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81.
This study demonstrates the separation of active ingredients in acne formulations (salicylic acid, cloramphenicol and resorcinol in presence of azulene) by capillary zone electrophoresis. Factors affecting their separations were the buffer pH and concentration, applied voltage, sample preparation, and presence of additives. Optimun results were obtained with a 50 mM sodium tetraborate-50 mM sodium phosphate, pH 9.0. The carrier electrolyte gave baseline separation with good resolution, short migration times (<6 min), great reproducibility and accuracy. Calibration plots were linear over at least three orders of magnitude of analyte concentrations, the lower limits of detection being within the range 0.39-1.25 μg ml−1. The procedure was fast and reliable and commercial pharmaceuticals could be analysed without prior sample clean-up procedure. 相似文献
82.
We prove an existence theorem for a nonlinear integral equation being a Volterra counterpart of an integral equation arising in the traffic theory. The method used in the proof allows us to obtain additional characterization in terms of asymptotic stability of solutions of an equation in question. 相似文献
83.
Isabel Brandariz José L. Barriada Teresa Vilari?o Manuel E. Sastre de Vicente 《Monatshefte für Chemie / Chemical Monthly》2004,343(6):1475-1488
Several reported procedures for calibrating glass electrodes in proton concentration are compared. Some recommendations for non-experts are also given. The examined procedures can be classified into two broad categories, namely: those based on direct potential difference measurements of solutions of known proton concentration and those that use one or several pH standards to calibrate the electrode and subsequently measure the pH of solutions containing known proton concentrations. With a single buffer, the two types of procedures lead to equivalent results. However, if two pH buffers are used, the slope of the calibration graph in proton concentration will differ from the real electrode slope to an extent proportional to the difference between the liquid junction potentials of the two buffers. Therefore, any other method is preferable under these circumstances. 相似文献
84.
L. D. Olivier W. A. Richter J. A. Stander J. W. Koen 《Zeitschrift für Physik A Hadrons and Nuclei》1993,347(2):99-108
Levels up to 9.3 MeV excitation in22Ne were studied with the19 F(α, pγ) 22Ne reaction atE α = 12 MeV. Level energies, branching ratios, mean lifetimes, spins and mixing ratios were obtained for a number of levels. Relevant results are compared with many-particle shell-model calculations. 相似文献
85.
Grega Cigler Roman Drnovšek Damjana Kokol-Bukovšek Matja? Omladi? Thomas J. Laffey Heydar Radjavi Peter Rosenthal 《Journal of Functional Analysis》1998,160(2):245
T. Laffey showed (Linear and Multilinear Algebra6(1978), 269–305) that a semigroup of matrices is triangularizable if the ranks of all the commutators of elements of the semigroup are at most 1. Our main theorem is an extension of Hthis result to semigroups of algebraic operators on a Banach space. We also obtain a related theorem for a pair {A, B} of arbitrary bounded operators satisfying rank (AB−BA)=1 and several related conditions. In addition, it is shown that a semigroup of algebraically unipotent operators of bounded degree is triangularizable. 相似文献
86.
The hyperspaces of strongly countable dimensional compacta of positive dimension and of strongly countable dimensional continua of dimension greater than 1 in the Hilbert cube are homeomorphic to the Hurewicz set of all nonempty countable closed subsets of the unit interval [0,1]. These facts hold true, in particular, for covering dimension dim and cohomological dimension dimG, where G is any Abelian group. 相似文献
87.
Dong Sheng WU Yi Min XIAO 《数学学报(英文版)》2007,23(4):613-622
Let B^α = {B^α(t),t E R^N} be an (N,d)-fractional Brownian motion with Hurst index α∈ (0, 1). By applying the strong local nondeterminism of B^α, we prove certain forms of uniform Hausdorff dimension results for the images of B^α when N 〉 αd. Our results extend those of Kaufman for one-dimensional Brownian motion. 相似文献
88.
The interaction of the synthetic oligonucleotide d(C-G-C-G-A-A-T-T-C-G-C-G)2 with two different transition-metal ions has been investigated in aqueous solution by means of 1H NMR spectroscopy. The effects on the DNA due to the presence of manganese(II) or zinc(II) have been monitored by observing the paramagnetic broadening and diamagnetic shifts of the non-exchangeable proton resonance lines, respectively. The 1H NMR spectra acquired during the course of the manganese(II) titration show very distinct broadening effects on certain DNA resonance lines. Primarily, the H8 resonance of G4 is affected, but also the H5 and H6 resonances of C3 are clearly affected by the metal. The results imply that the binding of manganese(II) to DNA is sequence specific. The 1H spectra obtained during the zinc(II) titration reveal diamagnetic shift effects which largely conform with the paramagnetic broadening effects due to the presence of manganese(II), although this picture is somewhat more complex. The H8 resonance of G4 displays a clearly visible high-field shift, while for the other guanosine H8 protons this effect is absent. The H1' and H2' protons of C3 show an effect of similar strength, although in the opposite direction, while H5 and H6 of C3 are only slightly affected. Local differences in the structure of the DNA and the basicities of potential binding sites on different base steps in the sequence might account for the observed sequence selectivity. 相似文献
89.
Marijana ?aković Zora Popović 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(11):m507-m509
In the title compound, [Ni(N3)2(C6H6N2O)2], the NiII atom lies on an inversion centre. The distorted octahedral nickel(II) coordination environment contains two planar trans-related N,O-chelating picolinamide ligands in one plane and two monodentate azide ligands perpendicular to this plane. Molecules are linked into a three-dimensional framework by N—H...N hydrogen bonds. 相似文献
90.
D. Seweryniak P. J. Woods B. Blank M. P. Carpenter T. Davinson S. J. Freeman J. Grres A. Heinz R. V. F. Janssens H. Mahmud T. L. Khoo Z. Liu G. Mukherjee E. Rehm F. Sarazin J. Shergur M. Shawcross S. Sinha A. Woehr 《Physics letters. [Part B]》2004,590(3-4):170-175
The fusion–evaporation reaction 10B(12C, 2n) was used to make the first observation of in-beam γ decays from the astrophysically important nucleus 20Na, lying adjacent to the proton drip-line. All states below the proton threshold in 20Na were populated and identified in the experiment. These include new levels, previously unresolved levels, and states located with improved energy precision. The level structure of 20Na, and its γ transitions, are compared to the mirror partner 20F measured simultaneously in this experiment. In particular, a high degree of energy stability is found for all negative parity states. These results are discussed in the context of the nuclear shell model. 相似文献