152.
Titanium dioxide ultrafine particles (UFPs) are produced by pulsed laser ablation of titanium or titanium dioxide (anatase and rutile) rods in an atmosphere of He or O
2/He mixture. The collected UFPs on cellulose membrane filters at the exit of the ablation chamber are analyzed by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The TiO
2 particles produced are composed of very small particles (diameter: 10–50nm) that are completely anatase, irrespective of the rod material, and relatively large particles (diameter: 100nm–1m) that are a mixture of anatase and rutile. The large particles consist of the direct strip-off fragments coming from the rod surface. The particles obtained from the laser ablation on TiO
2 rods in an atmosphere of He contains gray particles that are supposed to be amorphous TiO
2 (
x < 2). In the presence of O
2 in the ablation chamber, these oxygen defects in amorphous TiO
2 are stabilized and anatase UFPs are formed. These results suggest that the crystal phase of the products can be controlled by adjusting the rod material and the gases used in the ablation process.
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