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981.
982.
Allyldialkyltelluronium bromides were treated with aromatic amines in 1,2-dichloroethane, readily giving allyl aryl amines in excellent yields. 相似文献
983.
Wei-Yuan Huang 《Macromolecular Symposia》1994,82(1):67-75
Using sulfinatodehalogenation and related reagent systems several groups of perfluoroalkylated compounds including olefins, dienes, phenolic compounds and aromatic dicarboxylic acids were synthesized which may be useful as potential monomers. 相似文献
984.
985.
提出了一种改进的、可用于计算偏振相关拉曼增益的光纤拉曼放大器的非线性耦合波方程。建立了单模双折射光纤拉曼增益的数学模型,分析了线偏振抽运光以与光纤快轴成45°激励的单模双折射光纤拉曼放大器模型与实际具有随机双折射的光纤拉曼放大器的拉曼增益偏振相关特性的等价性。基于上述模型,提出了一个可定量表征单模光纤偏振模色散统计特性的拉曼增益偏振相关因子,用以替代常规的光纤拉曼放大器非线性耦合波方程中的偏振相关因子。计算结果与已报道文献的实验数据非常吻合。同时对抽运增益在同向和反向抽运方式下截然不同的增益偏振相关特性给出了合理的解释。 相似文献
986.
深空光通信中的图像信标捕获技术 总被引:1,自引:0,他引:1
为实现深空光通信链路建立过程中精确的对准,提出了一种深空光通信系统扩展信标的捕获方案。该方案以可视地球图像作为信标,在航天器上存储一幅信标图像作为参考图像,采用天线扫描的方式在各点对所瞄准的区域成像,利用像素扫描的方式,使参考图像和实际探测图像进行相关,在天线扫描完成以后,找出相关性最大的位置,即可认为在该点捕获到地球图像。在计算两图像相关系数的过程中,由于傅里叶梅林变换幅度谱具有伸缩及旋转不变性,因此利用傅里叶梅林变换即可消除两图像相关系数因为旋转和伸缩的影响。利用蒙特卡罗方法随机产生1000个视场,仿真结果表明,3σ内正确捕获到信标图像的概率为99.6%,表明这是一种可行的方法。 相似文献
987.
He-Xia Huang Hui-Jun Tan Zheng-Kang Lin Zi-Jie Li Shu Sun Hao Chen Zhi-Xiang Xiao 《Acta Mechanica Sinica》2021,37(1):156-168
The submerged inlet is an attractive configuration for advanced helicopters due to its high stealth performance and low external drag.In this paper,a submerged ... 相似文献
988.
Li-Zhao Huang Yue Shui Wei Chen Zhong-Ming Li Hong-Tao Song Guang-Ai Sun Jia-Zhuang Xu Gan-Ji Zhong Dong Liu 《高分子科学》2021,39(3):365-376
The correlation between aggregates and bound rubber structures in silicone rubbers(S(phr)) with various silica fractions(ΦSi) has been investigated by contrast matching small-angle neutron scattering(SANS), swelling kinetics, and low-field nuclear magnetic resonance(NMR).Mixed solvents with deuterated cyclohexane fractions of 4.9% and 53.7% were chosen to match the scattering length densities of the matrix(SMP(phr)) and the filler(SMS(phr)), respectively. All the data consistently suggest that:(i) There is a critical threshold ΦSic between 10 and 30 phr;below ΦSic, the isolated aggregates are dominant, while beyond ΦSic, some rubber fraction is trapped among the agglomerate;(ii) ΦSiindependent thicknesses around 7.5 nm(NMR) and 8.6 nm(SANS) suggest that the bound rubber formation is determined by inherent properties of the components, and the power-law around 4.2 suggests an exponential changed gradient density of the bound rubber;(iii) SMS(80) presents a bicontinuous bound rubber with three characteristic lengths of 41, 100, and 234 nm. The expanded correlation length, a 20 nm smaller aggregate sizes suggest that such existent bicontinuous network in dry samples with less ΦSi is kind of impacted by swelling. With the obtained bound rubber models, the reinforcing mechanism of filled silicone rubber is elucidated. 相似文献
989.
Tributylstibine can mediate the olefination of carbonyl compounds with bromomalonic ester and with dibromomalonic ester. An initial halophilic attack of tributylstibine on the bromine of bromomalonic or dibromomalonic ester forming an ion pair of bromotributylstibonium cation and malonic (A) or bromomalonic ester carbanion (B) , respectively, is proposed. These ion pairs react with carbonyl compounds to achieve subsequent olefination. Alternatively, 2 equiv of A collapse, with elimination of malonic ester, to form stiborane D , and the ion pair B reacts with another equivalent of tributylstibine to form stiborane D. This last undergoes a Wittig-type reaction with carbonyl compound to achieve olefination. 相似文献
990.
Shujing Xu Dang Ding Xujie Zhang Lin Sun Dongwei Kang Boshi Huang Xinyong Liu Peng Zhan 《Molecules (Basel, Switzerland)》2022,27(3)
Viral infections pose a persistent threat to human health. The relentless epidemic of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) has become a global health problem, with millions of infections and fatalities so far. Traditional approaches such as random screening and optimization of lead compounds by organic synthesis have become extremely resource- and time-consuming. Various modern innovative methods or integrated paradigms are now being applied to drug discovery for significant resistance in order to simplify the drug process. This review provides an overview of newly emerging antiviral strategies, including proteolysis targeting chimera (PROTAC), ribonuclease targeting chimera (RIBOTAC), targeted covalent inhibitors, topology-matching design and antiviral drug delivery system. This article is dedicated to Prof. Dr. Erik De Clercq, an internationally renowned expert in the antiviral drug research field, on the occasion of his 80th anniversary. 相似文献