The proton g9/2 isomer in theN=50 nucleus87Rb and M2 transition rates in85,87Rb

Low-lying states of theN=50 nucleus⁸⁷Rb have been investigated in the (, ') reaction measuring- and delayed-rf-coincidences. A half-life ofT _1/2=6(1) ns was obtained for the level at 1578.1 keV. This experimental result confirms the 9/2⁺ assignment and the proton 1g_9/2 single-particle character of this state. Experimental M2 transition strengths in^85,87Rb are compared with predictions of the shell model and the particle-core coupling model.This work was partly supported by the Bulgarian National Research Foundation.     

Theoretical and vibrational spectral investigation of sodium salt of acenocoumarol

The FT‐IR and FT‐Raman spectra of sodium salt of 4‐hydroxy‐3[1‐(4‐nitrophenyl)‐3‐oxobutyl]‐2H‐1‐benzopyran‐2‐one (acenocoumarol sodium salt) in solid phase have been recorded and analyzed. The optimization geometry, intramolecular hydrogen bonding, and harmonic vibrational wavenumbers of acenocoumarol sodium salt have been investigated with the help of B3LYP density functional theory (DFT) methods. The infrared and Raman spectra were predicted theoretically from the calculated intensities. Natural bond orbital (NBO) analysis indicates the presence of C H···O hydrogen bonding in the molecule. The first static hyperpolarizability of the molecule has been computed. Copyright © 2009 John Wiley & Sons, Ltd.     

Synthesis,characterization and antimicrobial activity of nalidixic acid derivatives with spirohydantoins

This article presents the synthesis of a series of amides, based on the interaction of several 3-aminospirohydantoins with nalidixic acid. The target compounds were characterized by physicochemical parameters, IR, ¹H and ¹³C NMR spectral data. The antimicrobial activity of the products obtained was determined against Gram-positive bacteria Staphylococcus aureus and Bacillus subtilis, Gram-negative bacteria Escherichia coli, Pseudomonas aeruginosa and Salmonella abony, the yeasts Candida albicans and Saccharomyces cerevisiae and the molds Penicillium chrysogenum and Aspergillus niger. The relationship between structure and biological activity of the products obtained was discussed. It was found that the most effective compounds are tetralin (5f) and indane (5g) derivatives, which exhibit a pronounced antimicrobial activity against both tested Gram-positive and Gram-negative bacteria.

     

New radon and gamma device using TLD and SSNTD to carry out monitoring in the environment

The research program, that we are leading, concerns and takes into consideration the potential risk of the natural and artificial radio-elements in the environment and particularly to consider their migration from environment to the people and with special respect to radon effects. To begin these investigations, we developed a new passive detectors using two solid nuclear track detector techniques: thermo-luminescent detectors (TLDs) (gamma measuring) and solid state nuclear track detectors (SSNTDs) (alpha measuring). The characteristics of the cell provide for alpha (SSNTD - LR115) and gamma-radioactivity (TLD-CaSO₄:Dy) measuring in different soil depths. The used technologies are with a low priced. The instrumentation has been first validated in laboratory to quality precisely its response and then, we have performed the survey for one site in Bulgaria.