Relative population of oblate and prolate structures in189Au

High spin states of¹⁸⁹Au were populated via the¹⁷⁴Yb (¹⁹F, 4n reaction at 86, 90, 95 and 100 MeV beam energies. The study of the relative population of oblate and prolate structures shows a striking disappearance of the prolate band relative to the oblate ones as the beam energy goes from 86 to 100 MeV.     

Lifetimes of a dipole cascade in 192Hg

The β-spectrum of the 3^?-2⁺ transition in the decay of¹⁴⁶Pm has been investigated with a 4π-Si(Li)-semiconductor spectrometer in a β-γ-coincidence experiment for the first time. The shape factor has been determined: C(W)=1?0.394W}-0.275/W+0.044 W². The spin and parity of the ground state of¹⁴⁶Pm can be determined to be 3^?. The shape of this non-allowed spectrum indicates the existence of the “cancellation” or “selection rule” effect.     

Ferromagnetism,half-metallicity and spin-polarised electronic structures characterisation insights in Ca1−xTixO

ABSTRACT

In this study, we have computed the structural, electronic and half-metallic ferromagnetic properties of Ca_1?xTi_xO compounds at concentrations x?=?0.125, 0.25, 0.5 and 0.75 by employing the first-principle approaches of density functional theory. The generalised gradient approximation of Wu and Cohen (GGA-WC) is used to calculate the structural parameters, whereas the electronic structures and magnetic properties are characterised by the accurate Tran–Blaha-modi?ed Becke–Johnson potential (TB-mBJ). The lattice constant, bulk modulus and indirect gap of CaO are in good agreement with other theoretical and experimental results. The Ca_0.25Ti_0.75O at x?=?0.75 has metallic ferromagnetic nature. The Ca_0.875Ti_0.125O, Ca_0.75Ti_0.25O and Ca_0.50Ti_0.50O compounds have total magnetic moments of 2?μ_B per Ti atom with a half-metallic character, a spin polarisation of 100% and a large half-metallic gap of 1.345?eV for x?=?0.125. Therefore, the Ca_1?xTi_xO material with a low concentration of Ti is a true half-metallic ferromagnet and seems to be a promising candidate for semiconductor spintronics.     

Synthesis,Structure and Impact of 5-Aminoorotic Acid and Its Complexes with Lanthanum(III) and Gallium(III) on the Activity of Xanthine Oxidase

The superoxide radical ion is involved in numerous physiological processes, associated with both health and pathology. Its participation in cancer onset and progression is well documented. Lanthanum(III) and gallium(III) are cations that are known to possess anticancer properties. Their coordination complexes are being investigated by the scientific community in the search for novel oncological disease remedies. Their complexes with 5-aminoorotic acid suppress superoxide, derived enzymatically from xanthine/xanthine oxidase (X/XO). It seems that they, to differing extents, impact the enzyme, or the substrate, or both. The present study closely examines their chemical structure by way of modern methods—IR, Raman, and ¹H NMR spectroscopy. Their superoxide-scavenging behavior in the presence of a non-enzymatic source (potassium superoxide) is compared to that in the presence of an enzymatic source (X/XO). Enzymatic activity of XO, defined in terms of the production of uric acid, seems to be impacted by both complexes and the pure ligand in a concentration-dependent manner. In order to better relate the compounds’ chemical characteristics to XO inhibition, they were docked in silico to XO. A molecular docking assay provided further proof that 5-aminoorotic acid and its complexes with lanthanum(III) and gallium(III) very probably suppress superoxide production via XO inhibition.     

Two proton high-spin excitations and dipole bands in192Hg

The¹⁹²Hg nucleus was populated in the¹⁶⁰Gd(³⁶S, 4n) reaction at a beam energy of E=159 MeV. Emittedγ-rays were detected with the EUROGAM array comprising 43 Compton-suppressed large volume Ge detectors. The level scheme of¹⁹²Hg has been extended up to an excitation energy of E=10.4 MeV and spin I=34 ?. Two new structures, made of competing ΔI=1 and ΔI=2 transitions have been observed and their connexions with the low-lying levels established. Their lowest levels are located at 6.304 MeV and 6.879 MeV excitation energy. The experimental results are compared with mean-field HF+BCS calculations. It is proposed that the new structures originate from deformation-aligned quasi-proton excitations π(i_13/2 * h_9/2)_K=11 andπ (h_9/2) _K=8 ² , coupled to rotation-aligned quasi-neutron ν(i_13/2)ⁿ and quasi-proton π(h_11/2)² excitations.     

Gamma-ray feeding and decay of superdeformed states

We report on four recent results concerning the population and the decay of superdeformed states, namely the structure of excited superdeformed states in ¹⁹⁴Hg, the search for fine structure of the last superdeformed transitions in ¹⁹⁴Pb, the primary decay-out strength analysis in ¹⁹⁴Hg and, as a consequence of this, the possibility of using the decay-out as a tool to study order-to-chaos properties of normally deformed states.Received: 3 December 2002, Published online: 17 February 2004PACS: 21.10.Re Collective levels - 23.20.Lv transitions and level energies - 24.60.-k Statistical theory and fluctuations - 24.60.Lz Chaos in nuclear systems - 27.80. + w F. Hannachi: Present address: CENBG/IN2P3, Gradignan, France.H. Amro: Present address: WNSL, Yale, USA.K. Hauschild: Present address: CSNSM/IN2P3, Orsay, France.T. Kröll: Present address: TU, Munich, Germany.M. Rejmund: Present address: GANIL, Caen, France.     

First observation of a superdeformed nucleus produced in an α xn reaction channel

Excited states in the neutron deficient ¹⁴⁵ Dy nucleus have been identified by means of the reaction ¹¹²Sn(³⁵ Cl,pn) at 159 MeV. The level scheme above the 11/2 ^? state and up to spin I～37/2 was obtained using γ-ray spectroscopy methods. The level structure is discussed in terms of the coupling of a h _11/2 neutron hole with the N=80 core excitations.     

Dipole bands and multi-quasiparticle excitations in 193Pb

The nucleus ¹⁹³Pb was populated via the ¹⁶⁸Er(³⁰Si,5n) reaction at a beam energy of 159 MeV and studied with the EUROGAM II spectrometer. Five new dipole Δ I = 1 cascades have been found. These structures have been connected to the level scheme which has been considerably extended up to a spin of ? and an excitation energy of about 8 MeV. Angular distribution coefficients, a₂, have been measured and confirm the dipole character of the in-band transitions. B(M1)/B(E2) ratios have been extracted for the two most intense cascades. The ¹⁹³Pb dipole bands are discussed in comparison with those known in odd lead isotopic series and the structure of the band heads is analyzed in terms of microscopic HF+BCS calculations. The proposed configurations are based on a high-K two quasiproton excitation, π ([505]9/2^t? ? [606]13/2⁺)_K=11^t -, coupled to one or three rotation aligned quasineutrons involving the i_13/2, p _3/2, f_5/2 and/or h{9/2} subshells. The main difference, compared with the heavier lead isotopes, is the presence of large Ω orbitals from the ν (i_13/2) shell near the Fermi surface which are responsible for the increasing band-head spin as A decreases.