Water treatment: functional nanomaterials and applications from adsorption to photodegradation

Global efforts for engineering desired materials which are able to treat the water sources still are ongoing in the bench level methods. Considering adsorbent and photocatalytic materials as the main reliable candidates still are encountering with struggles because of many challenges that restrict their large-scale application. This review comprehensively considered the recent advanced materials water treatment methods which involve to magnetic, activated carbon, carbon nanotubes (CNTs), graphene (G), graphene oxide (GO), (Graphene) quantum dots, carbon nanorods, carbon nano-onions, and reduced graphene oxide (RGO), zeolite, silica and clay-based nanomaterials. The adsorption and photocatalytic properties of these nanomaterials introduced them as highly potent option for heavy metal ions and organic dyes removal and photocatalytic degradation. High specific surface area in conjugation with presenting higher kinetics of adsorption and decomposition are the main characteristics of these materials which make them appropriate to treat wastewater even in ultralow concentration of the pollutants. Considering the mechanistic aspects of the adsorption and photocatalytic decomposition process, challenges and opportunities were other subjects that have been highlighted for the discussed nanomaterials. In term of the adsorption approaches, the mechanism of adsorptions and their influence on the maximum adsorption capacity were discussed and also for photocatalyst approach the radical active spices and their role in kinetic and efficiency of the organic pollutant decomposition were provided a deep discussion.     

Na-K liquid alloy:A review on wettability enhancement and ionic carrier selection mechanism

The intrinsic liquid interface of Na-K alloy allays concerns about dendrite growth on metal anodes that are thermodynamically within the room temperature(20-22℃).Nevertheless,it hinders the formation of a stable electrode structure due to the inferior wettability induced by considerable liquid tension.In addition,the dominant ionic carrier in the Na-K alloy is subject to multiple factors,which is not conducive to customized battery design.This review,based on recently reported frontier achievements on Na-K liquid anodes,summarizes practical strategies for promoting the wettability by hightemperature induction,capillary effect,vacuum infiltration,and solid interface protection.Furthermo re,four selection mechanisms of the dominant ionic carrier are presented:(1) ion property dominated,(2)cathode dominated,(3) separator dominated,and(4) solid electrolyte interface dominated.Notably,initial electrolytes in energy storage systems have been unable to play a decisive role in ionic selection.Utilizing a superior wettability strategy and simultaneously identifying the dominant ionic carrier can facilitate the tailored application of dendrite-free Na-K liquid anodes.     

Musa sp. Leaves Extract Ameliorates the Hepato-Renal Toxicities Induced by Cadmium in Mice

Heavy metals intoxication causes several health problems that necessitate finding new protective and therapeutic approaches. This study aimed to evaluate the impact of Musa sp. leaves extract (MLE) on hepato-renal toxicities induced by cadmium (Cd) in male mice. The phytochemical screening, metal chelating activity (MCA), and the median lethal dose (LD₅₀) of MLE were determined. Fifty CD-1 male mice were used and intraperitoneally (i.p.) injected with MLE (1000 to 5000 mg/kg b.wt) for MLE LD₅₀ determination. Another 50 mice were used for evaluating the effect of MLE on Cd toxicity. Blood samples were collected for hematological, liver, and kidney functions assessments. Liver tissue homogenates were used for determination of oxidant/antioxidant parameters. Liver and kidney tissues were harvested for histopathological and molecular investigations. MLE showed potent in vitro antioxidant activities. The MCA and LD₅₀ of the MLE were 75 µg/mL and 3000 mg/kg b.wt, respectively. MLE showed beneficial therapeutic activity against hepato-renal toxicities in Cd-intoxicated mice, evidenced by improving the hematological, biochemical, histopathological, and molecular alterations.     

