The aim of this study was to prepare transparent nanohybrid films with low coefficient of thermal expansion (low CTE), which consist of acryl resin and nanosized clay. The hybrid films with different clay contents were prepared by UV curing of tricyclodecane dimethanol diacrylate (TCDDMDA) including nanosized clay. All obtained films were transparent similar to pure poly(TCDDMDA). In addition, the film containing 40 wt.% of clay showed a low CTE of 10 ppm/K in 150–200 °C, which is similar to that of inorganic materials such as glass. The significant property improvement is related to shape effect and orientation of clay in polymer matrix. Wide-angle X-ray diffraction measurement was carried out to investigate orientation of nanosized clay in polymer matrix. From this measurement, it was confirmed that the clay platelets were oriented parallel with film surface with increasing clay content, and orientation coefficient of the clay in polymer matrix reached to f?=?0.65 for the hybrid film containing 40 wt.% of clay. Though, in comparison with the matrix, the flexibility of the hybrid film evaluated by the wind roll test with steel bar was lowered by increase of clay content, the hybrid film containing 40 wt.% of clay could be rewound with steel bar 10 mm across, and its flexibility was retained. 相似文献
Water pump : Polyion complex (PIC) vesicles are spontaneously formed from PIC microdroplets, which are formed by mixing cationic and anionic polymers (see picture). The formation process can be reversibly controlled by local heating with a focused infrared laser that triggers microphase separation and subsequent water influx. The size of the resulting giant unilamellar vesicles is determined by the initial size of the PIC droplets.
A one-dimensional (1D) uneven peanut-shaped C(60) polymer formed from electron-beam (EB)-induced polymerization of C(60) molecules showed an anomalous increase in two characteristic infrared (IR) peak intensities, which are respectively due to the radial and tangential motion of the 1D polymer, when compared to the IR peaks of pristine C(60) films. This anomaly was analyzed on the basis of the vibrational van Hove singularity (VHS), using an extended thin-shell elastic model fully considering the effects of periodic radius modulation inherent to the 1D uneven peanut-shaped C(60) polymer. We succeeded in explaining the enhancement in the tangential peak intensity by VHS, whereas the origin to cause that in the radial peak intensity is still unclear. 相似文献
Recent LHC data showed excesses of Higgs-like signals at the Higgs mass of around 125 GeV. This may indicate supersymmetric models with relatively heavy scalar fermions to enhance the Higgs mass. The desired mass spectrum is realized in the anomaly-mediated supersymmetry breaking model, in which the Wino can naturally be the lightest superparticle (LSP). We discuss possibilities for confirming such a scenario, particularly detecting signals from Wino LSP at direct detection experiments, indirect searches at neutrino telescopes and at the LHC. 相似文献
Topological superconductors classified as type D admit zero-energy Majorana fermions inside vortex cores, and consequently the exchange statistics of vortices becomes non-Abelian, giving a promising example of non-Abelian anyons. On the other hand, types C and DIII admit zero-energy Dirac fermions inside vortex cores. It has been long believed that an essential condition for the realization of non-Abelian statistics is non-locality of Dirac fermions made of two Majorana fermions trapped inside two well-separated vortices as in the case of type D. Contrary to this conventional wisdom, however, we show that vortices with local Dirac fermions also obey non-Abelian statistics. 相似文献
Based on ab initio electronic structure calculations by self-interaction-corrected local-density-approximation (SIC-LDA) with the Korringa–Kohn–Rostoker coherent potential approximation (KKR-CPA), we propose a materials design for high efficiency photovoltaic solar cells (PVSCs). It is shown that (i) the concentration dependence of the mixing energy of CuIn1−xGaxSe2 shows upward convexity, thus this system favors phase separation. Due to the type II band alignment between CuInSe2 and CuGaSe2, efficient electron–hole separation is realized in decomposed phase of this system. (ii) CuIn1−xZn0.5xSn0.5xSe2 has a direct band gap and no impurity state appears in the gap. Therefore, cost reduction is possible by using Zn and Sn instead of In. (iii) n-type CuAl1−xSnxS2 and p-type Cu1−xVCuxAlS2 have negative activation energy for doped impurities and are expected to be low-resistive transparent conducting sulfides, which should be useful for CuInSe2-based PVSCs. 相似文献
We present a first-principles study of the magnetic properties of N-doped MgO, CaO and SrO, which have been proposed to constitute a new class of dilute magnetic semiconductors (DMSs) with no magnetic elements. In this study, it was found that under a homogeneously distributed condition, Curie temperatures could reach room temperature at sufficient N concentrations in the range of 20–30 at.%; however, an inhomogeneous N distribution in these DMSs is the favored configuration, which indicates that spinodal decomposition leads to a room-temperature blocking temperature at smaller N concentrations than those estimated for room-temperature ferromagnetism in the homogeneous distribution condition. 相似文献
Intramolecular cyclization of precursor polyhydrazides derived from hydrazine and four 2,5‐dialkoxyterephthalic acids by direct polycondensation with Lawesson's reagent afforded new conjugated polymers constituted of 1,3,4‐thiadiazole and 2,5‐dialkoxybenzene units. The polymers emitted bluish green light in solution and green light in solid state in spite of the coexistence of non‐cyclized hydrazide linkage in the backbones, the Stokes shifts being 91–138 nm in the solid state. It was suggested that these polymers have appropriate lengths of conjugation backbones based on the 1,3,4‐thiadiazole moiety. 相似文献