全文获取类型
收费全文 | 4033篇 |
免费 | 437篇 |
国内免费 | 259篇 |
专业分类
化学 | 2673篇 |
晶体学 | 15篇 |
力学 | 171篇 |
综合类 | 22篇 |
数学 | 562篇 |
物理学 | 1286篇 |
出版年
2024年 | 13篇 |
2023年 | 68篇 |
2022年 | 91篇 |
2021年 | 107篇 |
2020年 | 111篇 |
2019年 | 98篇 |
2018年 | 82篇 |
2017年 | 65篇 |
2016年 | 155篇 |
2015年 | 123篇 |
2014年 | 174篇 |
2013年 | 263篇 |
2012年 | 354篇 |
2011年 | 329篇 |
2010年 | 241篇 |
2009年 | 201篇 |
2008年 | 286篇 |
2007年 | 217篇 |
2006年 | 206篇 |
2005年 | 190篇 |
2004年 | 157篇 |
2003年 | 166篇 |
2002年 | 135篇 |
2001年 | 103篇 |
2000年 | 79篇 |
1999年 | 73篇 |
1998年 | 48篇 |
1997年 | 64篇 |
1996年 | 70篇 |
1995年 | 50篇 |
1994年 | 45篇 |
1993年 | 42篇 |
1992年 | 30篇 |
1991年 | 23篇 |
1990年 | 33篇 |
1989年 | 19篇 |
1988年 | 20篇 |
1987年 | 14篇 |
1986年 | 20篇 |
1985年 | 19篇 |
1984年 | 22篇 |
1983年 | 13篇 |
1982年 | 14篇 |
1981年 | 8篇 |
1980年 | 18篇 |
1979年 | 14篇 |
1978年 | 7篇 |
1976年 | 8篇 |
1974年 | 5篇 |
1972年 | 5篇 |
排序方式: 共有4729条查询结果,搜索用时 15 毫秒
41.
42.
A novel local principal component analysis (LPCA) technique is presented for activation signal detection in functional magnetic resonance imaging (fMRI) without explicit knowledge about the shape of the model activation signal. Unlike the traditional PCA methods, our LPCA algorithm is based on a measure of separation between two clusters formed by the signal segments in active periods and inactive periods, which is computed in an eigen-subspace. In addition, we only applied PCA to the temporal sequence of each individual voxel instead of applying PCA to the fMRI data set. In our algorithm, we first applied a linear regression procedure to alleviate the baseline drift artifact. Then, the baseline-corrected temporal signals were partitioned into active and inactive segments according to the paradigm used for the fMRI data acquisition. Principal components were computed from all these segments for each voxel by PCA. By projecting the segments of each voxel onto a linear subspace formed by the corresponding most dominant principal components, two separate clusters were formed from active and inactive segments. An activation measure was defined based on the degree of separation between these two clusters in the projection space. We show experimental results on the activation signal detection from various sets of fMRI data with different types of stimulation by using the proposed LPCA algorithm and the standard t-test method for comparison. Our experiments indicate that the LPCA algorithm in general provides substantial signal-to-noise ratio improvement over the t-test method. 相似文献
43.
The synthesis of novel symmetrical liquid crystalline compounds based on 5-methyl-5-[2-(4-alkyloxyphenyl)-2-hydroxyethyl]-2,2-bipyridines is reported, together with some physical properties. Although the chelating head-groups are connected via a chiral sp3 carbon atom, all the materials are mesomorphic. Intermolecular hydrogen bonding between pyridino and hydroxy fragments in the mesophases is made apparent by FTIR spectroscopy. 相似文献
44.
Anisotropic energy distribution of sputtered atoms induced by low energy heavy ion bombardment 总被引:1,自引:0,他引:1
Lai Zhang 《辐射效应与固体损伤》2013,168(8):337-347
The theory of anisotropic sputtering published in Phys. Rev. B 71(2), 026101 (2005) and Radiat. Effects Defects Solids 159(5), 301 (2004) has been modified and used to calculate the sputtering yield energy distributions for copper, tungsten, and aluminum targets bombarded by low-energy argon ion. As usual, the electronic stopping is ignored in the analysis. The present theory (modified Sigmund’s theory) has been shown to fit the corresponding experimental results of sputtering yield energy distributions well, except for the cases where the larger ion incident angle and larger sputtering emission angles were considered. The larger discrepancy between the present theory and the experimental result in the latter cases is probably due to the influence of direct recoil atoms on the energy spectrum. Compared with Falcone’s analytical theory, the present theory can reproduce much better experimental results of sputtering phenomena. The fact clearly demonstrates the intrinsic relation between the ion–energy dependence of the total sputtering yield and the sputtering yield energy distribution and suggests the great importance of momentum deposited on the target surface in the physical sputtering 相似文献
45.
