全文获取类型
收费全文 | 848篇 |
免费 | 29篇 |
国内免费 | 4篇 |
专业分类
化学 | 635篇 |
晶体学 | 3篇 |
力学 | 12篇 |
数学 | 52篇 |
物理学 | 179篇 |
出版年
2021年 | 4篇 |
2020年 | 7篇 |
2019年 | 16篇 |
2018年 | 11篇 |
2017年 | 4篇 |
2016年 | 13篇 |
2015年 | 12篇 |
2014年 | 22篇 |
2013年 | 31篇 |
2012年 | 29篇 |
2011年 | 47篇 |
2010年 | 22篇 |
2009年 | 30篇 |
2008年 | 40篇 |
2007年 | 62篇 |
2006年 | 32篇 |
2005年 | 42篇 |
2004年 | 46篇 |
2003年 | 36篇 |
2002年 | 25篇 |
2001年 | 21篇 |
2000年 | 18篇 |
1999年 | 12篇 |
1998年 | 9篇 |
1997年 | 6篇 |
1996年 | 11篇 |
1995年 | 11篇 |
1994年 | 8篇 |
1993年 | 9篇 |
1992年 | 12篇 |
1991年 | 11篇 |
1990年 | 16篇 |
1989年 | 12篇 |
1988年 | 13篇 |
1987年 | 12篇 |
1986年 | 8篇 |
1985年 | 22篇 |
1984年 | 15篇 |
1983年 | 8篇 |
1982年 | 12篇 |
1981年 | 10篇 |
1980年 | 8篇 |
1979年 | 12篇 |
1978年 | 9篇 |
1977年 | 4篇 |
1976年 | 15篇 |
1975年 | 17篇 |
1974年 | 5篇 |
1973年 | 4篇 |
1972年 | 4篇 |
排序方式: 共有881条查询结果,搜索用时 15 毫秒
81.
Effect of sonication on the photo-catalytic mineralization of some chlorinated organic compounds 总被引:1,自引:0,他引:1
Effects of the irradiation of ultrasound (US) on the photo-catalytic mineralization of some chlorinated organic compounds such as dichloroethane, tri- and tetrachloroethylenes, chloroacetic acids and chloromethanes were examined in oxygen saturated aqueous solutions suspended titanium dioxide (P25) particles. The yields of the sonochemical mineralization for these compounds were found to be extremely low compared to the photo-catalysis. However, the pre-sonication, US irradiation on the sample solution before the photo-irradiation, enhanced significantly the following photo-catalytic degradation to the complete oxidation. The effect was investigated in detail and it was found that the effect was mainly owing to the increase in the capability of the catalysis of which particles were sparsely dispersed by the sonication. The other contribution of the pre-sonication effect was found to be "pre-sonolysis", the initial formation of some intermediated products sonochemically, which are oxidizable more rapidly further to carbon dioxide than the original compound by the following photo-catalytic reactions. The pre-sonolysis effect was observed remarkably for trichloroacetic acid and tetrachloromethane, both of which are known to be hardly reactive to the photo-catalytic degradation. The photo-catalytic degradation with simultaneous sonication were also carried out for these compounds. The synergetic effect in the mineralization was observed both for carbontetrachloride and for trichloroacetic acid, the higher carbon dioxide yield being obtained in the simultaneous reaction than the sum of the yields in the photo-catalysis and the sonolysis each alone, while no significant synergetic effect was observed in the mineralization of other compounds. 相似文献
82.
R.?GilardiEmail author S.?Streule N.?Momono M.?Oda J.?Mesot 《The European Physical Journal B - Condensed Matter and Complex Systems》2005,47(2):231-237
Magnetization and ac-susceptibility measurements are used to
characterize the mixed phase of the high-temperature cuprate
superconductor La2-xSrxCuO4 over a large range of doping (0.075
0.20). The first order vortex lattice phase transition line HFOT(T), the upper
critical field Hc2(T) and the second peak Hsp(T) have been
investigated up to high magnetic fields (8 Tesla applied perpendicular to the CuO2 planes).
Our results reveal a strong doping dependence of the magnetic phase diagram, which can mainly be
explained by the increasing anisotropy with underdoping.
Within our interpretation, the first order vortex lattice phase transition is due to the sublimation (rather than melting)
of the vortex lattice into a gas of pancake vortices, whereas the second peak is related to the transition to a more disordered
vortex glass state. 相似文献
83.
The dual Meissner effect is observed without monopoles in quenched SU(2) QCD with Landau gauge fixing. Magnetic displacement currents that are time-dependent Abelian magnetic fields act as solenoidal currents squeezing Abelian electric fields. Monopoles are not always necessary for the dual Meissner effect. A mean-field calculation suggests that the dual Meissner effect through the mass generation of the Abelian electric field is related to a gluon condensate A(a)(mu)A(a)(mu) not equal 0 of mass dimension 2. 相似文献
84.
