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81.
Hirofumi Ishikawa Yuta Nagasaka Hitoshi Ohta Takao Nanba Ryouji Kanno 《Journal of Physics and Chemistry of Solids》2005,66(11):2065-2067
The reflection measurements of superionic conductors LiCoO2 and Li1-xCoO2, which are already in use for the positive electrode material of 4 V rechargeable lithium batteries, have been performed in the millimeter wave region from 6 to 60 cm−1 using the electron storage ring facilities of Institute of Molecular Science in Okazaki. The increase of the reflectivity has been observed in the low wavenumber region below 10 cm-1 above 300 K in Li1-xCoO2 for the first time, while the reflectivity of LiCoO2 has almost the constant value in all observed temperature region between 77 to 380 K. The results will be discussed in connection with our previous results of LiNiO2. 相似文献
82.
83.
Masazumi Ishiguro Kensuke Harada Keiichi Tanaka Takehiko Tanaka 《Journal of Molecular Spectroscopy》1996,180(2)
Rotational transitions of fluoroacetylene in the ν1(CH stretch) vibrational state have been observed by the laser–microwave double resonance technique using a color center laser as a radiation source in the 3 μm region. The rotational constant and centrifugal distortion constant in the ν1state were determined to be 9684.310(16) MHz and 2.68(62) kHz, respectively, where the uncertainties given in parentheses correspond to 2.5 standard deviations. 相似文献
84.
The extraction behavior of mono-, poly-, anal bis-(benzothiacrown ether)s is studied for alkali, alkaline-earth, heavy, and transition metal ions in the presence of picrate. These ethers show high selectivity for silver ion. Silver extractions from binary and quaternary mixtures of silver with heavy or transition metal ions were successful, except for mixtures with mercury(II) ion. Silver was extracted from a copper ore with ca. 80% recovery. 相似文献
85.
86.
87.
Quark mixings and theor momentum dependences are discussed in a subquark model in which the weak current is made of the iso-doublet spinor subquarks. The Cabibbo angle is predicted to become larger as momentum transfer between quarks grows up. 相似文献
88.
Keiichi Ohno Hiroatsu Matsuura Don McNaughton Harold W. Kroto 《Journal of Molecular Spectroscopy》1985,111(2):415-424
The infrared spectra of 1-phosphapropyne, CH3CP, and its perdeuteride, CD3CP, have been measured in the gaseous and solid states. The QK branches of perpendicular bands have been analyzed in terms of the usual quadratic expression in K. Fermi resonances were identified for the ν1, ν2 + ν3, 2ν3, 2ν60; and ν5, 2ν3 + ν8 band systems of CH3CP and the ν1, 2ν3, 2ν60; ν6, ν7 + ν8; and ν7, 3ν81 band systems of CD3CP. The xy Coriolis interaction was also identified between the ν3 and ν6 bands of the two species. All the fundamentals were assigned and the normal coordinate treatment was carried out along with the Coriolis constants, ζz. 相似文献
89.
Cationic (carbene) organopalladium(II) complexes coordinated with cyclic diolefin or organic nitrile
The chloro-bridged (carbene)organopalladium(II) complex, di-μ-chlorobis(1,3-diphenyl-2-imidazolidinylidenato-2-C,2′-C)dipalladium(II) underwent chlorine abstraction with silver perchlorate in the presence of a cyclic diolefin or an organic nitrile, to give new cationic (carbene)organopalladium(II) complexes coordinated with the respective substrates. These new complexes were characterized by means of elemental analysis, molar conductivities, and IR and 1H NMR spectroscopy. 相似文献
90.
Hisakazu Kotani Masayoshi Yamada Keiichi Yamamoto Kenji Abe 《Solid State Communications》1982,41(6):461-463
Time-resolved optical transmission of annealing dye laser pulse (wavelength : 590 nm and pulse width : 250 nsec) itself has been measured in thin layers of Si+-implanted amorphized silicon-on-sapphire (SOS) with several energy densities in the range of 0.02 to 2.64 J/cm2. At the energy densities where the amorphized SOS is recrystallized, the transmission exhibits a sudden drop and subsequently remains at a detectable level. This laser-induced absorption is inconsistent with the presence of ordinary molten silicon but suggests an electronic structural-change from amorphous to crystalline state. 相似文献