Polymeric waveguides based on photopolymerizing methacrylate compositions

Contact photolithography was used to fabricate three-layer polymeric waveguide structures with transverse dimensions of 50 × 90 μm on the basis of two photopolymerizing methacrylate compositions with different refractive indices. The optical loss on the wavelength of 632.8 nm was 0.37 ± 0.14 dB cm^?1. This loss is mostly due to the light scattering by the material of the waveguide layer produced by bulk polymerization.     

Anodic oxide-film of the Co—Sn—O composition

Properties and electrocatalytic activity of thin-film (∼2 μm) oxide coatings on aTi support are considered by the example of the anodic chlorine evolution reaction. The coatings are obtained by thermally decomposing Co and Sn chloride solutions of different compositions on a Ti plate. The Co and Sn oxides are present in all studied compositions as individual phases and form no compounds or solid solutions. The oxide coating containing 70 at. % Co and 30 at. % Sn reveals a maximum electrocatalytic activity. The existence of the optimum composition is attributed to a favorable effect tin dioxide has on the formation of a transition layer between the Ti support and oxide coating. Tin dioxide hampers the Ti diffusion in the main coating and its subsequent oxidation, thus diminishing the negative impact titanium oxides have on the coating     

Effect of coalescence and of the character of the initial oxide on the photoluminescence of ion-synthesized Si nanocrystals in SiO<Subscript>2</Subscript>

The photoluminescence intensity (PLI) related to Si nanocrystals in a SiO₂: nc-Si system synthesized by ion implantation is studied experimentally and theoretically as a function of the Si+ ion dose at various annealing temperatures T_ann (1000–1200°C). The dose corresponding to the maximum PLI is found to decrease with increasing T_ann. These data are explained in terms of a model taking into account the coalescence of neighboring nanocrystals and the dependence of the probability of radiative recombination of quantum dots on their size. It is found that, when silicon oxide is grown in a wet atmosphere, the photoluminescence spectrum contains an additional band (near 850 nm), which is related to shells around the nanocrystals. This band weakens abrupily after high-temperature annealing in an oxidizing atmosphere (air).     

Electron-fractographic investigation of the brittle fracture of polyethylene

The results are presented of an electron-microscope investigation of the brittle fracture of linear polyethylene at the temperature of liquid nitrogen. It is shown that the physical nature of the structural details of the microrelief of the fracture surface is conditioned by local plastic deformation of the stratified lamellar structures in a thin layer adjacent to the fracture surface preceding and accompanying fracture. The possibility of local self-heating is discussed and a possible mechanism of plastic deformation of the crystal platelets at low temperatures is proposed.Mekhanika Polimerov, Vol. 3, No. 2, pp. 286–290, 1967     

Lamellar structure and plasticity micromechanisms in bulk crystalline polymers. Communication 1

It is shown by electron microscopy that the lamellar structure typical of bulk crystalline polymers is identical in its structural-morphological characteristics with the typical products of martensite transformations in metal systems. It is also established that the polymer crystallization process has the typical characteristics of transformations governed by the shear (martensite) mechanism. These conclusions are used as a basis for an examination of the principal factors controlling the formation of the real structure of bulk polymers. The thermodynamic conditions under which bulk polymers crystallize require that the lamellar-spherulitic structure be formed in accordance with a self-consistent shear mechanism. In accordance with the new model, the spherulites represent an organization of the martensite lamellae in which the structural stress fields are mutually compensated. The proposed model underlines the fact that polycrystalline polymers and metal systems in the martensitic state are structurally similar materials.E. O. Paton Electrowelding Institute, Academy of Sciences of the Ukrainian SSR, Kiev. Translated from Mekhanika Polimerov, No. 3, pp. 387–394, May–June, 1976.     

The effect of topology on organization of synchronous behavior in dynamical networks with adaptive couplings

We study the influence of the initial topology of connections on the organization of synchronous behavior in networks of phase oscillators with adaptive couplings. We found that networks with a random sparse structure of connections predominantly demonstrate the scenario as a result of which chimera states are formed. The formation of chimera states retains the features of the hierarchical organization observed in networks with global connections [D.V. Kasatkin, S. Yanchuk, E. Schöll, V.I. Nekorkin, Phys. Rev. E 96, 062211 (2017)], and also demonstrates a number of new properties due to the presence of a random structure of network topology. In this case, the formation of coherent groups takes a much longer time interval, and the sets of elements that form these groups can be significantly rearranged during the evolution of the network. We also found chimera states, in which along with the coherent and incoherent groups, there are subsets, whose different elements can be synchronized with each other for sufficiently long periods of time.