CONTINUUM TOPOLOGY OPTIMIZATION FOR MONOLITHIC COMPLIANT MECHANISMS OF MICRO-ACTUATORS

A multi-objective scheme for structural topology optimization of distributed compliant mechanisms of micro-actuators in MEMS condition is presented in this work, in which mechanical flexibility and structural stiffness are both considered as objective functions. The compliant micro-mechanism developed in this way can not only provide sufficient output work but also have sufficient rigidity to resist reaction forces and maintain its shape when holding the work-piece. A density filtering approach is also proposed to eliminate numerical instabilities such as checkerboards, mesh-dependency and one-node connected hinges occurring in resulting mechanisms. SIMP is used as the interpolation scheme to indicate the dependence of material modulus on element-regularized densities. The sequential convex programming method, such as the method of moving asymptotes (MMA), is used to solve the optimization problem. The validation of the presented methodologies is demonstrated by a typical numerical example.     

Effects of ultrasound on growth, bioconversion of isoflavones and probiotic properties of parent and subsequent passages of Lactobacillus fermentum BT 8633 in biotin-supplemented soymilk

This study aimed to evaluate the effects of ultrasound on Lactobacillus fermentum BT 8633 in parent and subsequent passages based on their growth and isoflavone bioconversion activities in biotin-supplemented soymilk. The treated cells were also assessed for impact of ultrasound on probiotic properties. The growth of ultrasonicated parent cells increased (P < 0.05) by 3.23-9.14% compared to that of the control during fermentation in biotin-soymilk. This was also associated with enhanced intracellular and extracellular (8.4-17.0% and 16.7-49.2%, respectively; P < 0.05) β-glucosidase specific activity, leading to increased bioconversion of isoflavones glucosides to aglycones during fermentation in biotin-soymilk compared to that of the control (P < 0.05). Such traits may be credited to the reversible permeabilized membrane of ultrasonicated parent cells that have facilitated the transport of molecules across the membrane. The growing characteristics of first, second and third passage of treated cells in biotin-soymilk were similar (P > 0.05) to that of the control, where their growth, enzyme and isoflavone bioconversion activities (P > 0.05) were comparable. This may be attributed to the temporary permeabilization in the membrane of treated cells. Ultrasound affected probiotic properties of parent L. fermentum, by reducing tolerance ability towards acid (pH 2) and bile; lowering inhibitory activities against selected pathogens and reducing adhesion ability compared to that of the control (P < 0.05). The first, second and third passage of treated cells did not exhibit such traits, with the exception of their bile tolerance ability which was inherited to the first passage (P < 0.05). Our results suggested that ultrasound could be used to increase bioactivity of biotin-soymilk via fermentation by probiotic L. fermentum FTDC 8633 for the development of functional food.     

Rapidity density distributions in antiproton-proton collisions

Data on the density of charged particles in rapidity space for annihilation and non-annihilation p?p interactions at 7.3 and 12 GeV/c are reported. It is shown that the central rapidity density for non-annihilation processes is a simple linear function of $\text{ln}\text{(}\text{s}\text{)}$ from these low energies up to p?p collider energies ($\text{s}\text{=540}\text{GeV}$). Significant differences in density distributions for p?p and e^?e⁺ annihilations at comparable energies are found.     

Practical aspects of shimming a high resolution magic angle spinning probe

High resolution magic angle spinning (HRMAS) has become an extremely versatile tool to study heterogeneous systems. HRMAS relies on magic angle spinning of the sample to average out to zero magnetic susceptibility differences in the sample and to obtain resonance linewidths approaching those of liquid state NMR. Shimming such samples therefore becomes an important issue. By analyzing the different sources of magnetic field perturbations present in a sample under MAS conditions, we propose a simple protocol to obtain optimum shim settings in HRMAS. In the case of aqueous samples, we show that the lock level cannot be used as a reliable indicator of the quality of the shims at high spinning speeds. This effect is explained by the presence of temperature gradients imparted by the sample rotation.     

Ambient noise cross correlation in free space: theoretical approach

It has been experimentally demonstrated that the Green's function between two points could be recovered using the cross-correlation function of the ambient noise measured at these two points. This paper investigates the theory behind this result in the simple case of a homogeneous medium with attenuation.