全文获取类型
收费全文 | 1523篇 |
免费 | 85篇 |
国内免费 | 24篇 |
专业分类
化学 | 1032篇 |
晶体学 | 15篇 |
力学 | 75篇 |
数学 | 146篇 |
物理学 | 364篇 |
出版年
2024年 | 4篇 |
2023年 | 14篇 |
2022年 | 40篇 |
2021年 | 75篇 |
2020年 | 72篇 |
2019年 | 59篇 |
2018年 | 73篇 |
2017年 | 77篇 |
2016年 | 77篇 |
2015年 | 58篇 |
2014年 | 78篇 |
2013年 | 150篇 |
2012年 | 133篇 |
2011年 | 118篇 |
2010年 | 56篇 |
2009年 | 61篇 |
2008年 | 65篇 |
2007年 | 59篇 |
2006年 | 50篇 |
2005年 | 44篇 |
2004年 | 44篇 |
2003年 | 39篇 |
2002年 | 37篇 |
2001年 | 17篇 |
2000年 | 8篇 |
1999年 | 7篇 |
1998年 | 4篇 |
1997年 | 3篇 |
1996年 | 10篇 |
1995年 | 12篇 |
1994年 | 9篇 |
1993年 | 7篇 |
1992年 | 5篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1983年 | 6篇 |
1982年 | 6篇 |
1981年 | 7篇 |
1980年 | 3篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1970年 | 2篇 |
1969年 | 2篇 |
排序方式: 共有1632条查询结果,搜索用时 15 毫秒
51.
Khalid Naim Manjeet Singh Sachin Sharma Dr. Rajesh V. Nair Prof. Paloth Venugopalan Dr. Subash Chandra Sahoo Dr. Prakash P. Neelakandan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(52):11979-11984
The design of molecular compounds that exhibit flexibility is an emerging area of research. Although a fair amount of success has been achieved in the design of plastic or elastic crystals, realizing multidimensional plastic and elastic bending remains challenging. We report herein a naphthalidenimine–boron complex that showed size-dependent dual mechanical bending behavior whereas its parent Schiff base was brittle. Detailed crystallographic and spectroscopic analysis revealed the importance of boron in imparting the interesting mechanical properties. Furthermore, the luminescence of the molecule was turned-on subsequent to boron complexation, thereby allowing it to be explored for multimode optical waveguide applications. Our in-depth study of the size-dependent plastic and elastic bending of the crystals thus provides important insights in molecular engineering and could act as a platform for the development of future smart flexible materials for optoelectronic applications. 相似文献
52.
Guan-Yeow Yeap Elango Hrishikesan Yi-Huan Chan Wan Ahmad Kamil Mahmood 《Journal of fluorescence》2017,27(1):105-110
A new chalcone-based probe containing coumarin and naphthol at both ends has been synthesized via aldol condensation. The uniqueness of the newly derived probe can be ascribed to the presence of naphthol and coumarin units acting as binding site and signaling element, respectively. The fluorogenic behaviors toward various anions were investigated. The probe was characterized by various spectroscopic techniques and the in-depth study led to show excellent selectivity and sensitivity for fluoride ions. The hydrogen bonding thus formed with fluoride anion provides remarkable fluorometric responses. The interactions of the probe with fluoride ions were determined by fluorescence, FT-IR and NMR spectroscopic techniques. The exploratory studies by fluorescent spectral changes augur well for the naked-eye sensing applications. 相似文献
53.
54.
The results of our investigation on the sensitized luminescence properties of three Eu(III) ??-diketonate complexes of the form [Eu2(fod)6(??-bpm)], [Eu(fod)3(phen)] and [Eu(fod)3(bpy)] and 4f?C4f absorption properties of their Er(III) analogues ( fod = anion of 6,6,7,7,8,8,8- heptafluoro-2,2-dimethyl-3,5-octanedione, bpm = 2,2??-bipyrimidine, phen = 1,10-phenanthroline and bpy = 2,2??-bipyridyl) in a series of non-aqueous solvents are presented. The Eu(III) complexes are highly luminescent and their luminescence properties (intensity and band shape) are sensitive to the changes in the inner coordination sphere of the Eu(III) ion. The luminescence intensity of the mononuclear complexes in pyridine is drastically decreased. The coordination structure of the complexes in pyridine is transformed into a more symmetrical one which results into a slow radiative rate of the emission from the complexes. The ancillary ligands, phen and bpy are found better co-sensitizers as compared to the bpm to sensitize Eu(III)-luminescence. The 4f?C4f absorption properties (oscillator strength and band shape) of the Er(III) complexes demonstrate that 4G11/2 ?? 4I11/2 and 2H11/2 ?? 4I15/2 hypersensitive transitions of Er(III) are very sensitive in some coordinating solvents which reflects complex?Csolvent interaction in solution. The hypersensitive transitions of [Er(fod)3(phen)] remain unaffected in any of the solvents and this complex retains its bulk composition in solution. The erbium complexes as well as the Er(fod)3 chelate are invaded by DMSO. This solvent enters the inner coordination sphere by replacing heterocyclic ligand and the complexes acquire similar structure [Er(fod)3(DMSO)2] in this solvent. The results reveal that the luminescence and absorption properties of lanthanide complexes in solution can be controlled by tuning the coordination structure through ancillary ligands and donor solvents. This work shall prove useful in designing new biological applications with such probes. 相似文献
55.
Khalid Bouras Abdelmonaim El Kaddouri Jawad H’michane Mohammed Moussa 《Rendiconti del Circolo Matematico di Palermo》2012,61(3):355-360
We characterize Banach lattices on which each positive operators is b-weakly compact and we derive some characterizations of KB-spaces. 相似文献
56.
57.
Polypyrrole‐zirconium complex has been synthesized by reacting 2‐amino‐3,4‐dicyano‐5‐mercaptopyrrole with zirconium nitrate in absolute ethanol under reflux for 24 h. The product has been characterized by elemental analyses, FTIR spectroscopy, in addition to thermal analysis (TGA and DSC) and its solubility has been investigated. The DC electrical conductivity variation of polypyrrole‐zirconium complex has been studied in the temperature range 300–500 K after annealing for 24 h at 100°C and doping with I2, FeCl3 and CuCl2 · H2O for comparison. An attempt has been made to interpret the DC electrical conductivity behavior and thermal properties to chain length, dopant used, polymer structure and attached groups. 相似文献
58.
59.
Rahman Hosseinzadeh Mahmood Tajbakhsh Maryam Mohadjerani Parizad Rezaei Mohammad Alikarami 《合成通讯》2013,43(17):3023-3031
An efficient synthesis of diaryl ethers by the copper-catalyzed arylation of phenols with a variety of aryl iodide susing KF/Al2O3 as a suitable base and CuI and 1,3 diphenyl-1,3 propandione as the catalyst is described. 相似文献
60.
An efficient three-step synthesis of COX-2 inhibitor inotilone from acetaldoxime is described. The structure of inotilone was elucidated via an aldol reaction between 5-methyl-3(2H)-furanone and 3,4-dihydroxybenzaldehyde. This approach describes a convenient pathway to 5-alkyl-3-furanones through isoxazole chemistry. 相似文献