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排序方式: 共有215条查询结果,搜索用时 15 毫秒
101.
Pieter J. Nieuwland Kaspar Koch Noud van Harskamp Ron Wehrens Jan C. M. van Hest Prof. Dr. Floris P. J. T. Rutjes Prof. Dr. 《化学:亚洲杂志》2010,5(4):799-805
The generally accepted benefits of small lateral dimensions of microreactors (1 μm to 1 mm) enable a different way of performing synthetic chemistry: Extremely short contact times in the millisecond range can circumvent the need for performing highly exothermic and fast reactions at very low temperatures. In order to fully exploit this technology, such fast processes need to be redesigned and investigated for optimal reaction conditions, which can differ drastically from the ones traditionally applied. In a comprehensive study, we optimized the selective Swern–Moffatt oxidation of benzyl alcohol to benzaldehyde by varying five experimental parameters, including reaction time and temperature. Employing an ultrashort mixing and reaction time of only 32 ms, the optimal temperature was determined to be 70 °C, approximately 150 °C higher than in the conventional batch conditions. This remarkable difference shows both the potency of continuous‐flow chemistry as well as the urgency of a paradigm shift in reaction design for continuous‐flow conditions. 相似文献
102.
103.
Rösener B Kaspar S Rattunde M Töpper T Manz C Köhler K Ambacher O Wagner J 《Optics letters》2011,36(18):3587-3589
We demonstrate a 2 μm semiconductor disk laser emitting in a single longitudinal mode with a linewidth in the <10 kHz range. A heterodyne detection scheme was used for precise linewidth measurements. In these experiments, the output beams of two identical laser cavities were superposed in order to generate a beat note signal on a photodiode. In the absence of active frequency stabilization, a linewidth of 45 kHz was measured at an output power of 100 mW. When using a frequency stabilization consisting of a feedback loop with a Fabry-Perot interferometer as wavelength reference, the linewidth could be further reduced to 9 kHz. 相似文献
104.
Kaspar Nipp 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1983,34(3):277-290
A classical error estimate for singularly perturbed ordinary differential equations due to A. N. Tikhonov is generalized in the neighbourhood of a so-called leaving point where a certain stability assumption ceases to be valid. This is done for the planar case, and an application to the Van der Pol relaxation oscillator is given. 相似文献
105.
106.
[reaction: see text] An intermolecular hydroamination reaction of norbornene is presented that uses catalytic amounts of user-friendly TiCl(4) and tolerates a variety of functional groups. In addition, a secondary amine is converted using this methodology. 相似文献
107.
A general approach to 1-6 dioxa[4.5]spirodecanes is presented and applied to the total synthesis of one pheromone of Paravespula vulgaris L. 相似文献
108.
Morgenstern B Kutzky B Neis C Stucky S Hegetschweiler K Garribba E Micera G 《Inorganic chemistry》2007,46(10):3903-3915
The complex formation of vanadium(IV) with cis-inositol (ino) and the corresponding trimethyl ether 1,3,5-trideoxy-1,3,5-trimethoxy-cis-inositol (tmci) was studied in aqueous solution and in the solid-state. With increasing pH, the formation of [VO(H-2L)], [(VO)2L2H-5]-, [VO(H-3L)]- (L = ino) or [(VO)2L2H-6]2- (L = tmci), [V(H-3L)2]2-, and [VO(H-3L)(OH)2]3- was observed. For the vanadium(IV)/ino system, [(VO)2L2H-7]3- was observed as an additional dinuclear species. The formation constants of these complexes were determined by potentiometric titrations (25 degrees C, 0.1 M KCl). In addition, the vanadium(IV)/ino system was investigated by means of UV-vis spectrophotometric methods. EPR spectroscopy and cyclic voltammetry confirmed this complexation scheme. EPR measurements indicated the formation of three distinct isomers of the non-oxo complex [V(H-3ino)2]2- in weakly basic solution. This type of isomerism, which is not observed for the vanadium(IV)/tmci system, was assigned to the ability of ino to bind the vanadium(IV) center with three alkoxo groups having either a 1,3,5-triaxial or an 1,2,3-axial-equatorial-axial arrangement. The structures of [V(H-3ino)2][K2(ino)2].4H2O (1) and [Na6V(H-3ino)2](SO4)2.6H2O (2) were determined by single-crystal X-ray analysis. In both compounds, the coordination of each ino molecule to the vanadium(IV) center via three axial deprotonated oxygen donors was confirmed. The centrosymmetric structure of the coordination spheres corresponds to an almost regular octahedral geometry with a twist angle of 60 degrees. The crystal structure of the potassium complex 1 represents an unusual 1:1 packing of [V(H-3ino)2]2- dianions and [K2(ino)2]2+ dications, in which both K+ ions have a coordination number of nine and are bonded simultaneously to a 1,3,5-triaxial and an 1,2,3-axial-equatorial-axial site of ino. In 2, the [V(H-3ino)2]2- complexes are surrounded by six Na+ counterions that are bonded to the axial alkoxo oxygens and to the equatorial hydroxy oxygens of the cis-inositolato moieties. The six Na+ centers are further interlinked by bridging sulfate ions. According to EPR spectroscopy, the D3d symmetric structure of the [V(H-3ino)2]2- anion is retained in H2O, in dimethylformamide, and in a mixture of CHCl3/toluene 60:40 v/v. 相似文献
109.
Dong RY Geppi M Marini A Hamplova V Kaspar M Veracini CA Zhang J 《The journal of physical chemistry. B》2007,111(33):9787-9794
In this work, the liquid crystal (S)-2-methylbutyl-[4'-(4' '-heptyloxyphenyl)-benzoyl-4-oxy-(S)-2-((S)-2')-benzoyl)-propionyl)]-propionate (ZLL 7/*) was investigated by means of 13C NMR spectroscopy. This compound has a very peculiar mesomorphic behavior, showing the following phases: paraelectric SmA, ferroelectric SmC*, antiferroelectric SmC*A, re-entrant ferroelectric SmC*re, and ferroelectric hexatic Sm*HEX. The structural and orientational ordering properties of ZLL 7/* have been determined by exploiting the nuclear chemical shielding properties of 13C. To this aim, solid-state NMR techniques such as CP, SPINAL-64, and SUPER have been used in combination with DFT calculations. The agreement between experimental and in vacuo DFT shielding parameters appears to be satisfactory. The orientational order parameters obtained from the 13C shielding analysis have been discussed, taking into account different data analysis approaches and comparing them to those previously obtained from an independent 2H NMR study. 相似文献
110.
The long-chain branched thermoplastic tetrafluoroethylene–hexafluoropropylene–vinylidenefluoride terpolymers (LCB THV) investigated
in this paper are new polymers with a unique combination of properties like a high stability against aging or weathering and
a very good chemical resistance. But not much is known about the rheological behaviour of the LCB THV, yet. In this paper,
non-linear rheological properties like shear thinning and strain hardening are studied. Two different types of the THV with
different contents of comonomers and, therefore, different melting points are examined. The THV with the higher melting point
is insoluble. The other with the lower melting temperature is soluble and, therefore, was characterised by size exclusion
chromatography coupled with light scattering with respect to its molecular structure. The results of the rheological measurements
show a pronounced shear-thinning and strain-hardening behaviour for the long-chain branched materials. Both properties are
of great importance for processing operations governed by shear and elongational flows.
相似文献
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