The hydrothermal synthesis, single crystal X-ray structures and magnetic properties of two layered cobalt-carboxylate complexes, ∞2[CoII(O2C∗CH(OH)C6H5)2] (1) and ∞2[CoII(O2C∗CH(NH2)C6H5)2] (2), where O2CCH(OH)C6H5 is mandalate and O2CCH(NH2)C6H5 is phenylglycinate, are described. Pale pink crystals of 1 and 2 were obtained by the reaction of cobalt nitrate and the enantiomer-pure acids at 120 °C. In each case, the structure consists of stacks of quasi square-grid polymeric sheets consisting of carboxylato- bridges, M-O-C-O-M, and the presence of both d- and l-enantiomers of the ligands segregated on each face of the layer. The ligands exhibit both chelating and bridging functions with the carboxylate group adopting an anti-anti mode. The magnetic properties are characteristic of weakly interacting paramagnets where the moments are elevated by an important orbital contribution via spin-orbit coupling. 相似文献
85.
A nickel catalyst coordinated by trimethylphosphine is found to effect the addition reaction of Ar-CN bonds in aromatic nitriles across alkynes to give rise to various beta-arylalkenenitriles. 相似文献
86.
Abe S Fujishima T Tsubone T Fujimura R Ono H Matoba O Oda K Shimura T Kuroda K 《Optics letters》2003,28(6):420-422
The photorefractive effect in a nominally undoped 0.91Pb(Zn1/3Nb2/3)O3-0.09PbTiO3 single crystal is measured. We report what is, to our knowledge, the first observation of the photorefractive effect in Pb-based relaxor ferroelectric crystals. The crystal is grown by the flux solution method. Then it is cut into a 2 mm x 4 mm x 8 mm piece and electrically poled along the [111] direction. The coupling constant of the two-wave mixing is 17 cm(-1), and the normalized time constant under 1-W/cm(2) illumination is 12 s at a wave-length of 476 nm. The effective trap density is calculated as 5 x 10(16) cm(-3) from the Debye screening length under the assumption of Kukhtarev's band-transport model. The dominant carrier is identified to be holes from the direction of two-wave mixing energy transfer. 相似文献
87.
Katsuya Eda Kazuhiro Kawamura 《Proceedings of the American Mathematical Society》2000,128(5):1487-1495
Let be a locally -connected compact metric space. Then, the canonical homomorphism from the singular homology group to the Cech homology group is surjective. Consequently, if a compact metric space is locally connected, then the canonical homomorphism from to is surjective.
88.
Kenji Ohta Kei Hirose Suzue Onoda Katsuya Shimizu 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2007,83(3):97-100
We measured the electrical conductivity of Mg0.81Fe0.19O magnesiowüstite, one of the important minerals comprising Earth’s lower mantle, at high pressures up to 135 GPa and 300 K in a diamond-anvil cell (DAC). The results demonstrate that the electrical conductivity increases with increasing pressure to about 60 GPa and exhibits anomalous behavior at higher pressures; it conversely decreases to around 80 GPa and again increases very mildly with pressure. These observed changes may be explained by the high-spin to low-spin transition of iron in magnesiowüstite that was previously reported to occur in a similar pressure range. A very small pressure effect on the electrical conductivity above 80 GPa suggests that a dominant conduction mechanism changes by this electronic spin transition. The electrical conductivity below 2000-km depth in the mantle may be much smaller than previously thought, since the spin transition takes place also in (Mg,Fe)SiO3 perovskite. 相似文献
89.
The response of CR-39 detector has been obtained precisely for protons, deuterons, tritons, alpha-particles and lithiumions with energies of a few MeV/nucleon. The track etch rates were determined from the growth curves of pit radius and summarized as the response functions. The accuracy of this method is high enough to discriminate among hydrogen isotopes under a certain condition. The correlation between the response and LET with various cut-off energies has also been examined. It was found that LET is not an unique parameter describing the response function adequately for different ions by the same expression. 相似文献
90.
Low-velocity pneumatic conveying in horizontal pipe for coarse particles and fine powders 总被引:3,自引:0,他引:3
First,the characteristics of low-velocity conveying of particles having different hardness are experimentally investigated in a horizontal pipeline in terms of flow pattern and pressure drop to show that the slug flow can be classified into two types depending on the settling of particles along the pipeline,and the period is small for slug flow without the settled layer,which is called solitary slug flow.The pressure drop for soft particles is shown to be larger than that for hard particles.Then,experimental results are presented on horizontal fluidized-bed conveying of fine powders to show that air release from the top surface of the conveying channel is an important factor for high mass flow rate of particles. 相似文献