Stereogradient polymers by ruthenium-catalyzed stereospecific living radical copolymerization of two monomers with different stereospecificities and reactivities

Stereogradient polymers, a fundamentally new type of polymers, were prepared by the stereospecific living radical copolymerization of two monomers that have different stereospecificities and reactivities. The ruthenium-catalyzed living radical copolymerization of 2-hydroxyethyl methacrylate (HEMA) and the silyl-capped HEMA [(tert-butyldimethylsilyl)-HEMA] (SiHEMA) in (CF3)2C(Ph)OH afforded stereogradient poly(HEMA), in which the rr content gradually increased from 62 to 77% at 0 degrees C, due to the lower reactivity and the higher syndiospecificity of SiHEMA.     

Extraction mechanisms of charged organic dye molecules into silica-surfactant nanochannels in a porous alumina membrane

Extraction mechanisms of charged organic dye molecules are examined for an assembly of silica-surfactant nanochannels with a channel diameter of 3.4 nm, which is formed inside the pores of an anodic alumina membrane by a surfactant-template method. Experimental results confirm that the extraction mechanism depends on the sign of a charge of the dye molecules. The extraction of the cationic rhodamine 6G is predominantly caused by an ion-pair extraction process, whereas an anion-exchange process is mainly responsible for the extraction of the anionic sulforhodamine B. These extraction mechanisms are discussed by considering the microstructures of the silica-surfactant nanochannels.     

Measurement of coherent terahertz radiation for time-domain spectroscopy and imaging

A high-power terahertz (THz) source for THz time-domain spectroscopy (THz-TDS) and THz imaging has been developed based on an S-band compact electron linac at the National Institute of Advanced Industrial Science and Technology (AIST). A THz pulse was generated as coherent synchrotron radiation (CSR) from an ultra-short electron bunch and expected to have peak power of kW-order with frequency range of 0.1–2 THz. The electro-optic (EO) sampling method with a ZnTe crystal for the THz pulse measurement has been prepared for THz-TDS system. The timing measurement between the THz pulse and a probe laser was carried out. A preliminary experiment of THz transmission imaging of an integrated circuit (IC) card has been successfully demonstrated using the THz CSR pulse and a W-band rf detector. The imaging result was experimentally compared with a result of X-ray imaging. It is confirmed that its intensity and stability are enough to perform for the THz applications.     

Complete bounded null curves immersed in {\mathbb {C}^3} and {\rm {SL}(2,\mathbb {C})}

We construct a simply connected complete bounded mean curvature one surface in the hyperbolic 3-space ${\mathcal {H}^3}$ . Such a surface in ${\mathcal {H}^3}$ can be lifted as a complete bounded null curve in ${\rm {SL}(2,\mathbb {C})}$ . Using a transformation between null curves in ${\mathbb {C}^3}$ and null curves in ${\rm {SL}(2,\mathbb {C})}$ , we are able to produce the first examples of complete bounded null curves in ${\mathbb {C}^3}$ . As an application, we can show the existence of a complete bounded minimal surface in ${\mathbb {R}^3}$ whose conjugate minimal surface is also bounded. Moreover, we can show the existence of a complete bounded immersed complex submanifold in ${\mathbb {C}^2}$ .     

垂直轴风力机叶片表面结冰的风洞试验

为研究垂直轴风力机叶片表面结冰的规律以及结冰对其性能的影响,对采用NACA0018翼型的风力机叶片进行了风洞结冰试验研究。在风洞试验段内安装了喷水装置,室外的寒冷空气被吸入风洞后与过冷水滴一起吹向叶片并碰撞结冰。测试了不同水滴流量和叶片攻角下的叶表结冰分布及叶片的升阻力系数变化。在一定攻角范围内,叶表结冰量随翼型迎风面积增加而增加;结冰后的阻力系数增大,升力系数减小,叶片的气动特性降低。