Finite element approximation of a model for phase separation of a multi-component alloy with a concentration-dependent mobility matrix

We consider a model for phase separation of a multi-componentalloy with a concentration-dependent mobility matrix and logarithmicfree energy. In particular we prove that there exists a uniquesolution for sufficiently smooth initial data. Further, we provean error bound for a fully practical piecewise linear finiteelement approximation in one and two space dimensions. Finallynumerical experiments with three components in one space dimensionare presented.     

Explosions of xenon clusters in ultraintense femtosecond x-ray pulses from the LCLS free electron laser

Explosions of large Xe clusters ( ~ 11,000) irradiated by femtosecond pulses of 850 eV x-ray photons focused to an intensity of up to 10(17) W/cm(2) from the Linac Coherent Light Source were investigated experimentally. Measurements of ion charge-state distributions and energy spectra exhibit strong evidence for the formation of a Xe nanoplasma in the intense x-ray pulse. This x-ray produced Xe nanoplasma is accompanied by a three-body recombination and hydrodynamic expansion. These experimental results appear to be consistent with a model in which a spherically exploding nanoplasma is formed inside the Xe cluster and where the plasma temperature is determined by photoionization heating.     

Synthesis of nanocomposite, (CdxZn1-x)S by gamma-irradiation in an aqueous system

Gamma-irradiation has been applied to synthesize the nanocomposite semiconductor constituted of zinc and cadmium sulfide Cd_1-xZn_xS ultra fine particles at room temperature by utilizing homogeneous release of S^2– ions from the decomposition of sodium thiosulfate. The structure, morphology, size and optical properties of that compound have been studied by X-ray powder diffraction (XRD), transmission electron microscopy (TEM) and ultraviolet-visible spectrometer (UV-visible). The product obtained from irradiated solutions containing zinc ions, cadmium ions and the sulfur source has been characterized as a composite of (Cd_xZn_1-x)S, with spherical morphology and with a diameter of average size of about 5.3 nm. The possible mechanism of formation of the composite is proposed.The financial support of Shanghai Science and Technology Foundation through No. 0252nm 095 is gratefully acknowledged.The authors would thank the staff of Shanghai Applied Radiation Institute of Shanghai University for their valuable contributions.     

Electron beam excitation studies of potential dye vapor phase laser systems

Excitation processes of selected dye vapor-rare gas mixtures pumped by an electron beam have been studied. These experiments revealed the importance of effective collisional electron energy transfer pumping via a dense rare gas rather than a radiative energy transfer from an excimer laser gas mixture to achieve population inversion in an organic dye vapor. Work supported in part by the Energy Research and Development Adinistration, the Robert A. Welch Foundation and the National Science Foundation.     

MBO(N)D: A multibody method for long‐time molecular dynamics simulations

A modeling approach that can significantly speed up the dynamics simulation of large molecular systems is presented herein. A multigranular modeling approach, whereby different parts of the molecule are modeled at different levels of detail, is enabled by substructuring. Substructuring the molecular system is accomplished by collecting groups of atoms into rigid or flexible bodies. Body flexibility is modeled by a truncated set of body‐based modes. This approach allows for the elimination of the high‐frequency harmonic motion while capturing the low‐frequency anharmonic motion of interest. This results in the use of larger integration step sizes, substantially reducing the computational time required for a given dynamic simulation. The method also includes the use of a multiple time scale (MTS) integration scheme. Speed increases of 5‐ to 30‐fold over atomistic simulations have been realized in various applications of the method. © 2000 John Wiley & Sons, Inc. J Comput Chem 21: 159–184, 2000     

Gas and Pressure Dependence for the Mean Size of Nanoparticles Produced by Laser Ablation of Flowing Aerosols

Silver nanoparticles were produced by laser ablation of a continuously flowing aerosol of microparticles entrained in argon, nitrogen and helium at a variety of gas pressures. Nanoparticles produced in this new, high-volume nanoparticle production technique are compared with our earlier experiments using laser ablation of static microparticles. Transmission electron micrographs of the samples show the nanoparticles to be spherical and highly non-agglomerated under all conditions tested. These micrographs were analyzed to determine the effect of carrier gas type and pressure on size distributions. We conclude that mean diameters can be controlled from 4 to 20 nm by the choice of gas type and pressure. The smallest nanoparticles were produced in helium, with mean sizes increasing with increasing molecular weight of the carrier gas. These results are discussed in terms of a model based on cooling via collisional interaction of the nanoparticles, produced in the laser exploded microparticle, with the ambient gas.