A tunable optical rail is embedded into the cavity of a nonlinear-polarization-rotation(NPR) mode-locked fiber laser to generate a sampling pulse with different repetition frequencies and realize bit-rate-adaptive software synchronous optical sampling.Two ultrashort pulses(20.26677 and 20.22900 MHz) are derived,and a 100-MHz data signal is sampled twice with these pulses based on sum-frequency generation(SFG) in periodically poled lithium niobate(PPLN).The eye diagram is successfully recovered,and an estimated bit rate of 102.22 MHz is derived.This method is feasible for bit rates ranging from 200 MHz to 1 GHz,with <3% relative error. 相似文献
46.
采用一种新的种子层材料:(Ni081Fe019)1-xCrx,通过改变种子层中Cr原子的含量,使得在其上生长的NiFeFeMn双层膜的织构和晶粒尺寸产生极大的差异,系统研究了NiFeFeMn双层膜中FeMn晶粒尺寸和织构对交换偏置的影响.实验结果表明,在FeMn的γ相(111)织构较好的前提下,交换偏置场的大小与织构的差异没有关系;FeMn的晶粒尺寸对交换偏置场有很大影响,较小的反铁磁层晶粒对交换偏置场有利,过大的反铁磁层晶粒不利于交换偏置场.将(Ni081Fe019)05Cr05与传统的种子层材料Ta进
关键词:
交换偏置
晶粒尺寸
织构
种子层 相似文献
47.
以波长为780 nm、重复频率为76 MHz、脉宽为130 fs的飞秒激光作为激发光源, 采用超快时间分辨光谱技术研究了CdTe量子点-铜酞菁复合体系的荧光共振能量转移. 实验结果表明, 在780 nm的双光子激发条件下, 复合体系中CdTe量子点的荧光寿命随着铜酞菁溶液浓度的增加而减少, 荧光共振能量转移效率增加. 同时也研究了激发功率对荧光共振能量转移效率的影响. 结果表明, 随着激发光功率的增加, 复合体系溶液中CdTe量子点的荧光寿命增加, 荧光共振能量转移效率减小, 其物理机理是因为高激发功率下的热效应和由双光子诱导的高阶激发态的跃迁. 当激发光功率为200 mW时, 双光子荧光共振能量转移效率为43.8%. 研究表明CdTe量子点-铜酞菁复合体系是非常有潜力的第三代光敏剂. 相似文献
48.
根据等效颗粒散射模型,运用经典的Mie理论,对生物组织的散射相函数、各向异性因子及散射系数进行了数值计算.计算结果表明:可见光照射生物组织时,各向异性因子、散射系数随等效颗粒直径增大而增大;等效颗粒直径较小时,各向异性因子、散射系数随入射光波长增大而单调减小;随着等效颗粒直径增大,各向异性因子、散射系数随入射光波长变化不再具有单调性.上述计算结果可合理解释公布的实验结果.
关键词:
生物组织
散射
Mie理论
等效颗粒 相似文献
49.
利用飞秒时间分辨抽运-探测反射光谱技术研究了室温下Ge2Sb2Te5非晶薄膜中载流子超快动力学及其激发能量密度依赖性.发现光激发后05 ps时间内,反射变化率降到最小值,然后开始迅速增加,在几个皮秒时间内达到大于初始反射率的新的最大值.反射率的减小量、增加量和增加速率均随激发能量密度的增大而增加.利用高密度等离子体的Auger复合及其感应的晶格加热模型较好地定量解释了反射率由最小到最大的快速变化过程,表明高密度等离子体的Auger复合加热
关键词:
抽运-探测光谱
2Sb2Te5非晶薄膜')" href="#">Ge2Sb2Te5非晶薄膜
Auger复合
载流子动力学 相似文献
50.
Triphenylamine derivatized phenylacetylene macrocycle with large two-photon absorption cross-section
Zhen Fang Marek SamocRichard D. Webster Anna SamocYee-Hing Lai 《Tetrahedron letters》2012,53(36):4885-4888
A phenylacetylene macrocycle (PAM) derivative containing triphenylamine as the framework was synthesized in one-step Sonogashira coupling. The photophysical and electrochemical properties were investigated in details. This hexamer shows significant enhancement in two-photon absorption cross-section relative to reported PAM derivatives. 相似文献