Graphite and graphene as perfect spin filters

Based upon the observations (i) that their in-plane lattice constants match almost perfectly and (ii) that their electronic structures overlap in reciprocal space for one spin direction only, we predict perfect spin filtering for interfaces between graphite and (111) fcc or (0001) hcp Ni or Co. The spin filtering is quite insensitive to roughness and disorder. The formation of a chemical bond between graphite and the open d-shell transition metals that might complicate or even prevent spin injection into a single graphene sheet can be simply prevented by dusting Ni or Co with one or a few monolayers of Cu while still preserving the ideal spin-injection property.     

New laser plasma process to obtain solid coatings and their structural characteristics

Carbon nitride coatings are synthesized in the new laser plasma of powerful optical pulsating discharge using acetonitrile as a precursor. A high-pressure and -temperature C₃N₄ cubic phase with a spinel structure type is obtained. The microhardness of coatings of this structure type is ~45 gPa. The chemical composition and structure of the coatings are characterized by a complex of spectroscopic (IR, Raman, EDS) techniques as well as microscopic (AFM and XRD) techniques.     

Modular structure of a potassium-rich analogue of eudialyte with a doubled parameter c

The structure of a new potassium-rich representative of the eudialyte group described by the idealized formula Na₂₇K₈Ca₁₂Fe₃Zr₆[Si₅₂O₁₄₄](O,OH,H₂O)₆Cl₂ was established by the methods of the X-ray diffraction analysis (R = 0.045, 3900 reflections). The unit-cell parameters are a = 14.249(1) Å, c = 60.969(7) Å, V = 10 720.3 ų, sp. gr. R3m. The structure of the mineral is characterized by in-layer order in cation arrangement resulting in doubling of the parameter c and the formation of two different modules, of which one corresponds to composition and structure of eudialyte (with an admixture of kentbrooksite) and the other is the derivative of alluaivite.     

On the possibility of reprocessing spent nuclear fuel and radioactive waste by plasma methods

The concept of plasma separation of spent nuclear fuel and radioactive waste is presented. An approach that is based on using an accelerating potential to overcome the energy and angular spread of plasma ions at the separation region inlet and utilizing a potential well to separate spatially the ions of different masses is proposed. It is demonstrated that such separation may be performed at distances of about 1 m with electrical potentials of about 1 kV and a magnetic field of about 1 kG. The estimates of energy consumption and performance of the plasma separation method are presented. These estimates illustrate its potential for technological application. The results of development and construction of an experimental setup for testing the method of plasma separation are presented.     

Luminescent properties of solid solutions in the PbF<Subscript>2</Subscript>–Euf<Subscript>3</Subscript> system and lead fluoroborate glass ceramics doped with Eu<Superscript>3+</Superscript> ions

Lead fluoroborate glasses doped with Eu³⁺ are synthesized, studied, and used to produce glassceramics by heat treatment. The structure of glass-ceramics is determined by X-ray diffraction. The optical, mechanical, and luminescent properties of the glass-ceramics are studied. The structure and spectral-luminescent properties of solid solutions in the PbF₂–EuF₃ system obtained by both solid-phase reaction and coprecipitation from solutions are investigated.     

Structural characteristics of Na,Fe-decationated eudialyte with the symmetry <Emphasis Type="Italic">R</Emphasis>3

The crystal structure of a new highly decationated representative of the eudialyte group has been established (R = 0.055, 1734 |F|). The mineral is described by the simplified formula (H₃O)₉Na₂(K, Ba,Sr)₂Ca₆Zr₃[Si₂₆O₆₆(OH)₆](OH)₃Cl · H₂O (Z = 3). The unit-cell parameters are a = 14.078(3) Å, c = 31.24(1) Å; V = 5362 ų; sp. gr. R3. Being chemically and structurally related to the hydrated analogues studied previously (in particular, to potassium oxonium eudialyte), the new mineral differs from its analogues in that it has a higher degree of Na-and Fe-cation depletion. The replacement of 3/4 of Na cations by loose and mobile H₃O groups results in structure destabilization, which is seen from the high values of the thermal parameters of the atoms and the loss of the symmetry plane.     

非平衡态/不可逆过程的热力学理论(Ⅱ)

<正> 7 解的唯一性 如果不考虑非平衡态和不可逆性,则等能密度理论中的基本命题与经典弹性理论中的在形式上完全相同。无论整个系统的动能是大还是小,图6中(sumform)_o上的面力T_i和在(sumform)_c和在的位移u_i将始终在空间坐标系x_i和时刻i下给出。与一般力学中相同,必须知道有关位移u_i及其时间导数的初始条件。它们的影响则可通过(38)和(39)向等能面转化,从而得到     

Experimental Investigation of the Transverse Self-Oscillations of Circular Cylinders Mounted with a Narrow Clearance in a Plane Channel

The results of an investigation of the flow past and the behavior of free bluff bodies mounted in pipes and channels with a narrow clearance, conducted in the Institute of Mechanics of Moscow State University, are presented. The drag of circular cylinders of different size and mass in a circulation-free water flow in a plane channel of rectangular cross-section was studied in the transverse self-oscillation regime. The experiments were conducted for Reynolds numbers based on the cylinder diameter 1.7 ? 10⁴ ≤ Re ≤ 7.2 ? 10⁴, relative clearances \(\bar S\) based on a cross-sectional area ranging from 0.76 to 0.9, and cylinder-to-water density ratios ρ _c /ρ ranging from 1.29 to 8.2. Only the case of intense transverse self-oscillations accompanied by impact interaction with the channel wall was considered. The dependence of the period-average cylinder drag coefficient C _x on the basic dimensionless relevant parameters is obtained. The dependence of the dimensionless self-oscillation frequency determined in [1] is refined. The kinematic and dynamic features of the flows past spheres in cylindrical pipes and cylinders in plane channels are compared in the transverse self-oscillation regime.