Organotellurides as a source of organometallics: application in the synthesis of (+/−)-frontalin

A masked lithium homoenolate, generated by tellurium/lithium exchange, was reacted with epoxides. The lithium compound was also converted into other organometallics such as Grignard, and cuprates and the reactivity of those organometallics with epoxides was evaluated. The same building block was employed in the synthesis of (+/−)-frontalin.     

Optimization of the surface texture for silicon carbide sliding in water

Surface texturing has been recognized as an effective means to improve the tribological performances of sliding surfaces. Usually, generation additional hydrodynamic pressure to increase the load carrying capacity is regarded as the most significant effect of surface texture. In the case of silicon carbide sliding against identical material in water, the experimental results indicate that surface texture is also helpful to improve the running-in progress to smooth the contact surfaces, showing another reason to result in low friction. Based on the consideration of enhancing the generation of hydrodynamic pressure and improving running-in progress, a surface texture pattern, which was combined with large (circle, 350 μm in diameter) and small (rectangular, 40 μm in length) dimples, was designed to maximize the texture effect on the load carrying capacity of SiC surfaces sliding in water. The friction coefficient of such textured surface was evaluated and compared with that of untextured and those only with large or small dimples only. The friction reduction mechanisms of the patterns with different dimples in size are discussed.     

The matrix equation AX-YB=C and related problems

The main result of the paper is a theorem, using which a new proof of Roth’s theorem is obtained, a new solvability criterion for the matrix equation AX-YB = C is proved, a formula for a particular solution of the latter is derived, and the least of the orders of square nonsingular matrices containing a given rectangular matrix as a submatrix is determined. Bibliography: 5 titles. __________ Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 323, 2005, pp. 15–23.     

Scattering of surface plasmon polaritons by a nanoparticle with the inclusion of the magnetic dipole contribution

Using the method of the tensor Green’s function of the wave equation, the differential and total cross sections for the scattering of surface optical electromagnetic waves (surface plasmon polaritons) by a spherical nanoparticle into surface plasmon polaritons and light have been obtained with the inclusion of the magnetic dipole contribution. Using the example of noble metal systems, it has been shown that the magnetic dipole contribution may significantly affect the angular dependence of the differential cross sections and increase their anisotropy as the plasmon wavelength increases.     

Onset of crater formation during short pulse laser ablation

We report morphologic changes of metallic surfaces at the onset of ablation, starting from gentle ablation to the emergence of ablation craters. The evolution of both observed melting zones and of ablation craters therein are investigated in dependence of the ablation laser fluence for nanosecond ultraviolet laser pulses. Further, consequences of crater formation for cluster synthesis within the released atomic vapor are pointed out. PACS 52.38.Mf; 79.20.Ds; 65.40.De     

Duality for Finite Hopf Algebras Explained by Corings

We give a coring version for the duality theorem for actions and coactions of a finitely generated projective Hopf algebra. We also provide a coring analogue for a theorem of H.-J. Schneider, which generalizes and unifies the duality theorem for finite Hopf algebras and its refinements. This paper was written while the first author visited the Mathematics Departments of Syracuse University and California State University Dominguez Hills. He would like to thank both departments for their hospitality.     

Mass Power Spectrum in a Universe Dominated by the Chaplygin Gas

The mass power spectrum for a Universe dominated by the Chaplygin gas is evaluated numerically from scales of the order of the Hubble horizon to 100 Mpc. The results are compared with a pure baryonic Universe and a cosmological constant model. In all three cases, the spectrum increases with k, the wavenumber of the perturbations. The slope of the spectrum is higher for the baryonic model and smaller for the cosmological constant model, the Chaplygin gas interpolating these two models. The results are analyzed in terms of the sound velocity of the Chaplygin gas and the moment the Universe begins to accelerate.     

A STUDY OF VARIOUS BARRIERS IN ENCLOSED SOUND FIELD BY USING THE COMPUTER PROGRAM—SOFIS

In the study of the behaviors of barriers in an enclosed field, one should take into account such phenomena as sound energy reflection, absorption, scattering and diffraction. Therefore, the study is much more difficult than that in free field. In this paper, sound barriers are classified into four kinds according to their size, number and shape. Each kind of barriers is modelled by a corresponding method based on a computer program—SOFIS. The program combines the ray-tracing technique and statistical method. The impulse response and some acoustical parameters such as sound pressure level at different positions can be calculated by the program, no matter there are a certain kind of barriers in the field or the field is empty. The ray-tracing program and the algorithms for various barriers are validated by the comparison between measurement and prediction of the reverberation room and the anechoic room of the Northwestern Polytechnic University.     

Characteristics of propagation of light beams in gyrotropic crystals

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 54, No. 5, pp. 815–819, May, 1991.