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51.
E.M. Riordan A. Bodek M. Breidenbach D.L. Dubin J.E. Elias J.I. Friedman H.W. Kendall J.S. Poucher M.R. Sogard D.H. Coward 《Physics letters. [Part B]》1974,52(2):249-252
Deep-inelastic structure functions W1 and W2 have been extracted from electron-proton scattering cross sections that were measured in recent experiments at SLAC. The structure functions display deviations from scaling in the variable ω in the kinetic range 1.5 ? ω ? 3.0 and 2 ? Q2 ? 15 GeV2. 相似文献
52.
W. S. Kendall 《Probability Theory and Related Fields》1980,52(3):267-276
Summary Two generalisations of Brownian motion to several-dimensional time are considered and the topology of their level sets is analysed. It is shown that for these maps non-trivial contours are quite rare — their union has Lebesgue measure zero. The boundedness of all contours is established for the generalisation due to Lévy. For the other, the Brownian sheet, a partial result concerning the behaviour of the zero contour near the boundary is established.Most of the results in this paper were obtained in the course of an S.R.C studentship at the University of Oxford, and appear in the ensuing D. Phil. thesis. I wish to acknowledge the encouragement of my supervisor John Kingman, and the stimulus of correspondence with J.B. Walsh and R. Pyke. 相似文献
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This paper presents a real-world, capacitated examination timetabling problem from Universiti Malaysia Pahang (UMP), Malaysia. The problem has constraints which have not been modelled before, these being the distance between examination rooms and splitting exams across several rooms. These constraints provide additional challenges in defining a suitable model and in developing a constructive heuristic. One of the contributions of this paper is to formally define this real-world problem. A further contribution is the constructive heuristic that is able to produce good quality solutions for the problem, which are superior to the solutions that are produced using the university’s current software. Moreover, our method adheres to all hard constraints which the current systems fails to do. 相似文献
57.
Kasat RB Zvinevich Y Hillhouse HW Thomson KT Wang NH Franses EI 《The journal of physical chemistry. B》2006,110(29):14114-14122
The sorbent-solvent interactions for amylose tris(3, 5-dimethylphenylcarbamate) (ADMPC) with five commonly used solvents, hexane, methanol, ethanol, 2-propanol (IPA), and acetonitrile (ACN), are studied using attenuated total reflection infrared spectroscopy (ATR-IR) of thin sorbent films, X-ray diffraction (XRD) of thin films, (13)C cross polarization/magic angle spinning (CP/MAS) and MAS solid state NMR of polymer-coated silica beads (commercially termed "Chiralpak AD"), and DFT modeling. The ADMPC-polymer-coated silica beads are used commercially for analytical and preparative scale separations of chiral enantiomers. The polymer forms helical rods with intra- and inter-rod hydrogen bonds (H-bonds). There are various nm-sized cavities formed between the polymer side-chains and rods. The changes in the H-bonding states of the C=O and NH groups of the polymer upon absorption of each of the five solvents at 25 degrees C are determined with ATR-IR. The IR wavenumbers, the H-bonding interaction energies, and the H-bonding distances of the polymer side-chains with each of the solvent molecules are predicted using the DFT/B3LYP/6-311+g(d,p) level of theory. The changes in the polymer crystallinity upon absorption of each solvent are characterized with XRD. The changes in the polymer crystallinity and the H-bonding states of C=O groups are also probed with (13)C CP/MAS solid-state NMR. The changes in the polymer side-chain mobility are detected using (13)C MAS solid-state NMR. The H-bonding states of the polymer change upon absorption of each polar solvent and usually result in an increase in the polymer crystallinity and the side-chain mobility. The polymer rods are reorganized upon solvent absorption, and the distance between the rods increases with the increase in the solvent molecular size. These results have implications for understanding the role of the solvent in modifying the structure and behavior of the polymer sorbents. 相似文献
58.
We introduce a novel variant of the travelling salesmen problem and propose a hyper-heuristic methodology in order to solve it. In a competitive travelling salesmen problem (CTSP), m travelling salesmen are to visit n cities and the relationship between the travelling salesmen is non-cooperative. The salesmen will receive a payoff if they are the first one to visit a city and they pay a cost for any distance travelled. The objective of each salesman is to visit as many unvisited cities as possible, with a minimum travelling distance. Due to the competitive element, each salesman needs to consider the tours of other salesman when planning their own tour. Since equilibrium analysis is difficult in the CTSP, a hyper-heuristic methodology is developed. The model assumes that each agent adopts a heuristic (or set of heuristics) to choose their moves (or tour) and each agent knows that the moves/tours of all agents are not necessarily optimal. The hyper-heuristic consists of a number of low-level heuristics, each of which can be used to create a move/tour given the heuristics of the other agents, together with a high-level heuristic that is used to select from the low-level heuristics at each decision point. Several computational examples are given to illustrate the effectiveness of the proposed approach. 相似文献
59.
Julian Tu Dennis Svatunek Saba Parvez Albert C. Liu Brian J. Levandowski Hannah J. Eckvahl Randall T. Peterson Kendall N. Houk Raphael M. Franzini 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(27):9141-9146
The isocyano group is a structurally compact bioorthogonal functional group that reacts with tetrazines under physiological conditions. Now it is shown that bulky tetrazine substituents accelerate this cycloaddition. Computational studies suggest that dispersion forces between the isocyano group and the tetrazine substituents in the transition state contribute to the atypical structure–activity relationship. Stable asymmetric tetrazines that react with isonitriles at rate constants as high as 57 L mol?1 s?1 were accessible by combining bulky and electron‐withdrawing substituents. Sterically encumbered tetrazines react selectively with isonitriles in the presence of strained alkenes/alkynes, which allows for the orthogonal labeling of three proteins. The established principles will open new opportunities for developing tetrazine reactants with improved characteristics for diverse labeling and release applications with isonitriles. 相似文献
60.
The distortion/interaction activation strain (DIAS) analysis is a powerful tool for the investigation of energy barriers. However, setup and data analysis of such a calculation can be cumbersome and requires lengthy intervention of the user. We present autoDIAS, a python tool for the automated setup, performance, and data extraction of the DIAS analysis, including automated detection of fragments and relevant geometric parameters. © 2019 Wiley Periodicals, Inc. 相似文献