基于时变功率谱的激光器调谐瞬时线宽测量方法研究

半导体激光器的线宽通常采用激光外差测量技术,通过差拍信号的功率谱密度函数来确定,受傅里叶变换方法的限制,得到的均是在一定时间段内的静态平均线宽。为了获得半导体激光器在电流调谐过程中的瞬时线宽特性,提出了利用时变功率谱获知调谐瞬时线宽的相干和非相干测量方法,并分别进行了理论分析和实验验证。首先对半导体激光器输出光信号及差拍信号进行了时间-频率域下的数学描述,确定了时变功率谱与调谐瞬时线宽的关系;其次,针对差拍信号的趋向性特征,提出了趋势局部均值分解方法,并研究了利用分解出的乘积函数建立差拍信号及激光器输出光信号的时变功率谱的方法;最后利用非相干和相干测量法分别获得了分布反馈式半导体激光器在50~51及50~100 mA锯齿波电流调谐过程中的瞬时线宽。     

A Novel 3D Metal Organic Framework Based on an Azolate Ligand

Metal organic frameworks（MOFs） have attracted much attention over the world during the last several decades[1-3].Constructed from metal ions and organic building units,MOFs have great properties in gas adsorption[4],catalysis[5],luminescence[6] and magnetism[7].By varying the metal salts and organic building units,numerous MOF structures with designed functionalities and expected properties can be obtained.Among them,zeolitic imidazolate frameworks（ZIFs） have been investigated greatly due to their high thermal and chemical stabilities and tunable porosities[8].ZIFs can be obtained with imidazolate compounds as organic building units,such as imidazole,benzimidazole and 2-methylimidazole[9].Zeolite structures are composed of tetrahedral Si（Al）O4 units,with Si-O-Si angle ca.145°.ZIFs possess imidazole,with M-IM-M（M-metal,IM=imidazole） angle close to 145°,resembling zeolite（Scheme 1）[10].     

CoFe2O4纳米颗粒的制备及其磁学性能

采用溶胶凝胶法制备了CoFe2O4纳米颗粒,分别使用聚乙烯醇(PVA)和聚乙二醇(PEG)作为分散、凝胶剂,用X射线衍射仪(XRD)、扫描电子显微镜(SEM)和综合物性测量系统(PPMS)对CoFe2O4纳米颗粒的结构组成及物相、形貌尺寸和磁学性能进行分析研究.对比了两种分散剂制备的CoFe2O4纳米颗粒的磁学性能,并研究了不同量的PEG对CoFe2O4纳米颗粒的磁学性能的影响.结果表明:用PEG制得的CoFe2O4纳米颗粒的饱和磁化强度(143.11 emu/g)比用PVA制备的CoFe2O4纳米颗粒的饱和磁化强度(62.81 emu/g)大很多,其主要原因是Co2+在A位和B位的重新分布;PEG用量不同时,得到的CoFe2O4纳米颗粒尺寸不同,而颗粒尺寸大小又是影响CoFe2O4纳米颗粒的饱和磁化强度的主要因素;用4 gPEG制备的CoFe2O4纳米颗粒的形貌、尺寸和磁学性能最好.     

基于PSD的高精度光电定心仪

针对目前定心仪精度不高、并依赖于人眼的现状,提出一种基于PSD的高精度定心仪研究方法。采用自准直光路形式和位置敏感探测器PSD对经过被测目标返回的光斑实行定位,并通过读取计算机上的坐标值来判断是否达到准确的定心。文中对定心仪的光学系统进行设计,并运用神经网络的训练来校正PSD的非线性,在测量范围2 mm~500 mm内定心精度达到1 m的设计要求。     

A Laplace Decomposition Method for Nonlinear Partial Differential Equations with Nonlinear Term of Any Order

A Laplace decomposition algorithm is adopted to investigate numerical solutions of a class of nonlinear partial differential equations with nonlinear term of any order, utt ＋ auxx ＋ bu ＋ cup ＋ du^2p-1 = 0, which contains some important equations of mathematical physics. Three distinct initial conditions are constructed and generalized numerical solutions are thereby obtained, including numerical hyperbolic function solutions and doubly periodic ones. Illustrative figures and comparisons between the numerical and exact solutions with different values of p are used to test the efficiency of the proposed method, which shows good results are azhieved.     

