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41.
We report the experimental demonstration of spectral encoding of the polarization state of light by use of multiplexed distributed-feedback lasers in a dye-doped organic thin film by exploiting the pump polarization selectivity of the superimposed resonators. Measurement of the Stokes parameters of the pump light without a priori knowledge of the lasing properties of the structure is discussed. 相似文献
42.
Diekhöner L Schneider MA Baranov AN Stepanyuk VS Bruno P Kern K 《Physical review letters》2003,90(23):236801
The electronic structure of thin Co nanoislands on Cu(111) has been investigated below and above the Fermi level (E(F)) by scanning tunneling spectroscopy at low temperature. Two surface related electronic states are found: a strong localized peak 0.31 eV below E(F) and a mainly unoccupied dispersive state, giving rise to quantum interference patterns of standing electron waves on the Co surface. Ab initio calculations reveal that the electronic states are spin polarized, originating from d3(z(2)-r(2))-minority and sp-majority bands, respectively. 相似文献
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Bonner BE Buchanan JA Clement JM Corcoran MD Krishna NM Kruk JW Miettinen HE Moss RM Mutchler GS Nessi-Tedaldi F Nessi M Phillips GC Roberts JB Stevenson PM Tonse SR Birman A Chung SU Etkin A Fernow RC Kirk H Protopopescu SD Willutzki H Hallman T Madansky L Bar-Yam Z Dowd J Kern W King E Mayes BW Pinsky LS 《Physical review D: Particles and fields》1990,41(1):13-16
46.
Proch S Herrmannsdörfer J Kempe R Kern C Jess A Seyfarth L Senker J 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(27):8204-8212
The gas-phase loading of [Zn(4)O(btb)(2)](8) (MOF-177; H(3)btb=1,3,5-benzenetribenzoic acid) with the volatile platinum precursor [Me(3)PtCp'] (Cp'=methylcyclopentadienyl) was confirmed by solid state (13)C magic angle spinning (MAS)-NMR spectroscopy. Subsequent reduction of the inclusion compound [Me(3)PtCp'](4)@MOF-177 by hydrogen at 100 bar and 100 degrees C for 24 h was carried out and gave rise to the formation of platinum nanoparticles in a size regime of 2-5 nm embedded in the unchanged MOF-177 host lattice as confirmed by transmission electron microscopy (TEM) micrographs and powder X-ray diffraction (PXRD). The room-temperature hydrogen adsorption of Pt@MOF-177 has been followed in a gravimetric fashion (magnetic suspension balance) and shows almost 2.5 wt % in the first cycle, but is decreased down to 0.5 wt % in consecutive cycles. The catalytic activity of Pt@MOF-177 towards the solvent- and base-free room temperature oxidation of alcohols in air has been tested and shows Pt@MOF-177 to be an efficient catalyst in the oxidation of alcohols. 相似文献
47.
Gold(I)‐Catalyzed N‐Desulfonylative Amination versus N‐to‐O 1,5‐Sulfonyl Migration: A Versatile Approach to 1‐Azabicycloalkanes 下载免费PDF全文
Solène Miaskiewicz Boris Gaillard Dr. Nicolas Kern Prof. Dr. Jean‐Marc Weibel Prof. Dr. Patrick Pale Dr. Aurélien Blanc 《Angewandte Chemie (International ed. in English)》2016,55(31):9088-9092
Valuable 1‐azabicycloalkane derivatives have been synthesized through a novel gold(I)‐catalyzed desulfonylative cyclization strategy. An ammoniumation reaction of ynones substituted at the 1‐position with an N‐sulfonyl azacycle took place in the presence of a gold cation by intramolecular cyclization of the disubstituted sulfonamide moiety onto the triple bond. Depending on the size of the heterocyclic ring and substitution of the substrates, two unprecedented forms of nucleophilic attack on the sulfonyl group were exploited, that is, a N‐desulfonylation in the presence of an external protic O nucleophile (37–87 %, 10 examples) and a unique N‐to‐O 1,5‐sulfonyl migration (60–98 %, 9 examples). 相似文献
48.
Knez M Sumser MP Bittner AM Wege C Jeske H Hoffmann DM Kuhnke K Kern K 《Langmuir : the ACS journal of surfaces and colloids》2004,20(2):441-447
We studied the adsorption behavior and surface chemistry of the tobacco mosaic virus (TMV) on well-defined metal and insulator surfaces. TMV serves as a tubular supramolecular model system with precisely known surface termination. We show that if the surface chemistry of the substrate and the pH-dependent chemistry of the molecular surface match, for example, by hydrogen bonding, a strong adsorption occurs, and lateral movement is impeded. Due to the immobilization, the virion can be imaged by atomic force microscopy (AFM) in contact mode. We also used self-assembled monolayers with an acyl chloride group to induce covalent bonding via ester formation. Noncontact AFM proved that TMV keeps its cylindrical cross section only under weak adsorption conditions, that is, on hydrophobic surfaces, while on hydrophilic substrates a deformation occurs to maximize the number of interacting chemical groups. 相似文献
49.
J. Gerse J. Kern J. Imre L. Zsinka 《Journal of Radioanalytical and Nuclear Chemistry》1988,128(1):71-79
Three SUBLITECHR technetium generators were milked and generator products were tested for 5 d. Radionuclidic and radiochemical purity, pH of sodium pertechnetate solutions were -emitting impurities and pirogenity were not carried out. We can summarize that generators were running efficiently during our test period and in all cases the pertechnetate produced met the requirements of the European Pharmacopoeia. 相似文献
50.
J. Brenneisen B. Erhardt F. Glatz Th. Kern R. Ott H. Röpke J. Schmälzlin P. Siedle B. H. Wildenthal 《Zeitschrift für Physik A Hadrons and Nuclei》1997,357(2):157-173
Assignments of I, π, T are made to 30 levels in 32S between 7.35 and 11.76 MeV excitation energy, making the spectroscopy of the T= 0 states rather complete up to 10 MeV and that of the T = 1 states up to 12 MeV. A reassessment of existing data in the light of the new results clarifies the spectrum of I π = 1+, T = 1 states up to 15 MeV excitation energy. High-spin states (I = 52 - 7) below 10 MeV excitation energy have been investigated by n t γ angular-correlation measurements with the 29Si(α, nγ) reaction at E α 14.4 MeV. Five g-wave resonances of the 31P(p, γ) reaction, leading to the formation of I π + 4+, 5+ states in 32S, have been identified between 10 and 12 MeV excitation energy. The spectrum of T = 1 states between 10.7 and 12 MeV, has been investigated by measurements of γ-ray angular distributions on resonances of the 31P(p, γ) reaction and by measurements of resonance strengths. Several 32S levels between 7.35 and 8.75 MeV excitation energy were studied as final states in resonance decays. Finally a search was performed for I π = 0+ resonances of the 28Si(α, γ) reaction. 相似文献