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311.
Collisional vibrational energy transfer between cyclopropane molecules and a seasoned silica surface has been studied by the variable encounter method at temperatures from 800 to 1325 K. The average energy of a down-transition < ΔE' > upon collision with the wall decreases monotonically with increasing temperature. 相似文献
312.
Merlo JA Newman CR Gerlach CP Kelley TW Muyres DV Fritz SE Toney MF Frisbie CD 《Journal of the American Chemical Society》2005,127(11):3997-4009
We report the structural and electrical characterization of two new p-channel organic semiconductors, 5,5'-bis(2-tetracenyl)-2,2'-bithiophene (1) and 5,5'-bis(2-anthracenyl)-2,2'-bithiophene (2). Both compounds exhibited a high degree of thermal stability with decomposition temperatures of 530 degrees C and 425 degrees C for 1 and 2, respectively. The thin-film structures of 1 and 2 were examined using wide-angle X-ray diffraction (XRD), grazing incidence X-ray diffraction (GIXD), and atomic force microscopy (AFM). Films of 1 and 2 pack in similar triclinic unit cells with the long axes of the molecules nearly perpendicular to the substrate. Thin-film transistors (TFTs) based on 1 and 2 exhibit contact-corrected linear regime hole mobility as high as 0.5 cm2/Vs and 0.1 cm2/Vs, respectively. The specific contact resistance at high gate voltages for gold top contacts was 2 x 10(4) Ohms cm and 3 x 10(4) Ohms cm for 35 nm thick films of 1 and 2, respectively. Long-term air stability tests revealed less degradation of the electrical properties of 1 and 2 in comparison to pentacene. Variable temperature measurements revealed activation energies as low as 22 and 27 meV for 1 and 2, respectively. The temperature and gate voltage dependence of the mobility are discussed in terms of a double exponential distribution of trap states and a model accounting for the layered structure of the organic films. The enhanced air and thermal stability over pentacene, combined with good electrical performance characteristics, make 2 a promising candidate for future organic TFT applications. 相似文献
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316.
Given a setX and subsetsX
1,...,X
m, we consider the problem of finding a graphG with vertex setX and the minimum number of edges such that fori=1,...,m, the subgraphG
i; induced byX
i is connected. Suppose that for any pointsx
1,...,x
X, there are at mostX
i 's containing the set {x1,...,x
}. In the paper, we show that the problem is polynomial-time solvable for ( 2, 2) and is NP-hard for (3,=1), (=l,6), and (2,3).Support in part by the NSF under grant CCR-9208913 and CCR-8920505.Part work was done while this author was visiting at DIMACS and on leave from Institute of Applied Mathematics, Chinese Academy of Sciences, Beijing. 相似文献
317.
318.
Joel M. Kauffman Peter T. Litak John A. Novinski Charles J. Kelley Alem Ghiorghis Yuanxi Qin 《Journal of fluorescence》1995,5(3):295-305
Absorption and fluorescence emission spectral data, as well as fluorescence quantum yields (f), were determined for 41p-oligophenylene compounds containing 2–6, 8, and 10 benzene rings. Of 29 compounds containing carbon-bridged rings (fluorenes), 28 were dialkylated on each bridge for improved solubility and photostability. Absorption maxima for oligophenylenes were observed at wavelengths as long as 366 nm, emission maxima to 437 nm, and molar extinction coefficients () as large as 153,000 L/mol-cm; all three exceeded predicted maximum values for the corresponding unbridged oligophenylenes. The substitution of furan for benzene or carbazole for a fluorene (two examples each) bathochromically shifted absorption and emission maxima. Dialkylated carbon bridges bathochromically shifted absorption and emission maxima, and lowered f in biphenyl and in one terphenyl analogue, but appeared to cause no diminution of f in higher oligophenylenes. Bis(2-methoxyethyl) substitution on the bridges, incorporated to provide solubility in polar solvents, lowered f in all examples. Tertiary alkyl substituents on terminal rings bathochromically shifted the absorption and emission maxima and generally increased f. The loose bolt effect, which lowers f in mononuclear substituted benzenes, may operate in 9,9-dialkylfluorenes, but not in 2,7-di-t-butylfluorene or in higher oligophenylenes. Cyclic ether and methoxy substituents as auxofluors on terminal rings generally bathochromically shifted absorption and emission maxima and increased and f. Cyano substituents bathochromically shifted absorption and emission maxima, and increased , but lowered f slightly. 相似文献
319.
M. A. Quijada D. B. Tanner R. J. Kelley M. Onellion 《Zeitschrift für Physik B Condensed Matter》1994,94(3):255-259
The polarized reflectance of thea-b plane of single-domain Bi2Sr2CaCu2O8 crystals is anisotropic above and belowT
c
. The normal-state infrared conductivity is higher forEa whereas the high-frequency conductivity is higher alongb, particularly for transitions associated with the Bi–O layers. BelowT
c
there is a definite anisotropy to the far-infrared absorption, with a finite absorption forEb down to 20 meV. This anisotropy of thea-b plane could be due either to anisotropy of the superconducting gap or to anisotropy of the midinfrared component to the conductivity. 相似文献
320.
An automated method is described for optimizing the molecular parameters in simultaneous modeling of optical absorption spectra and resonance Raman excitation profiles. The method utilizes a previously developed Fortran routine that calculates absorption spectra and Raman excitation profiles for polyatomic molecules in solution from a model for the potential energy surfaces and spectral broadening mechanisms. It is combined here with an optimization routine from the commercial MATLAB package that iteratively adjusts the parameters of the molecular model to minimize the least-squared error between calculated and experimental spectra. Optimizations that typically require days to weeks of human time when performed interactively can be accomplished automatically in less than an hour of computer time. The method can handle large molecules (we show results for as many as 23 Raman-active modes) and mixtures of spectral broadening mechanisms (lifetime, Brownian oscillator, and inhomogeneous), and is robust toward noise or missing data points. 相似文献