M 《Physical review letters》2003,91(9):092001
Beam polarization asymmetries for the p(gamma-->,K+)Lambda and p(gamma-->,K+)Sigma(0) reactions are measured for the first time for E(gamma)=1.5-2.4 GeV and 0.6相似文献
102.
Kawai K Takada T Nagai T Cai X Sugimoto A Fujitsuka M Majima T 《Journal of the American Chemical Society》2003,125(52):16198-16199
The hole transfer causes the long-lived charge-separated state in DNA during the photosensitized one-electron oxidation of DNA. The combination of the transient absorption measurement and DNA damage quantification by HPLC clearly demonstrated that the yield of the DNA damage correlates well with the lifetime of the charge-separated state. 相似文献
103.
Kim H Ralph J Lu F Ralph SA Boudet AM MacKay JJ Sederoff RR Ito T Kawai S Ohashi H Higuchi T 《Organic & biomolecular chemistry》2003,1(2):268-281
Peroxidase/H2O2-mediated radical coupling of 4-hydroxycinnamaldehydes produces 8-O-4-, 8-5-, and 8-8-coupled dehydrodimers as has been documented earlier, as well as the 5-5-coupled dehydrodimer. The 8-5-dehydrodimer is however produced kinetically in its cyclic phenylcoumaran form at neutral pH. Synthetic polymers produced from mixtures of hydroxycinnamaldehydes and normal monolignols provide the next level of complexity. Spectral data from dimers, oligomers, and synthetic polymers have allowed a more substantive assignment of aldehyde components in lignins isolated from a CAD-deficient pine mutant and an antisense-CAD-downregulated transgenic tobacco. CAD-deficient pine lignin shows enhanced levels of the typical benzaldehyde and cinnamaldehyde end-groups, along with evidence for two types of 8-O-4-coupled coniferaldehyde units. The CAD-downregulated tobacco also has higher levels of hydroxycinnamaldehyde and hydroxybenzaldehyde (mainly syringaldehyde) incorporation, but the analogous two types of 8-O-4-coupled products are the dominant features. 8-8-Coupled units are also clearly evident. There is clear evidence for coupling of hydroxycinnamaldehydes to each other and then incorporation into the lignin, as well as for the incorporation of hydroxycinnamaldehyde monomers into the growing lignin polymer. Coniferaldehyde and sinapaldehyde (as well as vanillin and syringaldehyde) co-polymerize with the traditional monolignols into lignins and do so at enhanced levels when CAD-deficiency has an impact on the normal monolignol production. The implication is that, particularly in angiosperms, the aldehydes behave like the traditional monolignols and should probably be regarded as authentic lignin monomers in normal and CAD-deficient plants. 相似文献
104.
A reductive transmetalation of the pi-allylpalladium(II) complexes, generated in situ from a catalytic amount of a palladium(0) complex and a variety of allylic substrates, with indium(I) salts proceeded smoothly in various solvents, providing a new route for allylindium(III) reagents. 相似文献
105.
1.5-mum emissions from Nd:YAG, Nd:YVO(4), and LiNdP(4) O>(12) microchip lasers pumped by laser diodes have been observed. These coherent emissions are attributed to the effect of high-energy modified lattice vibration owing to the existence of Nd ions as well as to stimulated intracavity Raman scattering enhanced by the microchip configuration. A four-wave mixing process involving two lasing fields and a Stokes field was identified as the generator of new adjacent 1.5-mu;m emission. 相似文献
106.
A.K.M. Akther Hossain K. Khirul Kabir T. Kawai 《Journal of Physics and Chemistry of Solids》2007,68(10):1933-1939
Structural, AC and DC magnetic properties of polycrystalline Zn1−xCoxFe2O4 (x=0.2, 0.4) samples sintered at various temperatures (1100-1300 °C), and various dwell times (0.2-15 h) have been investigated thoroughly. The bulk density of the Zn0.60Co0.40Fe2O4 samples increases as the sintering temperature (Ts) increases from 1100 to 1250 °C, and above 1250 °C the bulk density decreases slightly. The Zn0.80Co0.20Fe2O4 samples show similar behavior of changes to that of Zn0.60Co0.40Fe2O4 samples except that the bulk density is found to be highest at 1200 °C. The DC magnetization as a function of temperature curves show that the Zn0.60Co0.40Fe2O4 sample is ferrimagnetic at room temperature while the Zn0.80Co0.20Fe2O4 sample is paramagnetic at room temperature. The Tc of Zn0.80Co0.20Fe2O4 sample is found to be 170 K from DC magnetization measurement. Separate measurement (AC magnetization), initial permeability as a function of temperature shows that the Tc of the Zn0.60Co0.40Fe2O4 sample is 353 K. Slight variation of Tc is observed depending on sintering condition. The initial permeability for the Zn0.60Co0.40Fe2O4 composition sintered at 1250 °C is found to be maximum. 相似文献
107.