4 mm腔长高功率单管半导体激光器封装应力的研究

为了减小长腔长高功率单管半导体激光器在封装过程中引入的热应力,根据应力改变禁带宽度的原理,理论上推导了应力与波长漂移的关系,提出了一种通过测量激光器脉冲条件下的光谱来定量计算激光器应力的方法。利用这种方法得到的研究结果表明,焊接质量直接决定着应力的大小,由焊接质量的不同引起的应力差值超过了300 MPa,提出了优化焊接回流曲线的方法,使激光器的应力由原来129.7 MPa降低到53.4 MPa,该方法还有效的解决了封装应力随储存时间变化的问题。实验表明,激光器光谱图的测量分析是研究高功率单管半导体激光器封装应力的有效方法,也是检测分析烧结工艺的有效手段。     

Prototype of time digitizing system for BESⅢ endcap TOF upgrade

The prototype of a time digitizing system for the BESⅢ endcap TOF (ETOF) upgrade is introduced in this paper. The ETOF readout electronics has a distributed architecture. Hit signals from the multi-gap resistive plate chamber (MRPC) are signaled as LVDS by front-end electronics (FEE) and are then sent to the back-end time digitizing system via long shield differential twisted pair cables. The ETOF digitizing system consists of two VME crates, each of which contains modules for time digitization, clock, trigger, fast control, etc. The time digitizing module (TDIG) of this prototype can support up to 72 electrical channels for hit information measurement. The fast control (FCTL) module can operate in barrel or endcap mode. The barrel FCTL fans out fast control signals from the trigger system to the endcap FCTLs, merges data from the endcaps and then transfers to the trigger system. Without modifying the barrel TOF (BTOF) structure, this time digitizing architecture benefits from improved ETOF performance without degrading the BTOF performance. Lab experiments show that the time resolution of this digitizing system can be lower than 20 ps, and the data throughput to the DAQ can be about 92 Mbps. Beam experiments show that the total time resolution can be lower than 45 ps.     

Ag+/Ag/ZnO多孔纳米结构纤维材料的制备及可见光催化性能

借助棉花纤维模板, 采用两步法制备了Ag⁺/Ag/ZnO多孔纳米结构纤维材料, 并利用X射线衍射(XRD)、 X射线光电子能谱(XPS)、 扫描电子显微镜(SEM)和紫外-可见光谱(UV-Vis)等对其进行了表征. 以亚甲基蓝(MB)的脱色降解为模型反应, 考察了银修饰量(摩尔分数, 0~1.50%)对ZnO纳米结构纤维材料光催化性能的影响. 结果表明, 利用模板辅助的两步法制备了Ag⁺-Ag共修饰的ZnO多孔纳米结构纤维材料Ag⁺/Ag/ZnO, Ag⁺和Ag通过改变ZnO的晶胞结构、 光吸收特性及形貌等影响其光催化性能; 在可见光条件下, Ag⁺/Ag/ZnO的催化性能优于纯ZnO, 且与修饰量有关.     

含乙撑桥键二苯炔四环液晶的合成及性能

以4-烷基反式环己基甲酸为原料, 经格氏、 黄鸣龙、 碘代及“一锅法”Sonogashira偶联等反应, 制备了10个含乙撑桥键二苯炔四环液晶化合物, 其结构经IR, NMR和MS确认. 利用差示扫描量热仪(DSC)、 偏光显微镜(POM)和阿贝折光仪对目标化合物进行了性能测试. 结果表明, 目标化合物具有高清亮点(220~240 ℃)、 宽向列相区间(59.6~99.6 ℃)和大光学各向异性(Δn>0.3), 其性能可满足液晶光学的应用要求.     

单分散纳米钛酸钡晶体的微波水热合成与表征——推荐一个研究型综合实验

介绍一个研究型综合实验——微波法合成单分散纳米钛酸钡晶体及其表征。采用廉价易得的原料,以微波水热合成法在短时间内（2 h）制备出粒径10～20 nm、单分散、长方体块形纳米钛酸钡晶体。利用X射线粉末衍射、红外光谱、激光拉曼光谱、接触角仪、热重分析和透射电子显微镜对产物的晶相结构、表面性质、形貌等进行表征。该实验既迎合现代科研的热点,又满足教学要求,同时,其很强的拓展性非常适用于培养学生的科研创新能力。