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排序方式: 共有386条查询结果,搜索用时 15 毫秒
291.
A new proof of admissibility of tests in MANOVA is given using Stein's theorem [7]. The convexity condition of Stein's theorem is proved directly by means of majorization rather than by the supporting hyperplane approach. This makes the geometrical meaning of the admissibility result clearer. 相似文献
292.
The pressure dependence of lattice constants of 13C-enriched diamond and diamond of natural isotopic composition have been studied by using x-ray synchrotron radiation and
the imaging plate technique. The compression curves reveal features which indicate an inversion of the isotope effect at high
pressure.
Pis’ma Zh. éksp. Teor. Fiz. 63, No. 2, 73–77 (25 January 1996)
Published in English in the original Russian journal. Edited by Steve Torstveit. 相似文献
293.
294.
Tsunehisa Hirashita Kazuma Mitsui Yousuke Hayashi Shuki Araki 《Tetrahedron letters》2004,45(50):9189-9191
Allylindium sesquihalide reacts with epoxide to give homoallyl alcohol via a 1,2-shift reaction. In contrast, allylindate gives the ring-opening product without rearrangement. 相似文献
295.
Kazuma Matsui Dr. Masatoshi Shibuya Prof. Dr. Yoshihiko Yamamoto 《Angewandte Chemie (International ed. in English)》2016,55(49):15397-15400
The use of N‐(p‐chlorophenyl)methylbenzoxazole‐2‐thione as a sulfur‐atom donor enables the catalytic [2+2+1] cycloaddition of diynes in wet DMF at 80 °C when open to air, thus affording diverse fused thiophenes with good yields and wide functional‐group compatibility. A plausible mechanism, involving a cationic ruthenacycle intermediate, was also proposed on the basis of several control experiments. 相似文献
296.
297.
Y Inamori M Ogawa Y Ohno S Nishihata H Tsujibo Y Miki S Takemura 《Chemical & pharmaceutical bulletin》1989,37(11):3137-3138
3,3'-Dihydroxy-alpha,beta-diethyldiphenylethane (I), an isomer of hexestrol (II), was found to have a strong hypotensive effect on rats and antifungal activity against some pathogenic fungi. The hypotensive effect of I (-100.0 +/- 21.0 mmHg, 10 mg/kg, i.v.) was stronger than that of II (-40.0 +/- 2.60 mmHg, i.v.). Unlike II and other oxystilbene-related compounds already tested, I showed prolonged hypotensive action at the dose of 10 mg/kg, and the blood pressure was not restored to the original level within 20 min. I also showed antifungal activity against all fungi tested (minimal inhibitory concentration: 10-120 micrograms/ml). It should be emphasized that by shifting the phenolic hydroxyl group to m-position, the biological activities were greatly increased. 相似文献
298.
299.
S Nakajima H Hayashi Y Omote Y Yamazaki S Hirata T Maeda Y Kubo T Takemura Y Kakiuchi Y Shindo 《Journal of photochemistry and photobiology. B, Biology》1990,7(2-4):189-198
The tumour-localizing abilities of various kinds of porphyrin derivatives in tumour-bearing hamsters were assessed by nitrogen-pulsed laser spectrofluorometry (N2-PLS). On examination of porphine derivatives (from haemoglobin), it was found that the dimer and acetylated and amidated compounds had a high affinity for tumour tissue; the dimer and hydroxylated compound of phorbine derivatives (from chlorophyll) also showed a high affinity. Furthermore, of the metalloporphines (gallium, zinc and indium complexes), those which contained hydrophilic groups showed a high affinity for tumour tissue; of the metallophorbines (gallium, zinc and indium complexes), those which contained hydrophobic groups showed a high affinity. A correlation was found between the side-chain structure of the porphyrins and metalloporphyrins and their affinity for tumour tissue. 相似文献
300.
Kawakami K Takahashi H Ohki H Kimura K Miyauchi S Miyauchi R Takemura M 《Chemical & pharmaceutical bulletin》2000,48(11):1667-1672
A series of 8-methoxyquinolones bearing 3-amino-4-methylpyrrolidines or 3-amino-4-fluoromethylpyrrolidines at the C-7 position was synthesized and their physicochemical and biological properties were evaluated. All of the compounds synthesized showed more potent activity than LVFX (3) against both gram-positive and negative bacteria. Increases in lipophilicity of these compounds had desirable effects on their potency of single intravenous toxicity and pharmacokinetic profiles in animals. Among the compounds synthesized, 1-fluorocyclopropyl derivatives 17 and 20, and 7-(cis-3-amino-4-fluoromethylpyrrolidinyl) derivative 19 (DC-756h) showed negative responses in the micronucleus test in mice while 1-cyclopropyl-7-(3-aminopyrrolidinyl) derivative 16 showed a positive response. These results suggested that the introduction of a fluorine atom into the 3-aminopyrrolidinyl substituent resulted in favorable influence on genetic toxicity as well as into the N-1 cyclopropyl substituent. 相似文献