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排序方式: 共有614条查询结果,搜索用时 15 毫秒
601.
M Köhnke S Schmitt N Ariotti AM Piggott RG Parton E Lacey RJ Capon K Alexandrov D Abankwa 《Chemistry & biology》2012,19(7):866-874
Highlights? Cellular FRET biosensors for Ras, Rho, and Rab membrane anchorage were developed ? We provide evidence for Rab protein nanoclustering on cellular membranes ? Two FRET biosensors were demonstrated to be suitable for high-throughput screening ? Macrotetrolides were identified as nanoclustering and MAPK signaling disruptors 相似文献
602.
We examine interferometric experiments in systems that exhibit non-Abelian braiding statistics, expressing outcomes in terms of the modular S-matrix. In particular, this result applies to fractional quantum Hall interferometry, and we give a detailed treatment of the Read-Rezayi states, providing explicit predictions for the recently observed nu = 12/5 plateau. 相似文献
603.
In this Letter we propose an interferometric experiment to detect non-Abelian quasiparticle statistics--one of the hallmark characteristics of the Moore-Read state expected to describe the observed fractional quantum Hall effect plateau at nu = 5/2. The implications for using this state for constructing a topologically protected qubit as has been recently proposed by Das Sarma et al. are also addressed. 相似文献
604.
Hydrothermal synthesis and characterization of nanorods of various titanates and titanium dioxide 总被引:3,自引:0,他引:3
Kolen'ko YV Kovnir KA Gavrilov AI Garshev AV Frantti J Lebedev OI Churagulov BR Van Tendeloo G Yoshimura M 《The journal of physical chemistry. B》2006,110(9):4030-4038
The formation process of titania based nanorods during hydrothermal synthesis starting from an amorphous TiO2.nH2O gel has been investigated. Sodium tri-titanate (Na2Ti3O7) particles with a rodlike morphology were prepared by a simple hydrothermal process in the presence of a concentrated NaOH aqueous solution. The ion exchange reaction of the synthesized Na2Ti3O7 nanorods with HCl under ultrasonic treatment promotes a complete sodium substitution and the formation of H2Ti3O7 nanorods. Low-temperature annealing of the as-produced nanorods of Na2Ti3O7 and H2Ti3O7 leads to a loss of the layered crystal structure and the formation of nanorods of condensed framework phases-sodium hexa-titanate (Na2Ti6O13) and metastable TiO2-B phases, respectively. These transformations proceed without a significant change in particle morphology. The nanostructures were investigated by scanning electron microscopy (SEM), powder X-ray diffraction (XRD), the Brunauer-Emmett-Teller (BET) method, thermogravimetric analysis (TGA), and Raman spectroscopy. The structural defects of the synthesized nanorods were investigated by high-resolution electron microscopy. The presence of planar defects can be attributed to the exfoliation of the zigzag ribbon layers into two-dimensional titanates as well as to the condensation of the layers of TiO6 octahedra into three-dimensional frameworks. 相似文献
605.
Elyashberg ME Blinov KA Williams AJ Molodtsov SG Martin GE 《Journal of chemical information and modeling》2006,46(4):1643-1656
Expert systems for spectroscopic molecular structure elucidation have been developed since the mid-1960s. Algorithms associated with the structure generation process within these systems are deterministic; that is, they are based on graph theory and combinatorial analysis. A series of expert systems utilizing 2D NMR spectra have been described in the literature and are capable of determining the molecular structures of large organic molecules including complex natural products. Recently, an opinion was expressed in the literature that these systems would fail when elucidating structures containing more than 30 heavy atoms. A suggestion was put forward that stochastic algorithms for structure generation would be necessary to overcome this shortcoming. In this article, we describe a comprehensive investigation of the capabilities of the deterministic expert system Structure Elucidator. The results of performing the structure elucidation of 250 complex natural products with this program were studied and generalized. The conclusion is that 2D NMR deterministic expert systems are certainly capable of elucidating large structures (up to about 100 heavy atoms) and can deal with the complexities associated with both poor and contradictory spectral data. 相似文献
606.
Slipchenko MN Kuyanov KE Sartakov BG Vilesov AF 《The Journal of chemical physics》2006,124(24):241101
Helium droplet technique has been used in order to measure the strength of the infrared absorption in small ammonia and water clusters as a function of size. Hydrogen bonding in ammonia and water dimers causes an enhancement of the intensity of the hydrogen stretching bands by a factor of four and three, respectively. Two types of the hydrogen bonded clusters show different size dependence of the infrared intensity per hydrogen bond. In ammonia (NH3)2 and (NH3)3 it is close to the crystal value. In water clusters, it increases monotonically with cluster size being in tetramers, a factor of two smaller than in the ice. The measured infrared intensity in water clusters is found to be a factor of two to three smaller as compared to the results of numerical calculations. 相似文献
607.
The reaction of o-fluorobenzaldehydes and their O-methyloximes with hydrazine has been developed as a new practical synthesis of indazoles. Utilization of the methyloxime derivatives of benzaldehydes (in the form of the major E-isomers) in this condensation effectively eliminated a competitive Wolf-Kishner reduction to fluorotoluenes, which was observed in the direct preparations of indazoles from aldehydes. Reaction of Z-isomers of methyloximes with hydrazine resulted in the formation of 3-aminoindazoles via a benzonitrile intermediate. 相似文献
608.
We develop a theory of turbulence based on the Navier-Stokes equation, without using dimensional or phenomenological considerations. A small scale vortex filament is the main element of the theory. The theory allows to obtain the scaling law and to calculate the scaling exponents of Lagrangian and Eulerian velocity structure functions in the inertial range. The obtained results are shown to be in very good agreement with numerical simulations and experimental data. The introduction of stochasticity into the equations and derivation of scaling exponents are discussed in details. A weak dependence on statistical propositions is demonstrated. The relation of the theory to the multifractal model is discussed. 相似文献
609.