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961.
Transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy were used to study the microstructure evolution of Al–Cu–Mg alloy during the initial stage of homogenization. It was found that two types of precipitation-free zones (PFZs) can form concurrently: one near grain boundaries and the other at the grain centres. Depth profile analyses of solute concentrations and dislocation-loop distributions strongly suggested that the formations of the two type of PFZs are different, due solely and exclusively to solute and vacancy depletion, respectively. A mechanism model was proposed to explain the concurrent formation of the two different type of PFZs during the initial stage of homogenization. 相似文献
962.
Ying Liang Delong Liu Hou Chen 《Journal of polymer science. Part A, Polymer chemistry》2013,51(9):1963-1968
Well‐defined high oil‐absorption resin was successfully prepared via living radical polymerization on surface of polystyrene resin‐supported N‐chlorosulfonamide group utilizing methyl methacrylate and butyl methacrylate as monomers, ferric trichloride/iminodiacetic acid (FeCl3/IDA) as catalyst system, pentaerythritol tetraacrylate as crosslinker, and L ‐ascorbic acid as reducing agent. The polymerization proceeded in a “living” polymerization manner as indicated by linearity kinetic plot of the polymerization. Effects of crosslinker, catalyst, macroinitiator, reducing agent on polymerization and absorption property were discussed in detail. The chemical structure of sorbent was determined by FTIR spectrometry. The oil‐absorption resin shows a toluene absorption capacity of 21 g g?1. The adsorption of oil behaves as pseudo‐first‐order kinetic model rather than pseudo‐second‐order kinetic model. © 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
963.
用一维Frenkel-Kontorova模型,对相互接触的两个单原子分子链具有相对运动趋势时所产生的最大静摩擦力进行了研究.分别在相邻原子的距离与周期势场的周期比b/a为可公度(commensurate)、黄金分割(golden mean)、螺旋分割(spiral mean)三种情况下,描述了特殊垫底势力的振幅A与分子链静摩擦力的关系,在特殊垫底势力的作用下上层原子链弹性系数K对静摩擦力的影响.研究表明,垫底势力的形式对静摩擦力的大小有很重要的影响.
关键词:
Frenkel-Kontorova模型
静摩擦力 相似文献
964.
AbstractThe photochemical reactions of eight carbohydrate trifluoromethanesulfonates (triflates) have been investigated in methanol in the presence of potassium iodide. For those compounds which do not contain an aromatic chromophore, photolysis results in two types of reaction. One type produces deoxy sugars by replacement of the trifluoromethylsulfonyloxy (triflyloxy) group with a hydrogen atom. The second type of reaction generates partially protected sugars by replacement of the trifluoromethylsulfonyl (triflyl) group with a hydrogen atom. When the triflate being irradiated also has a protecting group containing an aromatic ring (i.e., benzyl, benzoyl, or p-tolylsulfonyl group), removal of the protecting group is the exclusive reaction pathway. 相似文献
965.
966.
The escaped probability density of the photo-detached electron in an annular nanomicrocavity shows strong oscillations as a function of the length of the escape orbits. We present a semiclassical theory that describes theses oscillations in terms of bundles of escape orbits. Due to the interference effects of the electron waves travelling along different escaped orbits, oscillatory structures appear in the escaped probability density. In addition, the calculation results suggest that the escaped probability density of the photo-detached electron is not only related to the inner radius of the annular microcavity, but also related to the laser polarization. In order to show the correspondence between the escaped probability density and the detached electron’s escaped orbits clearly, we calculate the Fourier transformed semiclassical wave function and find that the peak positions agree well with the length of the detached electron’s orbits. We hope that our results will be useful in understanding the escape and propagation process of particles through semiconductor microjunctions or ballistic microstructure. 相似文献
967.
In this letter, we discuss the increase in the average cluster size by lowering the stagnation temperature of the methane (CH4) gas. The Coulomb explosion experiments are conducted to estimate the cluster size and the size distribution. The average CH4 cluster sizes Nay of 6 230 and 6 580 are acquired with the source conditions of 30 bars at 240 K and 60 bars at 296 K, respectively. Empirical estimation suggests a five-fold increase in the average size of the CH4 clusters at 240 K compared with that at room temperature under a backing pressure of 30 bars. A strong nonlinear Hagena parameter relation (Г^*∝ T0^-3.3) for the CH4 clusters is revealed. The results may be favorable for the production of large-sized clusters by using gases at low temperature and high back pressures. 相似文献
968.
Effect of non-hydrostatic stress on X-ray diffraction in a diamond anvil cell (DAC) is studied. The pressure gradient in the sample chamber leads to the broadening of the diffraction peaks, which increase with the hkl index of the crystal. It is found that the difference between the determined d-spacing compressive ratio d/d0 and the real d-spacing compressive ratio dr/d0 is determined by the yield stress of the pressure transmitting media (if used) and the shear modulus of the sample. On the basis of the corrected experiment data of Mao et al. (MXB86), which was used to calibrate the most widely used ruby fluorescence scale, a new relationship of ruby fluorescence pressure scale is corrected, i.e., P = (1904/9.827)[(1+λ/λ0)9.827-1]. 相似文献
969.
Yb3+ singly doped and Yb3+/Al3+ co-doped high silica glass samples are prepared,and their luminescent properties are investigated.Al3+ is considered as a beneficial activator for Yb3+-doped glass.However,the experimental result shows that the addition of Al3+ results in the transformation from Yb3+ to Yb2+ and the improvement in the photon luminescence of Yb2+.These characteristics indicate the role of Al3+ in Yb3+-doped glass. 相似文献
970.
We describe a Q-switched Er:GdVO4 laser resonantly pumped by a MgO-doped periodically poled LiNbO3 optical parametric oscillator (MgO: PPLN OPO) at 1536 nm. In continuous-wave lasing, the maximum output power is 1.14 W with an incident pump power of 4.7 W and a slope efficiency of 27%. In Q-switched operation, 1.1 mJ of output pulse energy is achieved at 200 Hz. The upper-state lifetime at different pulse repetition frequencies is also calculated. 相似文献