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31.
Richard Gawel Kazimierz Przybylski Massimo Viviani 《Journal of Thermal Analysis and Calorimetry》2014,116(2):895-903
The objective of this work is to analyse the chemical stability of BaCe0.85Y0.15O3?δ –Ce0.85Y0.15O2?δ (BCY15–YDC15) composite materials at 600 °C and to compare the aforementioned chemical stability with that of pure BCY15. The composite powders were obtained by mixing together powders of BCY15 and YDC15 in the following volume fractions: 90 % BCY15 + 10 % YDC15, 70 % BCY15 + 30 % YDC15, 30 % BCY15 + 70 % YDC15, 20 % BCY15 + 80 % YDC15 and 10 % BCY15 + 90 % YDC15. After that both powders and sintered samples of the BCY15 and the BCY15–YDC15 composites were saturated in two different atmospheres at 600 °C: CO2/H2O (3.1 mol% H2O) and N2/H2O (46.8 mol% H2O). The effects of the previously mentioned atmospheres on the physicochemical properties of the samples were investigated via differential thermal analysis (DTA) combined with thermogravimetric analysis (TG). Furthermore, mass spectrometry was used to analyse the chemical composition of the gases released from the samples during the DTA–TG heating process. The surface and cross-section morphology of the samples were examined by scanning electron microscopy. Moreover, the phase composition of each sample was studied via X-ray Diffraction. From the combined analysis, it can be concluded that the addition of YDC15 in the composite samples leads to an increase in resistance against the corrosive effects of CO2. Furthermore, it was determined that all samples maintain stability in the presence of H2O at 600 °C. 相似文献
32.
Ordered phases formed by surfactants in water solutions, and used in technological processes as templates for the synthesis of mesoporous materials, exhibit topological fluctuations. From the results of the Monte Carlo simulations of the lamellar phase we have established a relation between topological fluctuations and the behavior of the off-specular scattering intensity. We have defined the topological Lifshitz line. At this line the peak position in the off-specular scattering intensity moves from the zero (lamellar phase with fixed topology) to the nonzero value of the scattering wave vector (lamellar phase with fluctuating topology). 相似文献
33.
Zdzis?aw Dzedzej Kazimierz G?ba Wojciech Uss 《Journal of Fixed Point Theory and Applications》2011,10(2):233-252
A module structure of the cohomology Conley index is used to define a relative cup-length. This invariant is applied then to prove a multiplicity theorem for periodic solutions to Hamiltonian systems. 相似文献
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Dr. Guanzhao Wu Yangxue Liu Hossein Rouh Liulei Ma Yao Tang Sai Zhang Peng Zhou Jia-Ying Wang Shengzhou Jin Dr. Daniel Unruh Dr. Kazimierz Surowiec Prof. Dr. Yanzhang Ma Prof. Dr. Guigen Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(30):8013-8020
The first asymmetric catalytic approach to multilayer 3D chirality has been achieved by using Suzuki-Miyaura cross-couplings. New chiral catalysts were designed and screened under various catalytic systems that proved chiral amide-phosphines to be more efficient ligands than other candidates. The multilayer 3D framework was unambiguously determined by X-ray structural analysis showing a parallel pattern of three layers consisting of top, middle and bottom aromatic rings. The X-ray structure of a catalyst complex, dichloride complex of Pd-phosphine amide, was obtained revealing an interesting asymmetric environment nearby the Pd metal center. Three rings of multilayer 3D products can be readily changed by varying aromatic ring-anchored starting materials. The resulting multilayer products displayed strong luminescence under UV irradiation and strong aggregation-induced emission (AIE). In the future, this work would benefit not only the field of asymmetric synthesis but also materials science, in particular polarized organic electronics, optoelectronics and photovoltaics. 相似文献
37.
Tyihk Ern Mricz gnes M. Ott Pter G. Hajnos Michal L. Gowniak Kazimierz 《平面色谱法杂志一现代薄层色谱法》2008,21(5):331-336
JPC – Journal of Planar Chromatography – Modern TLC - The accumulation of hydrogen peroxide (H2O2) is an early and crucial step in paclitaxel-induced cancer cell death before commitment... 相似文献
38.
Anthony Przybylski Xavier Gandibleux Matthias Ehrgott 《European Journal of Operational Research》2008
In this paper, we present several algorithms for the bi-objective assignment problem. The algorithms are based on the two phase method, which is a general technique to solve multi-objective combinatorial optimisation (MOCO) problems. 相似文献
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Marzena Ciemala Kazimierz Szymiczek 《Proceedings of the American Mathematical Society》2005,133(9):2519-2523
We prove that the kernel of the ring homomorphism between the Witt ring of any order of a global field and the Witt ring of the field is a nilideal.