There are many approaches to achieving high-performance speech enhancement. The modeling of the human auditory system is a good approach, since human beings can focus on target speech under concurrent speech conditions. One example of the binaural models is the time domain binaural model. However, this model has a high-calculation cost because the algorithm is based on auto-correlation, which is computationally intensive. Another example is the frequency domain binaural model proposed by Nakashima et al. [Nakashima H, Chisaki Y, Usagawa T, Ebata M. Frequency domain binaural model based on interaural phase and level differences. Acoust Sci Technol 2003;24(4):172-8]. Since the frequency domain binaural model uses the fast fourier transform, the calculation cost is much lower than that of the time domain binaural model. Therefore, it is not difficult to perform real-time processing using recent hardware such as digital signal processors and even laptop personal computers. However the quality of the segregated sound obtained using the frequency domain binaural model depends on system parameters such as frequency resolution and frame shift length for overlap adding in time domain. This paper introduces the construction of a prototype of a hearing assistant system based on the frequency domain binaural model. The detailed implementation techniques and parameter tuning are mentioned. The proposed system runs in real-time after parameter tuning. The directional attenuation levels, that is, the directivity patterns of the proposed system is measured. Finally, it is shown that the prototype can extract sounds coming from specific directions in real-time. 相似文献
108.
The low-energy electronic structure of a c-axis SrxAyCuO2 (A is alkaline earth cation, x+y≦1, hole- and electron-doped infinite layer) thin film, grown by laser-molecular-beam epitaxy
on a SrTiO3 (001) substrate, has been studied using ultrahigh-vacuum scanning tunneling microscopy/spectroscopy. Images have been obtained
for co-deposited SrxAyCuO2 thin films, which show the surface consisting of flat terraces separated by steps that are unit cell high. Tunneling spectra
of undoped Sr0.3Ca0.7CuO2 indicate a wide band gap of 1.8 eV which is consistent with the charge transfer gap. Hole-doped Sr0.85CuO2 shows in-gap states appearing at both the valence and conduction band edges. In contrast, for the electron-doped Sr0.9La0.1CuO2, in-gap states appear predominantly above the Fermi level, and the spectral shape becomes asymmetric around the Fermi level.
When these two systems are compared, barrier-height measurements reveal that there is no apparent shift of the Fermi level
measured from the vacuum level. This suggests that the framework of the rigid-band picture might break down implying a strongly
correlated electron system.
Received: 20 August 1998 / Accepted: 15 February 1999 / Published online: 5 May 1999 相似文献
109.
Kenshu Fujiwara Akiyoshi Goto Daisuke Sato Hidetoshi Kawai Takanori Suzuki 《Tetrahedron letters》2005,46(20):3465-3468
A simple stereoselective synthesis of cis- and trans-2,3-disubstituted medium-sized cyclic ethers has been developed based on geometry-selective synthesis of 3-alkoxy-2-propenyl glycolate esters, Ireland-Claisen rearrangement of the glycolate esters, and ring-closing olefin metathesis. 相似文献
110.
Chromatographic separation of styrene-methyl methacrylate (MMA) copolymers depending on the chemical composition was studied using liquefied carbon dioxide as an adsorption promoting solvent, and tetrahydrofuran, chloroform containing ethanol as a desorption promoting solvent in the mobile phase and the column packed non-bonded silica gel by a solvent gradient method. With the increase of MMA content, the elution was retarded indicating that the typical normal-phase type of adsorption occurred. The effects of type of desorption solvents, molecular mass of sample, and column temperature on the elution were investigated. 相似文献