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31.
I. O. O. Korhonen 《Chromatographia》1982,15(8):505-508
Summary The gas chromatography of all chlorinated methyl acetates, methyl propanoates and methyl mono- and dichlorobutanoates has been studied on Carbowax 20M and SE-30 glass capillary columns under various running conditions. The order of elution on a non-polar column was largely determined by the boiling point of esters, whereas on a polar column it was much influenced by the structure of compounds. Complete separation of the combined mixture of all 27 compounds could not be achieved, however, methyl 3,3-dichlorobutanoate was the only ester overlapped on both columns in spite of the various column temperatures used. The best separation of the mixture was on Carbowax 20M with a temperature program from 50°C at 8°C/min, isothermal running conditions leading either to poor separation of volatile components or long analysis time and broad peaks of higher chlorinated esters. The relative retention times for compounds at the various column temperatures are given and the retention order on a polar and on a non-polar column discussed. 相似文献
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Experimental study of color degree of freedom of gluons in e+e- annihilation at sqrt s around 60 GeV
Abe K Amako K Arai Y Asano Y Chiba M Chiba Y Daigo M Emura T Fukawa M Fukui T Fukushima Y Haba J Hemmi Y Higuchi M Hirose T Hojyo Y Homma Y Hoshi Y Ikegami Y Ishihara N Kamitani T Kanematsu N Kanzaki J Kikuchi R Kondo T Korhonen TT Koseki T Kurashige H Matsui T Minami M Miyake K Mori S Nagashima Y Nakamura T Nakano I Narita Y Odaka S Ogawa K Ohama T Ohsugi T Okamoto A Ono A Oyama T Sakamoto H Sakuda M Sasao N Sato M Shioden M Shirai J Shirakata M Sugimoto S Sumiyoshi T Suzuki A Suzuki Y 《Physical review letters》1991,66(3):280-284
34.
The behaviour of all nine chlorinated veratroles (1,2-dimethoxybenzenes) under electron impact has been investigated. The most common fragmentation processes are interpreted using metastable ion analysis and deuterium labelled compounds. For all compounds studied, the most common fragmentation route seems to be the primary loss of a methyl radical followed by loss of carbon monoxide. The ion formed has a well-known quinonoid structure and fragments by several routes elucidated by metastable ion analysis. In general, the spectra of the positional isomers are shown to be practically similar and it is apparent that e.g. the 3- and 4-chloro isomers can be differentiated only from the abundance ratio of the [M? CH3? CO? CH3]+ and [M? CH3? CO? H2O]+ ions. 相似文献
35.
The additions of chlorine, bromine and bromine chloride to trans methyl 2-butenoate 1, trans methyl 2-methyl-2-butenoate 2 and methyl 3-methyl-2-butenoate 3 under ionic conditions were studied. Bromine chloride addition always gave as a major regioisomer the 2-bromo-3--chloro compound,almost quantitatively in the case of 3. The mechanism of bromonium ion ring-opening (SN1 or SN2) is discussed with respect to the double bond substitution and regioisomer proportions. The dihalo products were identified by MS, 1H and 13C NMR. 相似文献
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In a commercial Al-2·5% Mg alloy stress relaxation runs are well described by Hart's low temperature flow law and show essentially friction controlled flow behaviour, ranging from nearly anelastic to plastic flow, depending on the time, temperature and strain. Anelasticity during repeated relaxations indicates substantial strain aging during the initial relaxation run. Initial stages of relaxations show yield point like transients in the temperature/strain regime, where yield points are observed also in the tensile test.The authors are grateful te Drs. C.-Y. Li, D. Stone and M. Hamersky for helpful discussions. Thanks are extended to Nokia Corp. Pikkala Works, for providing the Al-alloy used in this study. 相似文献
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