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31.
A continuous time random walk (CTRW) is a random walk in which both spatial changes represented by jumps and waiting times between the jumps are random. The CTRW is coupled if a jump and its preceding or following waiting time are dependent random variables (r.v.), respectively. The aim of this paper is to explain the occurrence of different limit processes for CTRWs with forward- or backward-coupling in Straka and Henry (2011) [37] using marked point processes. We also establish a series representation for the different limits. The methods used also allow us to solve an open problem concerning residual order statistics by LePage (1981) [20]. 相似文献
32.
E. Almasi N. Kirshen H. Kern 《International journal of environmental analytical chemistry》2013,93(1-4):39-48
Abstract Trace level Volatile Organic Compounds (VOCs) in ambient air are normally determined according to EPA Method TO-14. This method describes the analysis in ambient air of 41 VOCs, ranging in boiling point from -29 to 215°C. It covers a concentration range from 0.2 to 20 parts per billion, volume/volume (ppb), and specifies sample enrichment of a 400 mL air sample on glass beads at -160°C. While this sample volume provides sub-ppb levels of VOC detection for target analytes when using a quadrupole mass spectrometer detector in SIM mode or when using GC detectors, the identification of non-target analytes may only be done in full scan mode for higher concentrations. Also with this sample volume a Nafion dryer is needed for water removal thereby lowering the recovery of polar VOCs. Because of the very high sensitivity of the ion trap MS, relatively small air volumes (60 mL) are adequate to obtain the required or lower detection levels. An integrated air analysis system based on a GC-ion-trap MS has been investigated and is described. This system has a built-in cryogenic trap and necessary valving, internal standard gas sampling loop, and is controlled from the GC-MS workstation. The linearity, precision, and method detection levels obtainable with this system when using small volumes are reported. In addition, examples of the quantitative and qualitative analysis of ambient air samples are shown. 相似文献
33.
34.
Susanne Kern Hafida Dkhil Prisca Hendarsa Graham Ellis Andreas Natsch 《Analytical and bioanalytical chemistry》2014,406(25):6165-6178
On prolonged exposure to air, linalool can form sensitizing hydroperoxides. Positive hydroperoxide patch tests in dermatitis patients have frequently been reported, but their relevance has not been established. Owing to a lack of analytical methods and data, it is unclear from which sources the public might be exposed to sufficient quantities of hydroperoxides for induction of sensitization to occur. To address this knowledge gap, we developed analytical methods and performed stability studies for fine fragrances and deodorants/antiperspirants. In parallel, products recalled from consumers were analysed to investigate exposure to products used in everyday life. Liquid chromatography–mass spectrometry with high mass resolution was found to be optimal for the selective and sensitive detection of the organic hydroperoxide in the complex product matrix. Linalool hydroperoxide was detected in natural linalool, but the amount was not elevated by storage in a perfume formulation exposed to air. No indication of hydroperoxide formation in fine fragrances was found in stability studies. Aged fine fragrances recalled from consumers contained a geometric mean linalool concentration of 1,888 μg/g and, corrected for matrix effects, linalool hydroperoxide at a concentration of around 14 μg/g. In antiperspirants, we detected no oxidation products. In conclusion, very low levels of linalool hydroperoxide in fragranced products may originate from raw materials, but we found no evidence for oxidation during storage of products. The levels detected are orders of magnitude below the levels inducing sensitization in experimental animals, and these results therefore do not substantiate a causal link between potential hydroperoxide formation in cosmetics and positive results of patch tests. Graphical Abstract
35.
Ast CR Henk J Ernst A Moreschini L Falub MC Pacilé D Bruno P Kern K Grioni M 《Physical review letters》2007,98(18):186807
The long-range ordered surface alloy Bi/Ag(111) is found to exhibit a giant spin splitting of its surface electronic structure due to spin-orbit coupling, as is determined by angle-resolved photoelectron spectroscopy. First-principles electronic structure calculations fully confirm the experimental findings. The effect is brought about by a strong in-plane gradient of the crystal potential in the surface layer, in interplay with the structural asymmetry due to the surface-potential barrier. As a result, the spin polarization of the surface states is considerably rotated out of the surface plane. 相似文献
36.
Wahl P Simon P Diekhöner L Stepanyuk VS Bruno P Schneider MA Kern K 《Physical review letters》2007,98(5):056601
The magnetic coupling between single Co atoms adsorbed on a copper surface is determined by probing the Kondo resonance using low-temperature scanning tunneling spectroscopy. The Kondo resonance, which is due to magnetic correlation effects between the spin of a magnetic adatom and the conduction electrons of the substrate, is modified in a characteristic way by the coupling of the neighboring adatom spins. Increasing the interatomic distance of a Cobalt dimer from 2.56 to 8.1 A we follow the oscillatory transition from ferromagnetic to antiferromagnetic coupling. Adding a third atom to the antiferromagnetically coupled dimer results in the formation of a collective correlated state. 相似文献
37.
38.
Sandra Schl?gl Nicolai Aust Raimund Schaller Armin Holzner Wolfgang Kern 《Monatshefte für Chemie / Chemical Monthly》2010,79(7):1365-1372
Abstract
Latex allergies arise from the presence of latex proteins as well as noxious rubber additives (mainly accelerators and activators used in conventional sulfur-accelerated vulcanization processes) in medical devices (e.g., medical gloves, catheters) made from natural rubber latex. As a new approach the ultraviolet (UV) light-initiated pre-vulcanization of natural rubber latex makes efficient cross-linking feasible without using any toxic, mutagenic, or irritating chemicals. The cross-linking in the latex particles is accomplished via the thiol-ene addition reaction in the presence of a polyfunctional thiol and a photoinitiator. The new process is carried out in a falling film photoreactor on a pilot scale which provides a continuous irradiation of the latex emulsion. The UV technique is suitable for an easy up-scaling and represents the entrance into large-volume industrial production. The surgical gloves are then made by a conventional coagulant dipping process comprising good physical properties and high ageing stabilities. The aim of this study was to evaluate the biological properties and skin compatibility of UV-pre-cured gloves in skin sensitization, skin irritation studies, and cytotoxic tests. In addition the biologically available chemical residues in the gloves were characterized by UV–visible spectroscopy, elementary analyses, and high-performance liquid chromatography coupled with mass spectroscopy. The results of the studies revealed that UV-cross-linked surgical gloves exhibit good skin compatibility together with low cytotoxicity and residual chemical levels in the range of 60 and 120 μg/gglove. 相似文献39.
40.
O.?Kern G.?AlberEmail author 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2005,36(2):241-248
The stabilizing properties of one-error correcting jump codes are explored under the realistic non-ideal condition of finite
recovery times.
For this purpose the quantum algorithm of the tent-map is decomposed into a universal set of Hamiltonian quantum gates which
ensure perfect correction of spontaneous decay processes under ideal circumstances even if they occur during a gate
operation. An entanglement gate is presented which is capable of entangling any two logical qubits of different one-error
correcting code spaces.
With the help of this gate simultaneous spontaneous decay processes affecting physical qubits of different code spaces can
be corrected and decoherence can be suppressed significantly. 相似文献