The deactivation of HBr(υ = 1) by Br(2P32) atoms

The vibrational relaxation of HBr(υ = 1) by bromine atoms has been measured at 295 K by a flow system using resonance fluorescence method for the detection of bromine atom concentration combined with IR laser fluorescence. The measured rate constants are

     

Classification of twisted free tensor products

Summary We would like to monitor the homotopy type of the loop space of mapping cones (Y _tf CX) for X and Y fixed and varying f. The effect of f on the homotopy type is reflected by the cooperation of the loop space of the mapping cone induced by the usual cooperation of the mapping cone Y _tfCX Y _tfCXX. Using the singular complex functor we move to the category of differential graded algebras. Motivated by the cooperation of the loop space of the mapping cone we define a free co-module. We find universal objects in this category and two classification theorems.     

Experimental test of the PCAC hypothesis in the reactionsv μ p→ μ− pπ+ and \bar v_\mu p \to \mu ^ + p\pi ^ - in theΔ(1232) region

Data on the reactionsv _μ p→ μ^? pπ⁺ and \( \bar v_\mu p \to \mu ^ + p\pi ^ - \) in the Δ(1232) region are presented and a test of the PCAC hypothesis, using a modified version of the Adler model, is performed. The analysis is based on 1081 events in the neutrino and on 180 events in the antineutrino reaction, obtained in a bubble chamber experiment with BEBC at CERN. The experimental cross-sections for an invariant hadronic massW<1.4 GeV and an (anti-)neutrino energyE _v ^L >10 GeV are determined to be (0.628±0.059)·10^?38 cm² for the neutrino and (0.168±0.023)·10^?38 cm² for the antineutrino reaction. TheQ ² andW distributions, the density matrix elements of the Δ resonance, and moments of the pion angular distribution are discussed. The data are found to be in good agreement with the Adler model in theQ ² region below 1 GeV². A maximum likelihood fit for the axial massm _A in the axial-vector form factor yields a value ofm _A =1.31±0.12 GeV. At lowQ ² the data confirm the PCAC hypothesis and the discrepancy, formerly observed between the experimental and theoretical cross-sections forv _μ p→ μ^? pπ⁺ at low momentum transfers (Q ²?0.2 GeV²), is understood as being due to inadequate pion ‘off-mass-shell’ corrections.     

Production ofρ +, −, 0 (770),η(550), ω(783) andf 2(1270) mesons in\bar v neon and ν neon charged current interactions

The production of the meson resonances ?(770) (all three charge states), η(550), ω(783) andf ₂(1270) in \(\bar v\) Ne and ν Ne charged current interactions is investigated in a bubble chamber experiment with BEBC at CERN. Except for thef ₂, the main features of resonance production are reasonably well described by the Lund model, although the average resonance multiplicities are overestimated by the model by (67±30)%. The average multiplicities of all resonances, including thef ₂, are well reproduced by a semiempirical model, whose parameters were determined from hadron interaction data.     

Dissipative dynamics of a system passing through a conical intersection: ultrafast pump-probe observables

The dynamics of a system incorporating a conical intersection, in the presence of a dissipative environment, is studied with the purpose of identifying observable ultrafast spectroscopic signatures. A model system consisting of two vibronically coupled electronic states with two nuclear degrees of freedom is constructed. Dissipation is treated by two different methods, Lindblad semigroup formalism and the surrogate Hamiltonian approach. Pump-probe experimental expectation values such as transient emission and transient absorption are calculated and compared to the adiabatic and diabatic population transfer. The ultrafast population transfer reflecting the conical intersection is not mirrored in transient absorption measurements such as the recovery of the bleach. Emission from the excited state can be suppressed on the ultrafast time scale, but the existence of a conical intersection is only one of the possible mechanisms that can provide ultrafast damping of emission.     

A new technique (COMSPARI) to facilitate the identification of minor compounds in complex mixtures by GC/MS and LC/MS: tools for the visualization of matched datasets

In the rapidly growing field of metabolomics, it is common to analyze complex biological samples by chromatography coupled to mass spectrometry. While several techniques are available for the detection of significant peaks in individual samples, it is still difficult to determine small differences between similar samples. Using conventional software, visual inspections of individual chromatograms or individual mass spectra are often of little use because the differences in the composition of small molecules are too small to be recognizable. Thus, we developed a new approach to visualizing mass spectral datasets using a tool that allows one to easily detect these small differences between mass spectra and chromatograms derived from matched samples. Using these tools on extracts from wild-type and methyltransferase knockout strains of the yeast Saccharomyces cerevisiae, we were able to readily identify those mass spectra in our data sets that were different between the wild-type and the knockout extracts and to identify the molecules involved. The software was also successfully applied to a set of LC/MS data from peptide digests that were performed with identical substrates but different enzymes. We have named this visualization tool COMSPARI (COMparision of SPectrAl Retention Information) and are making the software publicly available via Internet at.     

Stimulated fluorescence and fluorescence quenching in chlorophyll a and bacteriochlorophyll a

This communication deals with the photophysical processes that take place in chlorophyll solutions under intense nitrogen laser irradiation. The effect of the pump photon density on the fluorescence yield depends strongly on the geometry of the irradiation and the sampling set-up. If the fluorescence cell and sampling probe are placed close to the transverse arrangement used for obtaining laser output, line narrowing and gain, which are processes associated with high population inversions and stimulated fluorescence, are observed. A normal fluorescence spectrum and a decrease in fluorescence quantum yield with increasing pump power are observed in the fluorescence cells in oriented at an angle of 20–40° with respect to the transverse axis of the exciting beam. The decrease in quantum yield appears to result from absorption of the pump photons by the excited singlet of the chlorophylls, and it is suggested that an analogous mechanism may be responsible for the anomalous fluorescence quantum yield reported for in in vivo Chlorella vulgaris algae.