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41.
    
Anchoring of [PtCl6]2– on -Al2O3 follows an ion exchange mechanism without altering the ligand environment. Drying catalysts at elevated temperatures leads to chemical conversions of the adsorbed complex to form oxygen-containing Pt(IV) complexes due to the substitution of Cl ligands by surface groups of the support.
[PtCl6]2– -Al2O3 . Pt(IV) Cl- .
  相似文献   
42.
Suppose that F is a field of prime characteristic p and V p is the variety of associative algebras over F defined by the identities [[x, y], z] = 0 and x p = 0 if p > 2 and by the identities [[x, y], z] = 0 and x 4 = 0 if p = 2 (here [x, y] = xy ? yx). As is known, the free algebras of countable rank of the varieties V p contain non-finitely generated T-spaces. We prove that the varieties V p are minimal with respect to this property.  相似文献   
43.
Nucleophilic addition of imidazole to arabinogalactan propargyl ether has been accomplished for the first time in the presence of hydrogen tetrachloroaurate(III) tetrahydrate with the goal of obtaining new pharmacologically promising polysaccharides.  相似文献   
44.
Conclusions O-Ethyl-S-(-alkylmercaptoethyl)cyclohexylthiophosphonates are inhibitors of acetylcholinesterase and butyrylcholinesterase with a combinative type of action. The iodomethylates of O-ethyl-S-(-alkylmercaptoethyl) cyclohexylthiophosphonates inhibit acetylcholinesterase irreversibly, and butyrylcholinesterase according to a combinative type of inhibition.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskayaj No. 7, pp. 1600–1606, July, 1977.  相似文献   
45.
Russian Chemical Bulletin - New (co)polyimides possessing good thermal and physicomechanical characteristics, high hydrolytic stability, and transparency at the best world level were synthesized....  相似文献   
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47.
Russian Chemical Bulletin - Alkylation of N-aryl and N-arylalkyl acetamides with hydroxy adamantane derivatives in trifluoroacetic acid was studied. The differentiating effect of trifluoroacetic...  相似文献   
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49.
The influence of organophosphonates on decomposition of equilibrium peracetic acid was studied in the temperature range 50-70°C and pH 4.5-5.0.  相似文献   
50.
The destruction of amylose at high pressures (20 MPa) combined with shear deformations (540°) was studied. The destruction products were analyzed by mass spectrometry. The degradation of the polysaccharide caused by the extremal mechanical and mechanochemical treatment of amylose macromolecules was investigated. The formation of an appreciable amount of low-molecular oligomers was explained by the predominant cleavage of chains near the boundary zones of crystallites.  相似文献   
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