An experimental study of choked foam flows in a convergent-divergent' nozzle

Choked flow of a foam in a convergent-divergent nozzle has been investigated. The foam consisted of air and a solution of a surface active agent in water. The upstream gas-liquid volume ratio $\text{δ}{}_0$ was in the range 0.053–1.57. The experimental results are in very good agreement with a homogeneous frictionless nozzle flow theory, assuming isothermal behaviour of the gas and no relative motion between the phases, for throat gas-liquid volume ratios $\text{δ}{}_1$ as high as 0.8; for ratios in the range $\text{0.8 < δ}{}_{\mathrm{t}}\text{< 2.98}$ the agreement, while only approximate, is still quite close. Departures from the homogeneous theory are explained in terms of (a) the failure of the assumption of the isothermal behaviour and (b) the existence of relative velocity between the phases. The latter effect predominates at low values of $\text{δ}{}_1$ but at large values, it appears that both contribute to errors in the predictions.     

Imidazolium Based Probes for Recognition of Biologically and Medically Relevant Anions

The imidazolium derivatives due to their positive charge possess one of the most polarized and positively charged proton at C2‐H to form strong ionic hydrogen bond (also termed as double ionic hydrogen bond) with anions and also provide opportunities for anion – π interactions with electron‐deficient imidazolium ring. In the present review article, imidazolium based molecular probes for their ability to recognize inorganic anions like halides, cyanide, perchlorate, carboxylic acids, phosphate, sulfate etc. and their derived molecules viz. nucleotides, DNA, RNA, surfactants, proteins, etc have been discussed. The review covers the literature published after year 2009 and has > 130 references. The previous literature has already been discussed by Yoon et al. in two review articles published in Chem. Soc. Rev. 2006 and 2010.     

Synthesis,Spectroscopy, and Structures of Mono‐ and Dinuclear Copper(I) Halide Complexes with 1,3‐Imidazolidine‐2‐thiones

Copper(I) halides with triphenyl phosphine and imidaozlidine‐2‐thiones (L ‐NMe, L ‐NEt, and L ‐NPh) in acetonitrile/methanol (or dichloromethane) yielded copper(I) mixed‐ligand complexes: mononuclear, namely, [CuCl(κ¹‐S‐L ‐NMe)(PPh₃)₂] ( 1 ), [CuBr(κ¹‐S‐L ‐NMe)(PPh₃)₂] ( 2 ), [CuBr(κ¹‐S‐L ‐NEt)(PPh₃)₂] ( 5 ), [CuI(κ¹‐S‐L ‐NEt)(PPh₃)₂] ( 6 ), [CuCl(κ¹‐S‐L ‐NPh)(PPh₃)₂] ( 7 ), and [CuBr(κ¹‐S‐L ‐NPh)(PPh₃)₂] ( 8 ), and dinuclear, [Cu₂(κ¹‐I)₂(μ‐S‐L ‐NMe)₂(PPh₃)₂] ( 3 ) and [Cu₂(μ‐Cl)₂(κ¹‐S‐L ‐NEt)₂(PPh₃)₂] ( 4 ). All complexes were characterized with analytical data, IR and NMR spectroscopy, and X‐ray crystallography. Complexes 2 – 4 , 7 , and 8 each formed crystals in the triclinic system with P$\bar{1}$ space group, whereas complexes 1 , 5 , and 6 crystallized in the monoclinic crystal system with space groups P2₁/c, C2/c, and P2₁/n, respectively. Complex 2 has shown two independent molecules, [(CuBr(κ¹‐S‐L ‐NMe)(PPh₃)₂] and [CuBr(PPh₃)₂] in the unit cell. For X = Cl, the thio‐ligand bonded to metal as terminal in complex 4 , whereas for X = I it is sulfur‐bridged in complex 3 .     

Non-destructive evaluation of scientific and biological samples by scattering of 145 keV gamma rays

The objective of present experiment is to assign effective atomic number (Z_eff) to samples of scientific interest (oxides of lanthanoids, also called rare earths, and alloys of lead and tin of known composition) and to measure stable iodine content of tissue (biological sample). An HPGe semiconductor detector, placed at 70° to the incident beam, detects gamma photons scattered from the sample under investigation. The experiment is performed on various elements with atomic number satisfying, 6 ≤ Z ≤ 82, for 145 keV incident photons. The intensity ratio of Rayleigh to Compton scattered peaks, corrected for photo-peak efficiency of gamma detector and absorption of photons in the sample and air, is plotted as a function of atomic number and constituted a fit curve. From this fit curve, the respective effective atomic numbers of the scientific samples are determined. The agreement of measured values of Z_eff with theoretical calculations is found to be quite satisfactory. The measured intensity ratio from phantom (KI solutions, simulating thyroid content of stable iodine) varies linearly with KI concentration and provides stable iodine content of tissue.     

Decay Analysis of Ge Isotopes Formed in Reactions Induced by Tightly and Loosely Bound Projectiles

The dynamical cluster-decay model (DCM) is employed to investigate the decay of ^68,70Ge^* compound nuclei formed respectively via tightly (⁴He) and loosely (⁶He) bound projectiles, using ⁶⁴Zn target. The study is carried out over a wide energy range (E_c.m.~5 MeV to 16 MeV) by including the quadrupole deformations (β2i) and optimum orientations (θ_i^opt) of the decaying fragments. The fusion cross-sections, obtained by adding various evaporation channels show nice agreement with the experimental data for ⁴He+⁶⁴Zn reaction. The contribution from competing compound inelastic scattering channel is also analyzed particularly for ⁶⁸Ge^* nucleus at above barrier energies. On the other hand, the decrement in the fusion cross-sections of ⁷⁰Ge^* nuclear system is addressed by presuming that ⁶⁵Zn ER is formed via two different modes:(i) the αn evaporation of ⁷⁰Ge^* nucleus, and (ii) 1n-evaporation of ⁶⁶Zn^* nuclear system, formed via breakup and 2n-transfer channels due to halo structure of the ⁶He projectile. Besides this, the suppression in 2np evaporation cross-sections suggests the contribution of another breakup and transfer process of ⁶He i.e. ⁴He+⁶⁴Zn. The contribution of breakup+transfer channels for ⁶He+⁶⁴Zn reaction is duly addressed by applying relevant energy corrections due to the breakup of " ⁶He" projectile into 2n and ⁴He. In addition to this, the barrier lowering, angular momentum and energy dependence effects are also explored in view of the dynamics of chosen reactions.     

Experimental evaluation of effective atomic number of composite materials using back-scattering of gamma photons

A method has been presented for calculation of effective atomic number (Z_eff) of composite materials, by using back-scattering of 662?keV gamma photons obtained from a ¹³⁷Cs mono-energetic radioactive source. The present technique is a non-destructive approach, and is employed to evaluate Z_eff of different composite materials, by interacting gamma photons with semi-infinite material in a back-scattering geometry, using a 3^″?×?3^″ NaI(Tl) scintillation detector. The present work is undertaken to study the effect of target thickness on intensity distribution of gamma photons which are multiply back-scattered from targets (pure elements) and composites (mixtures of different elements). The intensity of multiply back-scattered events increases with increasing target thickness and finally saturates. The saturation thickness for multiply back-scattered events is used to assign a number (Z_eff) for multi-element materials. Response function of the 3^″?×?3^″ NaI(Tl) scintillation detector is applied on observed pulse-height distribution to include the contribution of partially absorbed photons. The reduced value of signal-to-noise ratio interprets the increase in multiply back-scattered data of a response corrected spectrum. Data obtained from Monte Carlo simulations and literature also support the present experimental results.