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排序方式: 共有131条查询结果,搜索用时 15 毫秒
21.
22.
P. Chr. Petrov G. K. Kostov 《Journal of polymer science. Part A, Polymer chemistry》1994,32(12):2235-2239
Emulsion copolymerization of tetrafluoroethylene (TFE) and propylene (P) initiated by trilon-rongalite catalytic system containing tert-C4H9OH, initial monomer mixture, emulsifier (C7F15COONH4) concentration, and monomer mixture/water ratio on the polymerization rate (R) and molecular weight (M?n ) was investigated. Both R and M?n increased considerably with TFE content in monomer mixture up to 75 mol %. Alternating rubber-like copolymers in a wide range of initial monomer mixture (from 55–85 mol %) were obtained. The reactivity ratio was found to be rTFE = 0.005 ± 0.04 and rp = 0.17 ± 0.07. Above the critical miscelle concentration, the effects of the initiating system Is and emulsifier Cs on R and M?n were found to obey the following relations: according to which emulsion copolymerization proceeds by the I case of Smith-Ewart theory. Polymerization mechanism of the reaction studied was suggested. The copolymerization is mainly terminated by degradative chain transfer of the propagating radicals to propylene. © 1994 John Wiley & Sons, Inc. 相似文献
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24.
We study restricted multiple three wave interaction system by the inverse scattering method. We develop the algebraic approach
in terms of classical r-matrix and give an interpretation of the Poisson brackets as linear r-matrix algebra. The solutions are expressed in terms of polynomials of theta functions. In particular case for n = 1 in terms of Weierstrass functions.
相似文献
25.
Bogdan Goranov Desislava Teneva Rositsa Denkova-Kostova Vesela Shopska Nadia Oulahal Zapryana Denkova Georgi Kostov Pascal Degraeve Rafael Pagan 《Molecules (Basel, Switzerland)》2022,27(17)
Probiotic bacteria are used for food biopreservation because their metabolic products might contribute to ensuring food microbiological safety and/or increase its shelf life without the addition of chemical preservatives. Moreover, biopreserved foods are excellent vehicles for the delivery of probiotic bacteria. The aim of the study was to investigate the potential of chocolate mousse food matrix for the delivery of the probiotic strain Lactobacillus helveticus 2/20 (Lb. helveticus 2/20) and to investigate its capacity to inhibit the growth of two foodborne pathogenic bacteria (Staphylococcus aureus and Escherichia coli). Therefore, the populations of free or encapsulated in calcium alginate Lb. helveticus 2/20 cells and/or of each pathogen (used to voluntarily contaminate each sample) were monitored both in complex nutrient medium (MRS broth) and in chocolate mousse under refrigeration conditions and at room temperature. Lb. helveticus 2/20 alone in free or encapsulated state effectively inhibited the growth of Escherichia coli ATCC 25922 and Staphylococcus aureus ATCC 25923 in chocolate mousse when stored at 20 ± 2 °C. Practically no viable unwanted bacteria were identified on the 7th day from the beginning of the process. High viable Lb. helveticus 2/20 cell populations were maintained during storage under refrigerated conditions (4 ± 2 °C) and at room temperature. Chocolate mousse is thus a promising food matrix to deliver probiotic Lb. helveticus 2/20 cells, which could also protect it from contamination by unwanted bacteria. 相似文献
26.
The melting and crystallization of copolymers of tetrafluoroethylene with ethylene, synthesized in bulk and in suspension by semi-flow method, were studied by DSC. X-ray diffractions and infrared spectra of the copolymers were measured and new crystalline reflections different from those of the homopolymers were observed. The melting temperature of the copolymers synthesized in bulk depends strongly on the composition and exhibits several maxima. A certain small decrease in the melting temperature within the range of the alternating composition is observed. For alternating copolymers synthesized in suspension, the peaks are monomodal indicating a higher structural and chemical homogeneity of the copolymer. The nonisothermal crystallization kinetics in the temperature interval from 260 to 255°C of the alternating copolymer prepared in suspension can be described by a modified Avrami equation. The mechanism of nucleation and nuclei growth during the nonisothermal crystallization of the tetrafluoroethylene-ethylene copolymer is close to that of polyethylene. 相似文献
27.
Thermodynamic investigations of Ga-GeSb0.855 section in the ternary system Ga-Ge-Sb, which is of a practical importance in electric-industry, are presented in this paper.
Results of a comparative thermodynamic analysis at 1273 K obtained by Oelsen calorimetry and predicting methods - general
solution model and Hajra's method are also given.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
28.
G. K. Kostov L. Sauguet B. Ameduri H. Kaspar T. Zipplies K. Hintzer 《Journal of polymer science. Part A, Polymer chemistry》2010,48(18):3964-3976
The radical copolymerization of vinylidene fluoride (VDF) and 1‐bromo‐2,2‐difluoroethylene (BDFE) in 1,1,1,3,3‐pentafluorobutane solution at different monomer molar ratios (ranging from 96/4 to 25/75 mol %) and initiated by tert‐butylperoxypivalate (TBPPI, mainly) is presented. Poly(VDF‐co‐BDFE) copolymers of various aspects (from white powders to yellow viscous liquids) were produced depending on the copolymer compositions. The microstructures of the obtained copolymers were characterized by 19F and 1H NMR spectroscopy and by elementary analysis and these techniques enabled one to assess the contents of both comonomers in the produced copolymers. VDF was shown to be more incorporated in the copolymer than BDFE. From the extended Kelen and Tudos method, the kinetics of the radical copolymerization led to the determination of the reactivity ratios, ri, of both comonomers (rVDF = 1.20 ± 0.50 and rBDFE = 0.40 ± 0.15 at 75 °C) showing that VDF is more reactive than BDFE. Alfrey‐Price's Q and e values of BDFE monomer were calculated to be 0.009 (from QVDF = 0.008) or 0.019 (from QVDF = 0.015) and +1.22 (vs. eVDF = 0.40) or +1.37 (vs. eVDF = 0.50), respectively, indicating that BDFE is an electron‐accepting monomer. Statistic cooligomers were produced with molar masses ranging from 1,800 to 5,500 g/mol (assessed by GPC with polystyrene standards). A further evidence of the successful copolymerization was shown by the selective reduction of bromine atoms in poly(VDF‐co‐BDFE) cooligomers that led to analog PVDF. The thermal properties of the poly(VDF‐co‐BDFE) cooligomers were also determined and those containing a high VDF amount exhibited a high thermal stability. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 3964–3976, 2010. 相似文献
29.
It is established that the hydrocarbon coverage (0<1) formed at T<400 K on the Ir surface is oxidized upon oxygen exposures to CO and H2O by an adsorption mechanism. Complete oxidation to CO2 and H2O is achieved at T350 K after C2H4 exposures of the oxygen coverage.
, (<1), T<400 K Ir, CO H2O . CO2 H2O T350 K C2H4 .相似文献
30.
Infinite symmetry is referred to for describing in a more rational manner the morphology of certain crystals and crystal, particularly mineral aggregates. Their non-crystallographic forms depend on the peculiarities of their structure, enhanced growth along preferred directions and on the symmetry and composition of the growth environment. Apart from the seven Curie forms others, fitting the corresponding point groups are suitably added as variants of the growth geometry, applicable also to the property of matter. 相似文献