全文获取类型
收费全文 | 634篇 |
免费 | 29篇 |
国内免费 | 1篇 |
专业分类
化学 | 460篇 |
晶体学 | 2篇 |
力学 | 5篇 |
数学 | 29篇 |
物理学 | 168篇 |
出版年
2023年 | 3篇 |
2022年 | 12篇 |
2021年 | 10篇 |
2020年 | 12篇 |
2019年 | 14篇 |
2018年 | 9篇 |
2017年 | 11篇 |
2016年 | 18篇 |
2015年 | 15篇 |
2014年 | 19篇 |
2013年 | 32篇 |
2012年 | 24篇 |
2011年 | 30篇 |
2010年 | 20篇 |
2009年 | 16篇 |
2008年 | 30篇 |
2007年 | 32篇 |
2006年 | 19篇 |
2005年 | 25篇 |
2004年 | 20篇 |
2003年 | 22篇 |
2002年 | 16篇 |
2001年 | 20篇 |
2000年 | 14篇 |
1999年 | 7篇 |
1998年 | 7篇 |
1997年 | 23篇 |
1996年 | 15篇 |
1995年 | 10篇 |
1994年 | 6篇 |
1993年 | 10篇 |
1992年 | 7篇 |
1991年 | 10篇 |
1990年 | 7篇 |
1989年 | 8篇 |
1988年 | 9篇 |
1987年 | 4篇 |
1986年 | 7篇 |
1985年 | 5篇 |
1984年 | 8篇 |
1982年 | 12篇 |
1981年 | 10篇 |
1980年 | 5篇 |
1978年 | 5篇 |
1977年 | 7篇 |
1976年 | 4篇 |
1975年 | 6篇 |
1974年 | 5篇 |
1971年 | 4篇 |
1934年 | 2篇 |
排序方式: 共有664条查询结果,搜索用时 15 毫秒
61.
Excellent Performance of Few‐Layer Borocarbonitrides as Anode Materials in Lithium‐Ion Batteries 下载免费PDF全文
Borocarbonitrides (BxCyNz) with a graphene‐like structure exhibit a remarkable high lithium cyclability and current rate capability. The electrochemical performance of the BxCyNz materials, synthesized by using a simple solid‐state synthesis route based on urea, was strongly dependent on the composition and surface area. Among the three compositions studied, the carbon‐rich compound B0.15C0.73N0.12 with the highest surface area showed an exceptional stability (over 100 cycles) and rate capability over widely varying current density values (0.05–1 A g?1). B0.15C0.73N0.12 has a very high specific capacity of 710 mA h g?1 at 0.05 A g?1. With the inclusion of a suitable additive in the electrolyte, the specific capacity improved drastically, recording an impressive value of nearly 900 mA h g?1 at 0.05 A g?1. It is believed that the solid–electrolyte interphase (SEI) layer at the interface of BxCyNz and electrolyte also plays a crucial role in the performance of the BxCyNz . 相似文献
62.
Cover Picture: Electron–Proton Decoupling in Excited‐State Hydrogen Atom Transfer in the Gas Phase (Angew. Chem. Int. Ed. 50/2015) 下载免费PDF全文
63.
Probing the Rotational Dynamics of meso‐(2‐Substituted)aryl Substituents in A2B‐Type Subporphyrins 下载免费PDF全文
Kota Yoshida Graeme Copley Hirotaka Mori Prof. Dr. Atsuhiro Osuka 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(32):10065-10072
A2B‐type B‐methoxy subporphyrins 3 a – g and B‐phenyl subporphyrins 7 a – c , e , g bearing meso‐(2‐substituted)aryl substituents are synthesized, and their rotational dynamics are examined through variable‐temperature (VT) 1H NMR spectroscopy. In these subporphyrins, the rotation of meso‐aryl substituents is hindered by a rationally installed 2‐substituent. The rotational barriers determined are considerably smaller than those reported previously for porphyrins. Comparison of the rotation activation parameters reveals a variable contribution of ΔH≠ and ΔS≠ in ΔG≠. 2‐Methyl and 2‐ethyl groups of the meso‐aryl substituents in subporphyrins 3 e , 3 f , and 7 e induce larger rotational barriers than 2‐alkoxyl substituents. The rotational barriers of 3 g and 7 g are reduced by the presence of the 4‐dibenzylamino group owing to its ability to stabilize the coplanar rotation transition state electronically. The smaller rotational barriers found for B‐phenyl subporphyrins than for B‐methoxy subporphyrins indicate a negligible contribution of SN1‐type heterolysis in the rotation of meso‐aryl substituents. 相似文献
64.
In the presence of palladium complexes as catalysts, fluorinated disilanes add to 1,3-dienes, metehyl vinyl ketone and p-benzoquinone to give mainly 1,4-addition products. 相似文献
65.
66.
Ramesh P Okazaki T Taniguchi R Kimura J Sugai T Sato K Ozeki Y Shinohara H 《The journal of physical chemistry. B》2005,109(3):1141-1147
Double-wall carbon nanotubes (DWNTs) have been selectively synthesized over Fe/Co loaded mesoporous silica by catalytic chemical vapor deposition of alcohol. Several silica materials with desired pore diameter and morphology have been investigated for the DWNT growth. The diameter distribution and selectivity of the DWNT are found to depend on the reaction temperature, pore size, and thermal stability of the support material. A high-yield synthesis of DWNTs has been achieved at 900 degrees C over high-temperature stable mesoporous silica. The outer diameter of DWNTs is found to be in the range of 1.5-5.4 nm with a "d" spacing of 0.38 +/- 0.02 nm between inner and outer layers, which is much larger than those of multiwall carbon nanotubes. 相似文献
67.
68.
The power spectrum analysis using the Lomb-Scargle false alarm probability statistic shows a clear separation between the average and fluctuating parts of the state density in embedded two-body random matrix ensembles with a mean-field for both fermion and boson systems as well as in the nuclear shell model. 相似文献
69.
Noriki Kutsumura Kota Shibuya Hitoshi Yamaguchi Takao Saito 《Tetrahedron letters》2017,58(43):4099-4102
Regioselective elimination of a vicinal bis-triflate having an adjacent ether oxygen functional group has been developed. Considered in the context of our studies of the regioselective elimination of vicinal dibromide, the key to the mechanism involves the electron-withdrawing inductive effect of the neighboring oxygen functional group. Aliphatic vinyl triflate was shown to be effective in Suzuki–Miyaura cross coupling compared with corresponding aliphatic vinyl bromide. 相似文献
70.
Mannepalli Lakshmi Kantam Gopaladasu Tirupati Venkanna Kota Balaji Shiva Kumar Vura Bala Subrahmanyam 《Helvetica chimica acta》2010,93(5):974-979
N‐Arylation of N‐containing heterocycles, such as pyrazoles, imidazoles, and benzimidazoles with aryl‐, heteroaryl‐, and vinylboronic acids was efficiently carried out by copper fluorapatite (CuFAP) catalyst in MeOH at room temperature under base‐free conditions. The N‐arylated heterocycles were isolated in good‐to‐excellent yields. 相似文献