Summary: Solid‐state processing for the preparation of poly(p‐phenylenesulfide) (PPS‐) based nano‐composites having finely dispersed layered fillers was conducted. The mixture of PPS and organically modified layered filler (OMLF) (95/5 wt./wt.) was subjected to the processing using thermostated hot‐press at 150 °C, below Tm of PPS (i.e., PPS is still at the solid‐state), and applying pressures of 33 MPa for 30 s. The mixture exhibited disorder and delaminated layer structure with the thickness of 10–20 nm into the PPS matrix. In contrast, a nano‐composite prepared by melt compounding at 300 °C for 3 min showed large stacked silicate layers in the PPS matrix. The processing led to delamination of the silicate layers and attained the discrete dispersion.
TEM bright field image and FFT spectrum of a solid‐state processed PPS nano‐composite. 相似文献
Fiber devices using polarization-maintaining fibers called PANDA fibers are presented. They are polarization-maintaining couplers and polarization-splitting couplers, optical isolators and optical circulators, and multi/demultiplexers designed for 1.3 μm wavelength. Crosstalk of-32 dB and excess loss of 0.03 dB for the polarization-maintaining coupler, and polarization-splitting ratio of 17 dB and excess loss of 0.5 dB for the polarization-splitting coupler have been fabricated by a fusion-elongation method. A fiber polarizer with the extinction ratio of more than 40 dB has been presented by using the difference of bending loss between the orthogonal modes in the PANDA fibers. Multi/demultiplexer with narrow band-pass of 1.4 nm utilizing combination of PANDA fiber polarization dispersion and the polarization-splitting coupler has been realized. An optical isolator consisting of fiber polarizers and a spherical YIG with a lens function and an optical circulator consisting of polarizing-splitting couplers and spherical YIGs have been achieved. 相似文献
The effect of alkyl and alkoxy chain lengths on the layer structures of smectic A and C phases has been examined by X-ray diffraction measurements on three isomeric systems: 4-alkoxyphenyl and 4-n-alkylphenyl 4-[(4-octyloxyphenyl)carbonyloxy]benzoates (1); 4-octyloxyphenyl 4-[4-(octyloxyphenyl)carbonyloxy]benzoates (2); 4-octyloxyphenyl, 4-alkoxyphenyl and 4-n-alkylphenyl terephthalates (3); and p-phenylene 4-octyloxybenzoates, 4-alkoxybenzoate and 4-n-alkylbenzoate (4). Although all the derivatives exhibit smectic A and/or C phases having a monolayer arrangement of the molecules, the layer spacings are considerably affected by alternation of the ester linkages. The layer spacings for the homologues of 1 are a little shorter than the calculated molecular lengths, while those for 2 agree with the calculated molecular lengths. The layer spacings for 3 show a notable even-odd alternation in the higher homologues. The results are discussed in terms of a subtle change in the molecular structures due to replacement of the ester groups. 相似文献