Viscosity of particle filled polymer melts

Summary Viscosities of particle filled polymer melts were measured at fairly low shear rate. Particles were glass beads, glass balloons, and silas balloons. Polymers were polyethylene and polystyrene. Flow curves were superimposed with respect to concentration of filler. The relative viscosity defined as the ratio of viscosity of filled polymer to that of unfilled polymer at the same shear stress is obtained as an asymptotic value even for highly filled material. The relation between relative viscosity and volume fraction of filler was represented by the equations derived byMaron andPierce orMooney. Only the distribution of particle size had influence on relative viscosity at a defined filler concentration. Yield stresses were estimated, and found to increase exponentially in the range of volume fraction from 0.1 to 0.5.

---

Zusammenfassung Viskositäten von Polymerschmelzen, die mit Teilchen gefüllt worden waren, wurden bei mittleren Schergeschwindigkeiten bestimmt. Als Teilchen wurden Voll- und Hohlkugeln aus Glas, sowie sog. silas balloons, als Polymere Polyäthylen und Polystyrol verwendet. Die Fließkurven für verschiedene Füllstoffkonzentrationen wurden überlagert. Die relative Viskosität, definiert als das Verhältnis der Viskositäten von gefülltem und ungefülltem Polymer bei gleicher Schubspannung, besitzt einen asymptotischen Wert selbst für hoch gefülltes Material. Die Beziehung zwischen relativer Viskosität und Füllstoff-Volumenkonzentration läßt sich durch eine vonMaron undPierce oder eine vonMooney abgeleitete Gleichung beschreiben. Nur die Teilchengrößenverteilung hat bei einer definierten Füllstoffkonzentration einen Einfluß auf die relative Viskosität. Fließspannungen werden abgeschätzt und dafür in einem Konzentrationsbereich zwischen 0,1 und 0,5 ein exponentieller Anstieg gefunden.

---

---

With 13 figures and 2 tables     

Current developments and future trends in solid-phase microextraction techniques for pharmaceutical and biomedical analyses

Sample preparation is important for the isolation and concentration of desired trace components from complex matrices. Sample preparation is the most labor-intensive and error-prone process in analytical methodology, and greatly influences the reliable and accurate determination of analytes. The integration of sample preparation with various analytical instruments is most conveniently achieved by using microextraction techniques and/or microdevices. Solid-phase microextraction (SPME) is both simple and effective, enabling miniaturization, automation and high-throughput performance. Moreover, SPME has reduced analysis times, as well as the costs of solvents and disposal. This review describes current developments and future trends in novel SPME techniques, including fiber SPME, in-tube SPME and related new microextraction techniques. Especially innovative SPME approaches, including multi-well high-throughput sampling, ligand-receptor binding study for pharmacokinetics, direct in vivo sampling, chip-based microfluidic system, and new sampling techniques using intelligent carbon nanotube and temperature-response polymer in pharmaceutical and biomedical analysis are focused items.     

Highly efficient enzymatic synthesis of 3'-deoxyapionucleic acid (apioNA) having the four natural nucleobases

The synthesis of the 3'-deoxyapionucleoside 3'-triphosphates (apioNTPs) having the four natural nucleobases and their enzymatic incorporation into a DNA-DNA primer-template have been tried. Therminator DNA polymerase was shown to incorporate these apioNTPs effectively giving 43mer DNA-apioNA chimera.     

Charged particle activation analysis of boron and carbon on the surface of silicon wafer

Boron and carbon on the surface of silicon wafers in ordinary atmospheres were measured by activation with the¹⁰B(d,n)¹¹C and¹²Cd(d,n)¹³N reaction, respectively. Two sample plates in intimate contact were bombarded by deuterons, and the¹¹C or¹³N formed at the inside surfaces were measured after chemical separation. From 1.2·10¹³ to 8.4·10¹³ atoms/cm² of boron and from 2.4·10¹⁴ to 6.1·10¹⁵ atoms/cm² of carbon were found ,and the sensitivity was extended down to 5·10¹² and 3·10¹² atoms/cm² for boron and carbon, respectively.     

Turbulence structure of air-water bubbly flow—III. transport properties

An experimental study of heat and bubble transport in turbulent air-water bubbly flow was carried out by means of tracer techniques. Helium tracer gas concentration data and temperature distributions were used to extract bubble and heat diffusivity information. The results indicated that the turbulent velocity components of the liquid phase play a predominant role in the turbulent transport process. A systematic increase of diffusivity of heat, ?_H, with quality and water velocity was observed. An empirical correlation for the diffusivity ratio ?_H,TP/?_H,SP is presented. The Péclet number, u′_covbar|dφ, for bubble dispersion can be approximated by 2.0, independent of the flow variables. The bubble-to-heat diffusivity ratio, φ/?_H, approaches unity with increasing quality and water velocity. Momentum transport is also discussed, based on a mixing length theory.     

Ultrasonic studies of membrane suspensions

Summary The mechanical and the dynamic properties of various membranes were studied by the ultrasonic-resonance method. The compressibility of the membranes was in the range from 2.5·10⁻¹¹ to 5·10⁻¹¹ cm²/dyn and influenced by several factors such as phase transition, incorporation of cholesterol or proteins and configuration of proteins. The ultrasonic relaxation was measured for two membrane systems, dipalmitoylphosphatidylcholine bilayer and sarcoplasmic-reticulum membrane. The results indicated that the ultrasonic measurements are very sensitive to the co-operative transition in lipid bilayers as well as the relaxation of biological membranes containing intrinsic proteins. Paper presented at the ?Meeting on Lyotropics and Related Fields?, held in Rende, Cosenza, September 13–18, 1982.