Corrected mirror systems with double reflection

We propose objectives consisting of two mirrors with central holes for passage of a light beam. The optical layout ensures multiple reflection of rays from both mirrors. We consider several approaches to calculating the design parameters for which three and four aberrations do not occur. The objectives can be used in optical devices operating in the UV and IR regions of the spectrum. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 2, pp. 267–270, March–April, 2007.     

Development of a universal constant rate thermal analysis system for being used with any thermoanalytical instrument

The SCTA method implies to control the temperature in such a way that the reaction rate changes with the time according to a function previously defined by the user. Constant Rate Thermal Analysis (CRTA) is one of the most commonly used SCTA methods and implies achieving a temperature profile at which the reaction rate remains constant all over the process at a value previously selected by the user. This method permits to minimize the influence of heat and mass transfer phenomena on the forward reaction. The scope of this work is to develop a universal CRTA temperature controller that could be adapted to any thermoanalytical device. The thermoanalytical signal is programmed to follow a preset linear trend by means of a conventional controller that at the time controls a second conventional temperature programmer that forces the temperature to change for achieving the trend programmed for the thermoanalytical signal. Examples of the performance of this control system with a Thermobalance and a Thermomechanical Analyser (TMA) are given.     

Gas solubility of carbon dioxide in poly(lactic acid) at high pressures: Thermal treatment effect

The sorption of carbon dioxide in glassy Poly(lactic acid) (PLA) films was studied by quartz crystal microbalance (QCM) at high pressures. Two thermal treatments, melted and quenched, were performed in PLA with two different L:D contents, 80:20 and 98:2, films and compared with a third thermal protocol, annealed, and used in a previous work. The results obtained show that for pressures higher than 2 MPa, the carbon dioxide solubility is larger in PLA 80:20 than in PLA 98:2, indicating that the L:D plays a dominant role on this property. The thermal treatments only affect the gas solubility in PLA 98:2. Sorption isotherms at temperatures 303, 313, and 323 K, below the glass transition temperature of the polymer, and pressures up to 5 MPa were measured and analyzed with three different models, the dual‐mode sorption model, the Flory–Huggins equation, and a modified dual‐mode sorption model where the Henry's law term was substituted by the Flory–Huggins equation. This last model performs especially well for CO₂ in PLA 80:20, due to the convex upward curvature of the solubility isotherms for that system. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 616–625, 2007     

Spectral Properties of Thioflavin T and Its Complexes with Amyloid Fibrils

Comparative analysis of the absorption and fluorescence spectra and fluorescence excitation spectra of thioflavin T (ThT) in various solvents and in the composition of amyloid fibrils has shown that ThT, when excited in the region of the long-wavelength absorption band, fluoresces in the spectral region with a maximum at 478–484 nm. The appearance in aqueous and alcohol solutions of a fluorescence band with a maximum near 440 nm has been attributed to the presence in the composition of the ThT preparations of an impurity with an absorption band in the 340–350-nm range. The literature data showing that in glycerol ThT has a wide fluorescence spectrum with two maxima are due to the artifact connected with the use of a high concentration of the dye. It has been suggested that the cause of the low quantum yield of ThT aqueous and alcohol solutions is the breakage of the system of conjugated bonds due to the reorientation of the benzothiozole and benzaminic rings of ThT in the excited state with respect to one another. The main factor determining the high quantum yield of fluorescence of ThT incorporated in fibrils is the steric restriction of the rotation of the rings about one another under these conditions. The suggestions made have been verified by the quantum-chemical calculation of the ThT molecule geometry in the ground and excited states.     

High-order harmonic generation with a strong laser field and an attosecond-pulse train: The Dirac-Delta comb and monochromatic limits

In recent publications, it has been shown that high-order harmonic generation can be manipulated by employing a time delayed attosecond-pulse train superposed to a strong, near-infrared laser field. It is an open question, however, which is the most adequate way to approximate the attosecond-pulse train in a semianalytic framework. Employing the strong-field approximation and saddle-point methods, we make a detailed assessment of the spectra obtained by modeling the attosecond-pulse train by either a monochromatic wave or a Dirac-Delta comb. These are the two extreme limits of a real train, which is composed by a finite set of harmonics. Specifically, in the monochromatic limit, we find the downhill and uphill sets of orbits reported in the literature, and analyze their influence on the high-harmonic spectra. We show that, in principle, the downhill trajectories lead to stronger harmonics, and pronounced enhancements in the low plateau region. These features are analyzed in terms of quantum interference effects between pairs of quantum orbits, and compared to those obtained in the Dirac-Delta limit.     

Polarization dynamics of longitudinally monomode bipolarized microchip solid-state lasers

This paper is devoted to the polarization dynamics of a longitudinally monomode bipolarized Nd:YAG laser: the low-frequency polarization dynamics of a microchip laser is studied experimentally and theoretically. The intensities and the relaxation oscillation spectrum of orthogonally polarized modes versus the direction of pump polarization is observed. A phase-sensitive model of a longitudinally monomode bipolarized solid-state laser with linear polarized diode laser pump is developed to account for the experimental observations.     

Modification of silica gels with small admixtures of titanium ions

Microporous silica gels containing small amounts of titanium ions are synthesized. Addition of Ti ions to the silica gels during the sol-forming step is demonstrated to increase the specific surface area and decrease the volume of sorptive pores. Spectral results indicate that Ti ions uniformly distribute in the silica gel matrix and isomorphously replace Si.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2217–2222, October, 1991.