Solvability of the -Laplacian with nonlocal boundary conditions

Rather mild sufficient conditions are provided for the existence of positive solutions of a boundary value problem of the form

which unify several cases discussed in the literature. In order to formulate these conditions one needs to know only properties of the homeomorphism and have information about the level of growth of the response operator F. No metric information concerning the linear operators L₀,L₁ in the boundary conditions is used, except that they are positive and continuous and such that L_j(1)<1 j{0,1}.     

Humean Supervenience in the Light of Contemporary Science

It is shown that Lewis’ ontological doctrine of Humean supervenience incorporates at its foundation the so-called separability principle of classical physics. In view of the systematic violation of the latter within quantum mechanics, the claim that contemporary physical science may posit non-supervenient relations beyond the spatiotemporal ones is reinforced on a foundational basis concerning constraints on the state representation of physical systems. Depending on the mode of assignment of states to quantum systems — unit state vectors versus statistical density operators — we distinguish between strongly and weakly non-Humean, non-supervenient relations. It is demonstrated that in either case, the relations of quantum entanglement constitute prototypical examples of irreducible physical relations that do not supervene upon a spatiotemporal arrangement of Humean qualities, weakening, thereby, the thesis of Humean supervenience. In this respect, the status of Lewis’ recombination principle is examined, whereas his conception of lawhood is critically investigated. It is concluded that the assumption of ontological reductionism, as expressed in Lewis’ Humean doctrine, cannot be regarded as a reliable code of the nature of the physical world and its contents. It is proposed instead that due to the undeniable existence of non-supervenient relations, a metaphysic of relations of a moderate kind ought to be acknowledged as an indispensable part of our understanding of the natural world at a fundamental level.     

Coordination-driven self assembly of a brilliantly fluorescent rhomboid cavitand composed of bodipy-dye subunits

The two sp(3) hybridized fluorine atoms of a Bodipy dye have been synthetically replaced with the linear donor ligand 4-ethynylpyridine (-C≡C-Py) to form a rigid and highly symmetrical 109.5° building block in which the fluorophore subunit is vertically aligned to the plane formed by the -C≡C-Py donors. Upon reaction of the above tecton with a 90° organoplatinum acceptor unit, an intensely fluorescent rhomboid cavitand was manifested in solution. In contrast to the vast majority of coordination-driven self-assembled chromophoric systems, the present one fully conserves the excellent photophysical properties of the parent Bodipy dye. These unique features of the present metallosupramolecular entity constitute a fascinating metal-to-ligand self-assembled prototype for building compact and intensely luminescent materials with host-guest capabilities.     

Ionization of aromatic sulfides in nonpolar media: free vs reaction-controlled electron transfer

The primary products of the bimolecular free electron transfer (FET) from aromatic sulfides (PhSCH2Ph, PhSCHPh2, PhSCPh3) to n-butyl chloride radical cations are two radical cation conformers: a dissociative and a metastable one. In analogy with formerly studied donor systems, this result seems to reflect femtosecond oscillations in the ground state of the sulfides such as torsion motions around the Ar-S bond. This motion is accompanied by a marked electron fluctuation within the HOMO (or the n) orbitals. The FET products observed in the nanosecond time scale such as the metastable sulfide radical cations (Ar-S-CR3*+), the dissociation products R3C+; and R3C*, and their (experimentally) nondetectable counterparts Ar-S* as well as Ar-S+ can be understood with the simplified assumption of two extreme conformations, namely a planar and a twisted donor molecule. Using mediator radical cations (benzene, butylbenzene, biphenyl), the stepwise reduction of the free energy of the electron transfer from -DeltaH = 2.5 to 相似文献   

Asymptotic 2–periodic difference equations with diagonally self–invertible responses

We provide sufficient conditions which guarantee that all positive solutions of a nonlinear difference equation of third order is asymptotically periodic 2. An estimate of the width of such solutions in terms of the initial values is also provided     

Category-Theoretic Interpretative Framework of the Complementarity Principle in Quantum Mechanics

This study aims to provide an analysis of the complementarity principle in quantum theory through the establishment of partial structural congruence relations between the quantum and Boolean kinds of event structure. Specifically, on the basis of the existence of a categorical adjunction between the category of quantum event algebras and the category of presheaves of variable Boolean event algebras, we establish a twofold complementarity scheme consisting of a generalized/global and a restricted/local conceptual dimension, where the latter conception is subordinate to and constrained by the former. In this respect, complementarity is not only understood as a relation between mutually exclusive experimental arrangements or contexts of comeasurable observables, as envisaged by the original conception, but it is primarily comprehended as a reciprocal relation concerning information transfer between two hierarchically different structural kinds of event structure that can be brought into partial congruence by means of the established adjunction. It is further argued that the proposed category-theoretic framework of complementarity naturally advances a contextual realist conceptual stance towards our deeper understanding of the microphysical nature of reality.

     

Maximizing throughput in queueing networks with limited flexibility

We study a queueing network where customers go through several stages of processing, with the class of a customer used to indicate the stage of processing. The customers are serviced by a set of flexible servers, i.e., a server is capable of serving more than one class of customers and the sets of classes that the servers are capable of serving may overlap. We would like to choose an assignment of servers that achieves the maximal capacity of the given queueing network, where the maximal capacity is λ^∗ if the network can be stabilized for all arrival rates λ < λ^∗ and cannot possibly be stabilized for all λ > λ^∗. We examine the situation where there is a restriction on the number of servers that are able to serve a class, and reduce the maximal capacity objective to a maximum throughput allocation problem of independent interest: the total discrete capacity constrained problem (TDCCP). We prove that solving TDCCP is in general NP-complete, but we also give exact or approximation algorithms for several important special cases and discuss the implications for building limited flexibility into a system.     

On the Recursive Sequence

The boundedness, global attractivity, oscillatory and asymptotic periodicity of the nonnegative solutions of the difference equation?in the title is investigated, where all the coefficients are nonnegative real numbers. The paper is motivated by an open problem proposed by Ladas [Open problems and conjectures, J. Differ. Equations?Appl., 5 (1999), 211–215].